Enhancing low-temperature electrochemical kinetics and high-temperature cycling stability by decreasing ionic packing factor

Liu, 2022, Origin of structural degradation in Li-rich layered oxide cathode, Nature, 606, 305, 10.1038/s41586-022-04689-y Zhang, 2020, Kinetic pathways of ionic transport in fast-charging lithium titanate, Science, 367, 1030, 10.1126/science.aax3520 Griffith, 2018, Niobium tungsten oxides for high-rate lithium-ion energy storage, Nature, 559, 556, 10.1038/s41586-018-0347-0 Schmuch, 2018, Performance and cost of materials for lithium-based rechargeable automotive batteries, Nat. Energy, 3, 267, 10.1038/s41560-018-0107-2 Feng, 2022, Challenges and advances in wide-temperature rechargeable lithium batteries, Energy Environ. Sci., 15, 1711, 10.1039/D1EE03292E Li, 2021, Multiphase, multiscale chemomechanics at extreme low temperatures: battery electrodes for operation in a wide temperature range, Adv. Energy Mater., 11 Liu, 2021, In situ observation of thermal-driven degradation and safety concerns of lithiated graphite anode, Nat. Commun., 12, 4235, 10.1038/s41467-021-24404-1 Masias, 2021, Opportunities and challenges of lithium ion batteries in automotive applications, ACS Energy Lett., 6, 621, 10.1021/acsenergylett.0c02584 Jaguemont, 2016, A comprehensive review of lithium-ion batteries used in hybrid and electric vehicles at cold temperatures, Appl. Energy, 164, 99, 10.1016/j.apenergy.2015.11.034 Chen, 2021, Electrochemical energy storage devices working in extreme conditions, Energy Environ. Sci., 14, 3323, 10.1039/D1EE00271F Zhang, 2022, Critical review on low-temperature Li-ion/metal batteries, Adv. Mater., 34 Kim, 2020, Operando identification of the chemical and structural origin of Li-ion battery aging at near-ambient temperature, J. Am. Chem. Soc., 142, 13406, 10.1021/jacs.0c02203 Collins, 2021, Alternative anodes for low temperature lithium-ion batteries, J. Mater. Chem. A, 9, 14172, 10.1039/D1TA00998B Hou, 2020, Fundamentals and challenges of lithium ion batteries at temperatures between −40 and 60 °C, Adv. Energy Mater., 10 Choi, 2017, Mesoporous germanium anode materials for lithium-ion battery with exceptional cycling stability in wide temperature range, Small, 13, 10.1002/smll.201603045 Collins, 2021, Alloying germanium nanowire anodes dramatically outperform graphite anodes in full-cell chemistries over a wide temperature range, ACS Appl. Energy Mater., 4, 1793, 10.1021/acsaem.0c02928 Tian, 2019, Quantifying the factors limiting rate performance in battery electrodes, Nat. Commun., 10, 1933, 10.1038/s41467-019-09792-9 Song, 2014, Tailored oxygen framework of Li4Ti5O12 nanorods for high-power Li ion battery, J. Phys. Chem. Lett., 5, 1368, 10.1021/jz5002924 Kang, 2006, Factors that affect Li mobility in layered lithium transition metal oxides, Phys. Rev. B, 74, 10.1103/PhysRevB.74.094105 Kang, 2006, Electrodes with high power and high capacity for rechargeable lithium batteries, Science, 311, 977, 10.1126/science.1122152 Deng, 2022, Selective doping to controllably tailor maximum unit-cell-volume change of intercalating Li+-storage materials: a case study of γ phase Li3VO4, Adv. Sci., 9, 10.1002/advs.202106003 Callister, 2000 Jiang, 2022, Partially reduced titanium niobium oxide: a high-performance