Tính năng hấp thụ khí ethylene của nano-silica tách chiết từ rơm và công thức dựa trên PVA được phủ trên giấy góp từ gỗ mềm và rơm

Shashank Saini1, Saurabh Kumar Kardam1, Ashish A. Kadam1,2, Surendra Pratap Singh1, Vivek Kumar3, Kirtiraj K. Gaikwad1
1Department of Paper Technology, Indian Institute of Technology Roorkee, Roorkee, India
2Department of Food Technology, Koneru Lakshmaiah Education Foundation, Vaddeswaram, India
3Center for Rural Development and Technology, Indian Institute of Technology Delhi, New Delhi, India

Tóm tắt

Việc sử dụng rơm (RS) đã được chứng minh ở mức tối đa khả thi để chế tạo các sản phẩm gia tăng giá trị nhằm phục vụ cho các ứng dụng bao bì thực phẩm chủ động. Rơm được dùng làm nguyên liệu khởi đầu để chiết xuất silica tinh khiết thông qua một phương pháp tương đối xanh, tức là sử dụng tối thiểu hóa chất. Kích thước của các hạt silica nằm trong khoảng 60–80 nm. Silica được đặc trưng thêm về độ tinh khiết, thành phần và tính chất bề mặt. Đồ thị nhiễu xạ X-ray cho thấy rằng nano-silica không chứa tạp chất, cụ thể là các kim loại kiềm thổ và silicat. Một loại giấy bìa duplex được tạo ra bằng cách kẹp một tấm giấy rơm 200 g·m−2 giữa hai tấm bột gỗ mềm, mỗi tấm 50 g·m−2. Giấy bìa duplex được phủ bằng công thức nano-silica/poly(vinyl alcohol) có các tính chất rào cản, cơ học và bề mặt được cải thiện với hoạt tính hấp thụ ethylene cao hơn so với giấy bìa không có lớp phủ. Giấy bìa duplex đã được phủ có tiềm năng trở thành một sản phẩm gia tăng giá trị được chế tạo từ rơm, vốn được coi là một loại phụ phẩm nông nghiệp.

