Khôi phục tellurium bằng phương pháp điện hóa từ chất thải công nghiệp luyện kim

Journal of Applied Electrochemistry - Tập 50 - Trang 1-14 - 2019
Petteri Halli1, Benjamin P. Wilson1, Taye Hailemariam1, Petri Latostenmaa2, Kirsi Yliniemi3, Mari Lundström1
1Department of Chemical and Metallurgical Engineering (CMET), Hydrometallurgy and Corrosion, School of Chemical Engineering, Aalto University, Aalto, Finland
2Boliden Harjavalta, Harjavalta, Finland
3Department of Chemistry and Materials Science (CMAT), School of Chemical Engineering, Aalto University, Aalto, Finland

Tóm tắt

Nghiên cứu hiện tại phác thảo quá trình khôi phục điện hóa tellurium từ phần chất thải của nhà máy luyện kim, cụ thể là xỉ Doré. Tại nhà máy kim loại quý, tellurium được giàu hóa vào xỉ lò TROF (Tilting, Rotating Oxy Fuel) và do đó được coi là một nguồn tài nguyên bị mất — mặc dù xỉ vẫn chứa một lượng tellurium có thể khôi phục được. Để khôi phục Te, xỉ trước tiên được ngâm trong nước cường toan, tạo ra dung dịch استخراج nhiều kim loại (PLS) với 421 ppm Te và các yếu tố hòa tan chiếm ưu thế là Na, Ba, Bi, Cu, As, B, Fe và Pb (trong khoảng từ 1.4 đến 6.4 g dm−3), cũng như các yếu tố vi lượng ở quy mô ppb đến ppm. Việc tiếp xúc của xỉ với dung dịch giàu chloride cho phép hình thành phức chloride đồng và do đó, giảm khả năng khử của đồng nguyên tố. Điều này cho phép tăng cường tính chọn lọc trong quá trình khôi phục điện hóa Te. Các kết quả cho thấy rằng điện thắng (EW) là phương pháp khôi phục Te ưa thích ở nồng độ trên 300 ppm, trong khi ở nồng độ thấp hơn EDRR được ưu tiên. Độ tinh khiết của tellurium đã khôi phục được nghiên cứu bằng SEM-EDS (kính hiển vi điện tử quét - quang phổ phân tán năng lượng). Dựa trên nghiên cứu, một quy trình khôi phục điện hóa hai giai đoạn mới kết hợp để thu hồi tellurium từ PLS xỉ Doré được đề xuất: EW được theo sau bởi EDRR.

Từ khóa


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