Electronic structure and electrical properties of interfaces between metals and π‐conjugated molecular films

Journal of Polymer Science, Part B: Polymer Physics - Tập 41 Số 21 - Trang 2529-2548 - 2003
Antoine Kahn1, Norbert Koch2, Weiying Gao1
1Department of Electrical Engineering, Princeton University, Princeton, New Jersey, 08544
2Physik von Makromolekülen, Institut für Physik, Humboldt‐Universität zu Berlin, Newtonstrasse 15, D‐12489 Berlin, Germany

Tóm tắt

AbstractThe field of organic thin films and devices is progressing at an extremely rapid pace. Organic–metal and organic–organic interfaces play crucial roles in charge injection into, and transport through, these devices. Their electronic structure, chemical properties, and electrical behavior must be fully characterized and understood if the engineering and control of organic devices are to reach the levels obtained for inorganic semiconductor devices. This article provides an extensive, although admittedly nonexhaustive, review of experimental work done in our group on the electronic structure and electrical properties of interfaces between films of π‐conjugated molecular films and metals. It introduces several mechanisms currently believed to affect the formation of metal–organic interface barriers. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 2529–2548, 2003

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Journal of Polymer Science, Part B: Polymer Physics

Tập 41 Số 21

2529-2548

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