Từ khóa

#nano-silica #rơm #bao bì thực phẩm #hấp thụ ethylene #giấy bìa duplex

Tài liệu tham khảo

Kaur S, Guleria P, Sidana A, Yadav SK (2022) Efficient process for xylitol production from nitric acid pretreated rice straw derived pentosans by Candida tropicalis GS18. Biomass Bioenergy 166:106618. https://doi.org/10.1016/J.BIOMBIOE.2022.106618 Kaur D, Bhardwaj NK, Lohchab RK (2017) Prospects of rice straw as a raw material for paper making. Waste Manag 60:127–139. https://doi.org/10.1016/j.wasman.2016.08.001 Kaur D, Bhardwaj NK, Lohchab RK (2017) Prospects of rice straw as a raw material for paper making. Waste Manag 60:127–139. https://doi.org/10.1016/j.wasman.2016.08.001 Singh R, Patel M (2022) Effective utilization of rice straw in value-added by-products: A systematic review of state of art and future perspectives. Biomass Bioenergy 159:106411. https://doi.org/10.1016/J.BIOMBIOE.2022.106411 Saini S, Kadam AA, Kumar V, Gaikwad KK, Singh SP, Dutt D (2021) Conversion of rice straw into disposable food - serving bowl via refiner mechanical pulping: an environmentally benign approach to mitigate stubble burning and plastic pollution. Biomass Convers Biorefin. https://doi.org/10.1007/s13399-021-01728-y Nandiyanto ABD, Ogi T, Iskandar F, Okuyama K (2011) Highly ordered porous monolayer generation by dual-speed spin-coating with colloidal templates. Chem Eng J 167:409–415. https://doi.org/10.1016/j.cej.2010.11.077 Nandiyanto ABD, Suhendi A, Ogi T, Umemoto R, Okuyama K (2014) Size- and charge-controllable polystyrene spheres for templates in the preparation of porous silica particles with tunable internal hole configurations. Chem Eng J 256:421–430. https://doi.org/10.1016/j.cej.2014.07.005 Galliker P, Hommes G, Schlosser D, Corvini PFX, Shahgaldian P (2010) Laccase-modified silica nanoparticles efficiently catalyze the transformation of phenolic compounds. J Colloid Interface Sci 349:98–105. https://doi.org/10.1016/j.jcis.2010.05.031 Munshi S, Sharma RP (2019) Utilization of rice straw ash as a mineral admixture in construction work. Mater Today Proc 11:637–644. https://doi.org/10.1016/j.matpr.2019.03.021 Makó É, Őze C (2022) The effects of silica fume and diatomaceous earth on the mechanochemical activation and pozzolanic activity of kaolin. Appl Clay Sci 228. https://doi.org/10.1016/j.clay.2022.106636 Wei J, Gencturk B, Jain A, Hanifehzadeh M (2019) Mitigating alkali-silica reaction induced concrete degradation through cement substitution by metakaolin and bentonite. Appl Clay Sci 182:105257. https://doi.org/10.1016/j.clay.2019.105257 Bansal V, Ahmad A, Sastry M (2006) Fungus-mediated biotransformation of amorphous silica in rice husk to nanocrystalline silica. J Am Chem Soc 128:14059–14066. https://doi.org/10.1021/ja062113+ Tchanang G, Djangang CN, Abi CF, Moukouri DLM, Blanchart P (2021) Synthesis of reactive silica from kaolinitic clay: Effect of process parameters. Appl Clay Sci 207:106087. https://doi.org/10.1016/j.clay.2021.106087 Tas CE, Hendessi S, Baysal M, Unal S, Cebeci FC, Menceloglu YZ, Unal H (2017) Halloysite Nanotubes/Polyethylene Nanocomposites for Active Food Packaging Materials with Ethylene Scavenging and Gas Barrier Properties. Food Bioprocess Technol 10:789–798. https://doi.org/10.1007/s11947-017-1860-0 Coloma A, Rodríguez FJ, Bruna JE, Guarda A, Galotto MJ (2014) Development of an active film with natural zeolite as ethylene scavenger. J Chil Chem Soc 59:2409–2414. https://doi.org/10.4067/S0717-97072014000200003 Spricigo PC, Foschini MM, Ribeiro C, Corrêa DS, Ferreira MD (2017) Nanoscaled Platforms Based on SiO2 and Al2O3 Impregnated with Potassium Permanganate Use Color Changes to Indicate Ethylene Removal. Food Bioprocess Technol 10:1622–1630. https://doi.org/10.1007/s11947-017-1929-9 do Nascimento Sousa SD, Santiago RG, Soares Maia DA, de Oliveira Silva E, Vieira RS, Bastos-Neto M (2020) Ethylene adsorption on chitosan/zeolite composite films for packaging applications. Food Packag Shelf Life 26. https://doi.org/10.1016/j.fpsl.2020.100584 DeMerlis CC, Schoneker DR, López-de-Dicastillo C, Jordá M, Catalá R, Gavara R, Hernández-Muñoz P, Moore GF, Saunders SM, Roy S, Rhim J-W, Tsujiyama S, Nitta T, Maoka T (2011) Biodegradation of polyvinyl alcohol by Flammulina velutipes in an unsubmerged culture. J Agric Food Chem 112:104694. https://doi.org/10.1021/jf200749f Moore GF, Saunders SM (1998) Advances in biodegradable polymers (Vol. 98). iSmithers Rapra Publishing DeMerlis CC, Schoneker DR (2003) Review of the oral toxicity of polyvinyl alcohol (PVA). Food Chem Toxicol 41:319–326. https://doi.org/10.1300/j147v21n03_03 Lu P, Lo Hsieh Y (2012) Highly pure amorphous silica nano-disks from rice straw. Powder Technol 225:149–155. https://doi.org/10.1016/j.powtec.2012.04.002 Zaky RR, Hessien MM, El-Midany AA, Khedr MH, Abdel-Aal EA, El-Barawy KA (2008) Preparation of silica nanoparticles from semi-burned rice straw ash. Powder Technol 185:31–35. https://doi.org/10.1016/j.powtec.2007.09.012 Tappi T (2001) Tensile properties of paper and paperboard (using constant rate of elongation apparatus). Technical Association of the Pulp and Paper Industry: Peachtree Corners, GE, USA KhoshnoodMotlagh E, Asasian-Kolur N, Sharifian S (2022) A comparative study on rice husk and rice straw as bioresources for production of carbonaceous adsorbent and silica. Biomass Convers Biorefin 