Facile Fabrication of Functional Polypyrrole Nanotubes via a Reactive Self‐Degraded Template

Macromolecular Rapid Communications - Tập 26 Số 21 - Trang 1736-1740 - 2005
Xiaoming Yang1, Zhenbang Zhu1, Tingyang Dai1, Yun Lu2
1Department of Polymer Science and Engineering, State Key Laboratory of Coordination chemistry, College of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, P. R. China
2Department of Polymer Science and Engineering, State Key Laboratory of Coordination Chemistry, College of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, P. R. China. Fax: 86‐25‐83317761

Tóm tắt

Abstract

Summary: Polypyrrole nanotubes with high electric conductivity and azo function have been fabricated in high yield via an in‐situ polymerization. During the process fibrillar complex of FeCl3 and methyl orange (MO), acting as a reactive self‐degraded template, directed the growth of polypyrrole on its surface and promoted the assembly into hollow nanotubular structures.

TEM image of uncompleted PPy nanotubes synthesized in MO solutions after reaction for 40 min.

magnified image

TEM image of uncompleted PPy nanotubes synthesized in MO solutions after reaction for 40 min.

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Tài liệu tham khảo

10.1038/354056a0

 

10.1021/ar00050a002

10.1088/0964-1726/11/5/304

10.1021/ac020711a

10.1002/cphc.200300770

10.1021/cm990001u

 

10.1088/0957-4484/14/10/305

10.1021/ma025521g

10.1002/adma.200390027

10.1002/(SICI)1099-0488(19991015)37:20<2845::AID-POLB4>3.0.CO;2-W

10.1063/1.1627484

 

Rodriguez J., 1997, Handbook of Organic Conductive Molecules and Polymers, 419

10.1039/b206896f

10.1002/app.13257

10.1021/ja00193a077

 

10.1039/b107499g

10.1039/b211716a

10.1021/ma035891k

10.1039/b102091i

10.1002/1099-0518(20010401)39:7<997::AID-POLA1075>3.0.CO;2-P

10.1088/0957-4484/13/6/315

10.1021/ja046359v

10.1002/marc.200400067

 

10.1016/0021-9797(71)90145-7

10.1007/BF00646118

10.1016/j.watres.2003.12.018

10.1016/j.dyepig.2004.11.003

10.1016/S0379-6779(98)80122-7

10.1103/PhysRevB.30.1023

 

10.1021/cm020206u

10.1021/cr9800816

10.1021/cr00098a012