Emission Mössbauer spectroscopy of grain boundaries in polycrystalline molybdenum
Tóm tắt
Grain boundaries in polycrystalline molybdenum have been studied by emission Mössbauer spectroscopy on 57Co (57Fe) nuclei. It has been shown that Co atoms diffuse along the grain boundaries by the interstitial mechanism. The states of Co atoms in grain boundaries and in near-boundary regions of the crystallites have been analyzed. The values of the effective diffusion coefficient in the subboundary regions of the crystallites have been estimated. The temperature dependence of the grain-boundary segregation factor of Co in Mo has been determined.
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