12:5729–5738. https://doi.org/10.1007/s13399-020-01145-7 Liu Y, Guo Y, Zhu Y, An D, Gao W, Wang Z, Ma Y, Wang Z (2011) A sustainable route for the preparation of activated carbon and silica from rice husk ash. J Hazard Mater 186:1314–1319. https://doi.org/10.1016/J.JHAZMAT.2010.12.007 Liou TH (2004) Preparation and characterization of nano-structured silica from rice husk. Mater Sci Eng A 364:313–323. https://doi.org/10.1016/j.msea.2003.08.045 Kalapathy U, Proctor A, Shultz J (2000) A simple method for production of pure silica from rice hull ash. Bioresour Technol 73:257–262. https://doi.org/10.1016/S0960-8524(99)00127-3 Siriwardena S, Ismail H, US Ishiaku (n.d.) A comparison of white rice husk ash and silica as fillers in ethylene-propylene-diene terpolymer vulcanizates. https://doi.org/10.1002/pi.691 Lv P, Almeida G, Perré P (2015) TGA-FTIR Analysis of Torrefaction of Lignocellulosic. BioResources 10:4239–4251 Kardam SK, Kadam AA, Dutt D (2021) Retention of cinnamaldehyde in poly(vinyl alcohol) films intended for preservation of faba beans through vapor-phase antimicrobial effect. Food Packag Shelf Life 29:100704. https://doi.org/10.1016/j.fpsl.2021.100704 Amutha K, Ravibaskar R, Sivakumar G (2010) Extraction, Synthesis and Characterization of Nanosilica from Rice Husk Ash. Int J Nanotechnol Appl 4:61–66. http://www.ripublication.com/ijna.htm Singh D, Kumar R, Kumar A, Rai KN (2008) Synthesis and characterization of rice husk silica, silica-carbon composite and H3PO4 activated silica. Ceramica 54:203–212. https://doi.org/10.1590/S0366-69132008000200011 Kauldhar BS, Yadav SK (2018) Turning waste to wealth: A direct process for recovery of nano-silica and lignin from paddy straw agro-waste. J Clean Prod 194:158–166. https://doi.org/10.1016/j.jclepro.2018.05.136 Premaratne WAPJ, Priyadarshana WMGI, Gunawardena SHP, De Alwis AAP (2013) Synthesis of nanosilica from paddy husk ash and their surface functionalization. J Sci Univ Kelaniya 8:33–48 Thommes M, Kaneko K, Neimark AV, Olivier JP, Rodriguez-Reinoso F, Rouquerol J, Sing KSW (2015) Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report). Pure Appl Chem 87:1051–1069. https://doi.org/10.1515/pac-2014-1117 KhoshnoodMotlagh E, Asasian-Kolur N, Sharifian S, EbrahimianPirbazari A (2021) Sustainable rice straw conversion into activated carbon and nano-silica using carbonization-extraction process. Biomass Bioenergy 144:105917. https://doi.org/10.1016/j.biombioe.2020.105917 Yuvakkumar R, Elango V, Rajendran V, Kannan N (2014) High-purity nano silica powder from rice husk using a simple chemical method. J Exp Nanosci 9:272–281. https://doi.org/10.1080/17458080.2012.656709 Kumar A, Gupta V, Singh S, Saini S, Gaikwad KK (2021) Pine needles lignocellulosic ethylene scavenging paper impregnated with nanozeolite for active packaging applications. Ind Crops Prod 170:113752. https://doi.org/10.1016/j.indcrop.2021.113752 Sothornvit R, Sampoompuang C (2012) Rice straw paper incorporated with activated carbon as an ethylene scavenger in a paper-making process. Int J Food Sci Technol 47:511–517. https://doi.org/10.1111/j.1365-2621.2011.02871.x Jani SM, Rushdan I (2016) Mechanical properties of beating pulp and paper from rice straw. J Trop Agric Fd Sc 44:103–109 Pettersson G, Höglund H, Norgren S, Sjöberg J, Peng F, Hallgren H, Moberg A, Ljungqvist CH, Bergström J, Solberg D (2015) Strong and bulky paperboard sheets from surface modified CTMP, manufactured at low energy. Nord Pulp Paper Res J 30:319–325. https://doi.org/10.3183/npprj-2015-30-02-p319-325 Shen Z, Rajabi-Abhari A, Oh K, Yang G, Youn HJ, Lee HL (2021) Improving the barrier properties of packaging paper by polyvinyl alcohol based polymer coating—effect of the base paper and nanoclay. Polymers (Basel) 13. https://doi.org/10.3390/polym13081334 Dias VM, Kuznetsova A, Tedim J, Yaremchenko AA, Zheludkevich ML, Portugal I, Evtuguin DV (2015) Silica-Based Nanocoating Doped by Layered Double Hydroxides to Enhance the Paperboard Barrier Properties. World J Nano Sci Eng 05:126–139. https://doi.org/10.4236/wjnse.2015.54015 Hellström P, Heijnesson-Hultén A, Paulsson M, Håkansson H, Germgård U (2014) Fenton pre-treated microfibrillated cellulose evaluated as a strength enhancer in the middle ply of paperboard. Nord Pulp Paper Res J 29:732–740. https://doi.org/10.3183/npprj-2014-29-04-p732-740 Yenidoğan S (2020) Nanocrystalline cellulose and polyvinyl alcohol coating application to cardboard packaging papers and investigation of the effects on paper properties. Mater Sci 26(3):317–322 Yousefhashemi SM, Khosravani A, Yousefi H (2019) Isolation of lignocellulose nanofiber from recycled old corrugated container and its interaction with cationic starch – nanosilica combination to make paperboard. Cellulose 26:7207–7221. https://doi.org/10.1007/s10570-019-02562-2 Dutt D, Lal M, Malik RS, Upadhyay MK (2005) Development of specialty papers is an art: Seed germination paper from indigenous raw materials - Part XIII. J Sci Ind Res (India) 64:440–442 Ni Y, Yi J (2019) Research on improving the surface hydrophobicity of paper coated by poly-vinyl alcohol -itaconic acid grafting copolymer. Prog Org Coatings 131:152–158. https://doi.org/10.1016/j.porgcoat.2019.02.006 Liu Q, Lv Y, Li J, Xu W (2011) Study on application of nanosilica in paper coating. Adv Mater Res 311–313:502–506. https://doi.org/10.4028/www.scientific.net/AMR.311-313.502