Electrospinning: A Fascinating Method for the Preparation of Ultrathin Fibers
Tóm tắt
Electrospinning is a highly versatile method to process solutions or melts, mainly of polymers, into continuous fibers with diameters ranging from a few micrometers to a few nanometers. This technique is applicable to virtually every soluble or fusible polymer. The polymers can be chemically modified and can also be tailored with additives ranging from simple carbon‐black particles to complex species such as enzymes, viruses, and bacteria. Electrospinning appears to be straightforward, but is a rather intricate process that depends on a multitude of molecular, process, and technical parameters. The method provides access to entirely new materials, which may have complex chemical structures. Electrospinning is not only a focus of intense academic investigation; the technique is already being applied in many technological areas.
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Tài liệu tham khảo
G. M. Bose Recherches sur la cause et sur la véritable théorie de l'électricité Wittenberg 1745.
J. F.Cooley US 692 631 1902.
W. J.Morton US 705 691 1902.
J. F.Cooley US 745 276 1903.
W.Simm K.Gosling R.Bonart B.von Falkai GB 1346231 1972.
Jacobsen M., 1991, Chemiefasern/Textilind., 36
Doshi J., 1995, Polym. News, 20, 206
Hagewood J., 2003, Nonwovens World, 69
Dersch R., 2004, Dekker Encyclopedia of Nanoscience and Nanotechnology, 2931
Raagavan N. N. V., 2005, Synth. Fibres, 34, 16
1985, High‐Speed Fiber Spinning: Science and Engineering Aspects
Z. Jun H. Hou J. H. Wendorff A. Greiner e‐Polymers2005 No. 38.
Yang Q.‐B., 2004, Gaodeng Xuexiao Huaxue Xuebao, 25, 589
Kang Y.‐S., 2002, Polymer (Korea), 26, 360
J. Zeng H. Hou A. Schaper J. H. Wendorff A. Greiner e‐Polymers2003 No. 9.
Jeun J. P., 2005, J. Ind. Eng. Chem. (Seoul), 11, 573
Lee B., 2003, J. Korean Fiber Soc., 40, 341
Tsai P., 2003, Adv. Filtr. Sep. Technol., 16, 340
Levit N., 2004, J. Supercrit. Fluids, 3, 1
Kim H.‐J., 2004, J. Korean Fiber Soc., 41, 424
Rangkupan R., 2003, J. Met. Mater. Miner., 12, 81
M. Becker Dissertation Philipps‐Universität Marburg.
C. Zhang X. Yuan L. Wu L. Wu J. Sheng e‐Polymers2005 No. 72.
M. Spasova N. Manolova D. Paneva I. Rashkov e‐Polymers2004 No. 56.
Graham N. B., 1986, Hydrogels in Medicine and Pharmacy, Vol. II, 96
Marten F. L., 1992, Polyvinyl Alcohol: Developments
J. Zeng H. Hou J. H. Wendorff A. Greiner e‐polymers2004 No. 78.
Ding B., 2004, Chem. Sens., 264
Lee D. Y., 2006, J. Korean Phys. Soc., 48, 1686
1997, Handbook of Biodegradable Polymers
Chun I., 1998, Int. SAMPE Symp. Exhib., 43, 718
Schreuder‐Gibson H. L., 2004, Int. Nonwovens J., 13, 39
Tsai P. P., 2004, Int. Nonwovens J., 13, 17
Peebles L. E., 1995, Carbon Fibers: Formation, Structure, and Properties, 7
Suthar A., 2001, Tce, 726, 26
S. L.Kwolek US 3600 350 1971.
Lee S.‐G., 2002, J. Korean Fiber Soc., 39, 1
Schreuder‐Gibson H. L., 2002, J. Adv. Mater., 34, 44
Kim Y. K., 2004, J. Korean Fiber Soc., 41, 30
M. Becker A. Greiner unpublished results.
Photograph by R. Dersch.
Ristolainen N., 2006, Macromol. Mater. Eng., 2
O. Kriha M. Becker M. Lehmann D. Kriha J. Krieglstein M. Yosef S. Schlecht R. Wehrspohn J. H. Wendorff A. Greiner Adv. Mater. in press.
Shao C‐ L., 2004, Chin. Chem. Lett., 15, 365
Shao C. L., 2004, Chin. Chem. Lett., 15, 471
Gouma P. I., 2003, Rev. Adv. Mater. Sci., 5, 147
Li S., 2006, J. Phys. Mater. Res., 67, 1869
Shao C. L., 2004, Chin. Chem. Lett., 15, 492
Shi T.‐J., 2005, Gaodeng Xuexiao Huaxue Xuebao, 26, 2373
Wunderlich B., 1973, Macromolecular Physics, Vol. 1
Lin D. Y., 2003, Polym. Prepr. Am. Chem. Soc. Div. Polym. Chem., 44, 70
A. Holzmeister Diplomarbeit Philipps‐Universität Marburg2006.
Lee S.‐H., 2005, Mater. Sci., 398, 77
Sun Z., 2005, Prog. Colloid Polym. Sci., 130, 15
Emig G., 2005, Technische Chemie. Einführung in die Chemische Reaktionstechnik
M. Graeser Diplomarbeit Philipps‐Universität Marburg 2004.
M. Stasiak A. Studer A. Greiner J. H. Wendorff Eur. Polym. J. in press.
M. Stasiak A. Studer A. Greiner J. H. Weendorff Polymer submitted.
1988, Fibre Reinforcements for Composite Materials
1993, Material Science and Technology, Vol. 13
Wu S., 1982, Polymer Interfaces and Adhesion
Y. A.Dzenis D. H.Reneker US 626 533 2001.
Li S., 1995, The Biomedical Engineering Handbook, 627
Kohn J., 1996, Biomaterials Science: An Introduction to Materials in Medicine, 64
Alberts B., 1994, Molecular Biology of the Cell, 971
Khil M.‐S., 2004, J. Biomed. Mater. Res. Part B, 72, 117
Li W.‐J., 2004, Biomaterials, 26
Lim T. C., 2005, Nanotechnology: Global Strategies, Industry Trends and Applications
R. A.Coffee PCT/GB97/01968 1998.
Martindale D., 2000, Sci. Am., 282, 34
Kenawy E. R., 2002, Polym. Prepr. Am. Chem. Soc. Div. Polym. Chem., 43, 457
D.Smith D. H.Reneker PCT/US00/27737 2001.
Brewster K. E., 2004, Pharmazie, 59, 387