Elution of leachable components from composites

Journal of Oral Rehabilitation - Tập 21 Số 4 - Trang 441-452 - 1994
Jack L. Ferracane1
1Dental Materials Science, Oregon Health Sciences University, Portland 97201.

Tóm tắt

SummaryA significant amount of residual monomer or short chain polymers remain unbound in set composite material. Due to its potential impact on both the biocompatibility and the structural stability of the restoration, many investigators have studied the elution of these unbound molecules into aqueous media. The results of these studies suggest that elution of leachable components from composites is rapid, with the majority being released within a matter of hours. Weight losses of up to 2% of the mass of the composite have been reported under certain conditions. The studies have also shown that the extent and rate of elution of components from composites is dependent upon several factors. The quantity of leachables has been correlated to the degree of cure of the polymer network. The composition and solubility characteristics of the extraction solvent influence the kinetics and mechanism of the elution process. Elution is generally thought to occur via diffusion of molecules through the resin matrix, and is therefore dependent upon the size and chemical characteristics of the leachable species.

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Tài liệu tham khảo

10.1177/00220345760550050501

10.1016/0300-5712(81)90088-9

10.1016/S0109-5641(05)80012-0

10.1016/0109-5641(92)90102-I

Freund M., 1990, Enzymatic degradation of Bis‐GMA/TEGDMA‐polymers causing decreased microhardness and greater wear, in vitro. Scandinavian Journal of Dental Research, 98, 351

10.1016/0022-3913(90)90293-L

10.1111/j.1365-2842.1982.tb01039.x

10.1016/0109-5641(90)90037-F

Larsen I.B., 1991, Effect of human saliva on surface degradation of composite resins, Scandinavian Journal of Dental Research, 99, 254

Munksgaard E.C., 1990, Enzymatic hydrolysis of (di) methacrylates and their polymers, Scandinavian Journal of Dental Research, 98, 261

10.1016/0003-9969(86)90092-0

10.1177/00220345860650110601

10.1177/00220345880670100901

10.1016/0300-5712(79)90041-1

10.1111/j.1365-2842.1989.tb01317.x

Pham D.C., 1989, Early elution of uncured components from light‐activated composites, Journal of Dental Research, 68, 207

10.1002/jbm.820250403

10.1177/00220345880670060801

Ruyter I.E., 1985, Posterior Composite Resin Dental Restorative Materials, 109

10.1002/jbm.820210107

10.1177/00220345830620020801

Soderholm K.‐J.M., 1990, Filler leachability during water storage of six composite materials, Scandinavian Journal of Dental Research, 98, 82

10.1177/00220345840630101701

Spahl W., 1991, Eine untersuchung zum restmonomerund additivagehalt verschiedener lichthärtender hybridkomposite, Deutsche Zahnarztliche Zeitschrift, 46, 471

10.1111/j.1365-2842.1991.tb00067.x

10.1177/00220345820610081501

Wu W., 1982, Influences of chemical on wear of dental composites, Journal of ental Research, 61, 1180

Yourtee D., 1992, Evaluation of polymeric restoratives and components as enzyme substrates, Journal of Dental Research, 71, 277