Enthalpy and entropy changes on molecular inclusion of pentane derivatives into α-cyclodextrin cavities in aqueous solutions

Journal of inclusion phenomena - Tập 70 - Trang 269-278 - 2010
Takayoshi Kimura1, Satoshi Fujie1, Takashi Yukiyama1, Masao Fujisawa1, Tadashi Kamiyama1, Hatsumi Aki2
1Department of Chemistry, Kinki University, Higashi-osaka, Japan
2Faculty of Pharmaceutical Science, Fukuoka University, Fukuoka, Japan

Tóm tắt

In order to investigate the contribution of the hydrophilic parts of guest molecules of aliphatic compounds to the inclusion reaction, the thermodynamic properties of inclusion compounds of cyclodextrin (α-CD) with eight pentane derivatives into the cavity of α-CD in dilute aqueous solutions were measured by micro-calorimeter at 298.15 K. The thermodynamic properties of the inclusion reactions of pentane derivatives into α-CD were compared to the hydrophobicity and polarizability of guest molecules and discussed. The interaction energies of inclusion compounds of α-CD and pentane derivatives were determined by DFT calculation (B3LYP/6-31G (d,p)) in water and compared with the experimental results.

Tài liệu tham khảo

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