Electrolytic binary metal-oxide compounds: Fundamental peculiarities of their structure and formation

Surface Engineering and Applied Electrochemistry - Tập 49 - Trang 368-372 - 2013
V. M. Nagirnyi1, R. D. Apostolova1, S. V. Petrichenko1
1Ukrainian State Chemical Engineering University, Dnepropetrovsk, Ukraine

Tóm tắt

Based on the experimental results and the data published in the literature, the specific features and qualitative distinctions of electrolytic binary metal-oxide systems (such as V-Mn, Co-Ni, Co-Cr, Mn-Ni, and Mn-Cr) from the individual oxides contained in them are studied. In a binary system, these oxides react to form a complex structurally homogeneous conglomerate. The precipitates of the binary compounds are characterized by a fine-grained close-packed structure of mainly columnar (filamentous) type, which results from the mutual suppression of the growth of the basic and alloying metal-oxide components.

Tài liệu tham khảo

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