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Chế tạo dễ dàng các hạt nano hợp kim Pt–Ni hỗ trợ trên graphene oxide khử để phục vụ như những chất điện xúc tác xuất sắc cho phản ứng tiến hóa hydro trong môi trường kiềm
Tóm tắt
Phát triển những điện xúc tác hiệu suất cao trong điện phân kiềm có ý nghĩa quan trọng về việc giảm thiểu tiêu tốn năng lượng không cần thiết trong quá trình sản xuất hydro. Trong nghiên cứu này, chúng tôi đã trình bày một chiến lược giảm hóa học một bước để chế tạo graphene oxide khử (rGO) hỗ trợ các hạt nano hợp kim platinum–nickel như những điện xúc tác xuất sắc cho phản ứng tiến hóa hydro (HER) ở điều kiện kiềm. Các điện xúc tác nano hợp kim hỗ trợ graphene được tạo ra bằng cách kiểm soát tỷ lệ mol của các tiền chất bimetallic. Chúng tôi xác nhận rằng các loại nickel trên bề mặt của các điện xúc tác nano được tổng hợp có xu hướng bị oxi hóa thành nickel hydroxide trong quá trình chế tạo. Các điện xúc tác nano của chúng tôi được tổng hợp với tỷ lệ mol tương đương giữa muối platinum và nickel cho thấy hoạt tính điện xúc tác rất cao cho HER hơn so với các loại Pt/C thương mại và các loại Pt hỗ trợ graphene trong cùng điều kiện. Sự cải thiện về hiệu suất không chỉ được cho là do lớp nickel hydroxide trên các điện xúc tác nano của chúng tôi thúc đẩy quá trình phân hủy nước trong môi trường kiềm mà còn do sự thay thế một phần các nguyên tử Pt bằng các nguyên tử Ni làm giảm năng lượng liên kết Pt–H và cải thiện quá trình desorption các nguyên tử hydrogen trên các điện xúc tác nano hợp kim Pt–Ni. Hơn nữa, các điện xúc tác nano của chúng tôi cũng thể hiện tính ổn định xúc tác HER tuyệt vời. Kết quả của chúng tôi sẽ cung cấp một chiến lược đơn giản và hiệu quả trong việc phát triển các điện xúc tác nano composite chứa Pt xuất sắc cho các ứng dụng trong điện xúc tác.
Từ khóa
#điện xúc tác #phản ứng tiến hóa hydro #graphene oxide khử #hợp kim platinum-nickel #môi trường kiềmTài liệu tham khảo
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