Facile Synthesis of Battery-Type CuMn2O4 Nanosheet Arrays on Ni Foam as an Efficient Binder-Free Electrode Material for High-Rate Supercapacitors

Nanomaterials - Tập 13 Số 6 - Trang 1125
Chandu V. V. Muralee Gopi1, R. Ramesh2, Rajangam Vinodh3, Salem Alzahmi4,5, Ihab M. Obaidat6,5
1Department of Electrical Engineering, University of Sharjah, Sharjah P.O. Box 27272, United Arab Emirates
2Department of Chemical Engineering, School of Mechanical, Chemical and Materials Engineering, Adama Science and Technology University, Adama P.O. Box 1888, Ethiopia
3Green Hydrogen Lab (GH2Lab), Institute for Hydrogen Research (IHR), Université du Québec à Trois-Rivières (UQTR), 3351 Boulevard des Forges, Trois-Rivières, QC G9A 5H7, Canada
4Department of Chemical & Petroleum Engineering, United Arab Emirates University, Al Ain P.O. Box 15551, United Arab Emirates
5National Water and Energy Center, United Arab Emirates University, Al Ain, P.O. Box 15551, United Arab Emirates
6Department of Physics, United Arab Emirates University, Al Ain, P.O. Box: 15551, United Arab Emirates

Tóm tắt

The development of battery-type electrode materials with hierarchical nanostructures has recently gained considerable attention in high-rate hybrid supercapacitors. For the first time, in the present study novel hierarchical CuMn2O4 nanosheet arrays (NSAs) nanostructures are developed using a one-step hydrothermal route on a nickel foam substrate and utilized as an enhanced battery-type electrode material for supercapacitors without the need of binders or conducting polymer additives. X-ray diffraction, scanning electron microscopy (SEM), and transmission electron microscopy (TEM) techniques are used to study the phase, structural, and morphological characteristics of the CuMn2O4 electrode. SEM and TEM studies show that CuMn2O4 exhibits a nanosheet array morphology. According to the electrochemical data, CuMn2O4 NSAs give a Faradic battery-type redox activity that differs from the behavior of carbon-related materials (such as activated carbon, reduced graphene oxide, graphene, etc.). The battery-type CuMn2O4 NSAs electrode showed an excellent specific capacity of 125.56 mA h g−1 at 1 A g−1 with a remarkable rate capability of 84.1%, superb cycling stability of 92.15% over 5000 cycles, good mechanical stability and flexibility, and low internal resistance at the interface of electrode and electrolyte. Due to their excellent electrochemical properties, high-performance CuMn2O4 NSAs-like structures are prospective battery-type electrodes for high-rate supercapacitors.

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Nanomaterials

Tập 13 Số 6

1125

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