Electrochemical Behavior Investigation of Cysteine on Nickel Corrosion in Acidic Medium
Tóm tắt
The corrosion inhibition of nickel in 0.5 M H2SO4 by cysteine was investigated with various electrochemical methods and surface observations by SEM. The cyclic voltammetry revealed that the current density is the highest in absence of the cysteine and decreases with increasing inhibitor concentration. The cysteine is an anodic inhibitor. The polarization and electrochemical impedance spectroscopy showed that the cysteine has a poor inhibitive effect. The surface observation by scanning electron microscope corroborates the addition of cysteine has no significant improvement of the surface morphology of nickel electrode in 0.5 M H2SO4. Results obtained by different methods corroborate each other.
Tài liệu tham khảo
P.A. Selembo, M.D. Merrill, B.E. Logan, The use of stainless steel and nickel alloys as low-cost cathodes in microbial electrolysis cells. J. Power Sour 190, 271–278 (2009)
J.C. Grant, Nickel–Cadmium Battery Application Engineering Handbook, 3rd edn. (General Electric Company, Gainesville, 1975)
U.C. Nwaogu, C. Blawert, N. Scharnagl, W. Dietzel, K.U. Kainer, Influence of inorganic acid pickling on the corrosion resistance of magnesium alloy AZ31 sheet. Corros. Sci. 51, 2544–2556 (2009)
K.F. Khaled, Molecular modeling and electrochemical investigations of the corrosion inhibition of nickel using some thiosemicarbazone derivatives. J. Appl. Electrochem. 41, 423–433 (2011)
A.A. Aksüt, S. Bilgiç, The effect of amino acids on the corrosion of nickel in H2SO4. Corros. Sci. 33, 379–387 (1992)
T. Arslan, F. Kandemirli, E.E. Ebenso, I. Love, H. Alemu, Quantum chemical studies on the corrosion inhibition of some sulphonamides on mild steel in acidic medium. Corros. Sci. 51, 35 (2009)
B.G. Ateya, M.B. Abo El-Khair, I.A. Abdel Hamed, Thiosemicarbazide as an inhibitor for the acid corrosion of iron. Corros. Sci. 16, 163–169 (1976)
H. Shokrya, E.M. Mabrouk, Computational and electrochemical investigation for corrosion inhibition of nickel in molar sulfuric acid by dihydrazide derivatives. Part II. Arab. J. Chem. 10, S3402–S3411 (2017)
C.F. Zinola, A.M. Castro Luna, The inhibition of Ni corrosion in H2S04 solutions containing simple non-saturated substances. Corros. Sci. 37, 1919–1929 (1995)
A. Samide, I. Bibicu, A new inhibitor for corrosion of carbon steel in hydrochloric acid solution. Rev. Roum. Chim. 54, 33–43 (2009)
P.C. Okafor, C.B. Liu, X. Liu, Y.G. Zheng, F. Wang, C.Y. Liu, F. Wangm, Corrosion inhibition and adsorption behavior of imidazoline salt on N80 carbon steel in CO2-saturated solutions and its synergism with thiourea. J. Solid State Electrochem. 14, 1367–1376 (2010)
S. Gowri, J. SathiyabamA, S. Rajendran, Corrosion inhibition by amino acids—an over review. Eur. Chem. Bull. 11, 470–476 (2012)
H. El Attari, K. Chefira, M. Siniti, A. El Kihel, H. Rchid, Adsorption and corrosion inhibition performance of 1,3-dihydro-2Hbenzimidazole-2-thione for mild steel C35 E in sulfuric acid solution. Int. J. Recent Trends Eng. Res. (IJRTER) 03, 2455–2457 (2017)
