Electrochemical Study of Spark Plasma-Sintered Copper Reinforced with Ni/SiC Micron-Sized Particles for Electrical Applications

K. Machethe1, A. P. I. Popoola1, V. S. Aigbodion1, O. M. Popoola2
1Department of Chemical, Metallurgical & Materials Engineering, Tshwane University of Technology, Pretoria, South Africa
2Department of Electrical Engineering, Tshwane University of Technology, Pretoria, South Africa

Tóm tắt

In the research study, incorporation of Cu with hard SiC and Ni micron-sized particles was applied in the fabrication of a multifunctional copper-based metal matrix composite using spark plasma sintering. The developed spark plasma-sintered Cu–xNi and Cu–xNi–xSiC composite charateristics were studied by conducting morphological analysis, electrochemical, microhardness, and densification tests. Analytical equipments used include scanning electron microscopy, equipped elemental dispersive spectroscopy, X-ray diffractometry, and Vickers hardness tester. Electrochemical characterizations using potentiodynamic polarization for the electrochemical stability of the sintered composite in 0.5 M H2SO4 was also carried out. 96% densification and 90.20% corrosion resistance were obtained. The Cu–Ni composite showed an increase in corrosion resistance as a result of Ni addition in H2SO4 environment, while Cu–xNi–xSiC composite showed a slight decrease in corrosion resistance with excess SiC. It can be inferred that Cu–xNi and Cu–NixSiC composites improves the hardness values and corrosion resistance for electrical application when applied.

Tài liệu tham khảo

Allan RN, Billinton R, Breipohl AM, Grigg CH (1999) Bibliography on the application of probability methods in power system reliability evaluation. IEEE Trans Power Syst 14(1):51–57 Diouf S, Menapace C, D’Incau M, Molinari A, Ischia G (2013) Spark plasma sintering of cryomilled copper powder. Powder Metall 56(5):420–426 Durowoju MO, Sadiku ER, Diouf S, Shongwe MB, Olubambi PA (2015) Spark plasma sintering of graphite–aluminum powder reinforced with SiC/Si particles. Powder Technol 284:504–513 Guerrero JM, Hang L, Uceda J (2008) Control of distributed uninterruptible power supply systems. IEEE Trans Ind Electron 55(8):2845–2859 Kwok CT, Wong PK, Man HC, Cheng FT (2010) Sliding wear and corrosion resistance of copper-based overhead catenary for traction systems. Int J Railw 3(1):19–27 Lukianova OA, Novikov VY, Parkhomenko AA, Sirota VV, Krasilnikov VV (2017) Microstructure of spark plasma-sintered silicon nitride ceramics. Nanoscale Res Lett 12:293 Mamedov V (2002) Spark plasma sintering as advanced PM sintering method. Powder Metall 45(4):322–328 Miranzo P, Ramírez C, Román-Manso B, Garzón L, Gutiérrez HR, Terrones M, Ocal C, Osendi MI, Belmonte M (2013) In situ processing of electrically conducting graphene/SiC nanocomposites. J Eur Ceram Soc 33(10):1665–1674 Molina A, Torres-Islas A, Serna S, Acosta-Flores M, Rodriguez-Diaz RA, Colin J (2015) Corrosion, electrical and mechanical performance of copper matrix composites produced by mechanical alloying and consolidation. Int J Electrochem Sci 10:1728–1741 Shijie Z, Bingjun Z, Zhen Z, Xin J (2006) Application of lanthanum in high strength and high conductivity copper alloys. J Rare Earths 24(1):385–388 Singh IB, Mandal DP, Singh M, Das S (2009) Influence of SiC particles addition on the corrosion behavior of 2014 Al–Cu alloy in 3.5% NaCl solution. Corros Sci 51(2):234–241 Su H, Tang X, Zhang H, Jing Y, Bai F, Zhong Z (2013) Low-loss NiCuZn ferrite with matching permeability and permittivity by two-step sintering process. J Appl Phys 113(17):17B301 Suganuma K, Kim SJ, Kim KS (2009) High-temperature lead-free solders: properties and possibilities. J Miner Metals Mater Soc 61(1):64–71 Ullbrand JM, Córdoba JM, Tamayo-Ariztondo J, Elizalde MR, Nygren M (2010) Thermomechanical properties of copper-carbon nanofibre composites prepared by spark plasma sintering and hot pressing. Compos Sci Technol 70(16):2263–2268 Vollertsen F, Partes K, Meijer J (2005) State of the art of laser hardening and cladding. WLT-conference on lasers in man. Munich Zhu Congxu, Wang Chan, Lang Jing, Ma Yi, Ma Nangang (2013) Si-coated diamond particles reinforced copper composites fabricated by spark plasma sintering process. Mater Manuf Process 28(2):143–147