lithium-storage material in a broad temperature range, Adv. Sci., 9, 10.1002/advs.202105119 Wang, 2022, Conductive LaCeNb6O18 with a very open A-site-cation-deficient perovskite structure: a fast- and stable-charging Li+-storage anode compound in a wide temperature range, Adv. Energy Mater., 12 Shannon, 1976, Revised effective ionic radii and systematic studies of interatomic distances in dalides and chalcogenides, Acta Crystallogr. Sect. A, 32, 751, 10.1107/S0567739476001551 Toby, 2001, EXPGUI, a graphical user interface for GSAS, J. Appl. Crystallogr., 34, 210, 10.1107/S0021889801002242 Rietveld, 2014, The Rietveld method, Phys. Scripta, 89, 10.1088/0031-8949/89/9/098002 Pinus, 2014, Neutron diffraction and electrochemical study of FeNb11O29/Li11FeNb11O29 for lithium battery anode applications, Chem. Mater., 26, 2203, 10.1021/cm500442j Norin, 1963, The crystal structure of Nb12O29 (o-rh), Acta Chem. Scand., 17, 1391, 10.3891/acta.chem.scand.17-1391 Lou, 2017, Exploration of Cr0.2Fe0.8Nb11O29 as an advanced anodematerial for lithium-ion batteries of electric vehicles, Electrochim. Acta, 245, 474, 10.1016/j.electacta.2017.05.168 Yang, 2017, Cr3+ and Nb5+ co-doped Ti2Nb10O29 materials for high-performance lithium-ion storage, J. Power Sources, 360, 470, 10.1016/j.jpowsour.2017.06.026 Yang, 2016, Cu0.02Ti0.94Nb2.04O7: an advanced anode material for lithium-ion batteries of electric vehicles, J. Power Sources, 328, 336, 10.1016/j.jpowsour.2016.08.027 Fu, 2020, A low-strain V3Nb17O50 anode compound for superior Li+ storage, Energy Stor. Mater., 30, 401 Li, 2021, Mo3Nb14O44: a new Li+ container for high-performance electrochemical energy storage, Energy Environ. Mater., 4, 65, 10.1002/eem2.12098 Fu, 2020, A highly Li+-conductive HfNb24O62 anode material for superior Li+ storage, Chem. Commun., 56, 619, 10.1039/C9CC07447C Lv, 2022, Rational design and synthesis of nickel niobium oxide with high-rate capability and cycling stability in a wide temperature range, Adv. Energy Mater., 12, 10.1002/aenm.202102550 Li, 2018, Conductive Nb25O62 and Nb12O29 anode materials for use in high-performance lithium-ion storage, Electrochim. Acta, 266, 202, 10.1016/j.electacta.2018.02.034 Zhu, 2019, MoNb12O33 as a new anode material for high-capacity, safe, rapid and durable Li+ storage: structural characteristics, electrochemical properties and working mechanisms, J. Mater. Chem. A, 7, 6522, 10.1039/C9TA00309F Lou, 2018, GaNb11O29 nanowebs as high-performance anode materials for lithium-ion batteries, ACS Appl. Nano Mater., 1, 183, 10.1021/acsanm.7b00091 Fu, 2019, Design, synthesis and lithium-ion storage capability of Al0.5Nb24.5O62, J. Mater. Chem. A, 7, 19862, 10.1039/C9TA04644E Allen, 2006, Low temperature performance of nanophase Li4Ti5O12, J. Power Sources, 159, 1340, 10.1016/j.jpowsour.2005.12.039 Pohjalainen, 2015, Effect of Li4Ti5O12 particle size on the performance of lithium ion battery electrodes at high C-rates and low temperatures, J. Phys. Chem. C, 119, 2277, 10.1021/jp509428c Marinaro, 2011, Low temperature behaviour of TiO2 rutile as negative electrode material for lithium-ion batteries, J. Power Sources, 196, 9825, 10.1016/j.jpowsour.2011.07.008 Ma, 2022, VPO5: an all-climate lithium-storage material, Energy Stor. Mater., 46, 366 Bard, 2001