Ester‐Directed Selective Olefination of Acrylates by Rhodium Catalysis

Advanced Synthesis and Catalysis - Tập 356 Số 7 - Trang 1501-1508 - 2014
Ruokun Feng1, Wenlong Yu1, Kai Wang1, Zhanxiang Liu1, Yuhong Zhang2,3
1Department of Chemistry, ZJU‐NHU United R&D Center, Zhejiang University, Hangzhou 310027, People's Republic of China, Fax: (+86)‐571‐8795‐3244
2Department of Chemistry, ZJU-NHU United R&D Center, Zhejiang University, Hangzhou 310027, People's Republic of China, Fax: (+86)-571-8795-3244
3State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, People's Republic of China

Tóm tắt

AbstractEster‐directed olefination of acrylates via rhodium(III)‐catalysis was developed. Various alkenes were reacted with acrylates to give the desired products in high stereoselectivity. Mechanistic investigations revealed that ester‐directed CH bond activation was the key step to this reaction.magnified image

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Tài liệu tham khảo

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Advanced Synthesis and Catalysis

Tập 356 Số 7

1501-1508

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