H.I. Taleb, A.Z. Mohamed, Corrosion inhibition of mild steel using fig leaves extract in hydrochloric acid solution. Int. J. Electrochem. Sci. 6, 6442–6455 (2011)
M. Bethencourt, F.J. Botana, J.J. Calvino, M. Marcosm, Lanthanide compounds as environmentally-friendly corrosion inhibitors of aluminium alloys. Corros. Sci. 40, 1803–1819 (1998)
M.A. Arenas, A. Conde, J.J. De Damborenea, Cerium: a suitable green corrosion inhibitor for tinplate. Corros. Sci. 44, 511–520 (2002)
S.M. El-Sawy, Y.M. Abu-Ayana, F.A. Abdel-Mohdy, Some chitin/chitosan derivatives for corrosion protection and waste water treatments. Anticorros. Methods Mater. 48, 227–235 (2001)
P.B. Raja, M.G. Sethuraman, Natural products as corrosion inhibitor for metals in corrosive media (a review). Mater. Lett. 62, 113–116 (2008)
H. Tian, W. Li, K. Cao, B. Hou, Potent inhibition of copper corrosion in neutral chloride media by novel non-toxic thiadiazole derivatives. Corros. Sci. 73, 281–291 (2013)
G. Moretti, F. Guidi, G. Grion, Tryptamine as a green iron corrosion inhibitor in 0.5 M deaerated sulphuric acid. Corros. Sci. 46, 387 (2004)
G. Moretti, F. Guidi, Tryptophan as copper corrosion inhibitor in 0.5 M aerated sulfuric acid. Corros. Sci. 44, 1995–2011 (2002)
W. Yang, J.J. Gooding, D.B. Hibbert, Characterisation of gold electrodes modified with self-assembled monolayers of l-cysteine for the adsorptive stripping analysis of copper. J. Electroanal. Chem. 516, 10–16 (2001)
J.B. Matos, L.P. Pereira, S.M.L. Agostinho, O.E. Barcia, G.G.O. Cordeiro, E. D’Elia, Effect of cysteine on the anodic dissolution of copper in sulfuric acid medium. J. Electroanal. Chem. 570, 91–94 (2004)
K.M. Ismail, Evaluation of cysteine as environmentally friendly corrosion inhibitor for copper in neutral and acidic chloride solutions. Electrochim. Acta 52, 7811–7819 (2007)
A.B. Silva, S.M.L. Agostinho, O.E. Barcia, G.G.O. Cordeiro, E. D’Elia, The effect of cysteine on the corrosion of 304 L stainless steel in sulphuric acid. Corros. Sci. 48, 3668–3674 (2006)
H. Saifi, M.C. Bernard, S. Joiret, K. Rahmouni, H. Takenouti, B. Talhi, Corrosion inhibitive action of cysteine on Cu–30Ni alloy in aerated 0.5 M H2SO4. Mater. Chem. Phys. 120, 661–669 (2010)
M. Abdallah, A.Y. El-Etre, Corrosion inhibition of nickel in sulfuric acid using tween surfactants. Port. Electrochim. Acta 21, 315–326 (2003)
W.J. Lorenz, F. Mansfeld, Determination of corrosion rates by electrochemical DC and AC methods. Corros. Sci. 21, 647–672 (1981)
T.S. De Gromoboy, L.L. Shreir, The formation of nickel oxides during the passivation of nickel in relation to the potential/pH diagram. Electrochim. Acta 11, 895 (1966)
F. Said, N. Souissi, K. Es-Salah, N. Hajjaji, E. Triki, A. Srhiri, Phosphonium iodine as nickel corrosion inhibitor in 1 M sulphuric acid medium. J. Mater. Sci. 42, 9070–9074 (2007)
K.F. Khaled, M.A. Amin, Computational and electrochemical investigation for corrosion inhibition of nickel in molar nitric acid by piperidines. J. Appl. Electrochem. 38, 1609–1621 (2008)
V.V. Parshutin, N.L. Bogdashkina, G.P. Chernova, The effect of medium on the corrosion and electrochemical behavior of nickel. Prot. Met 43, 59–65 (2007)
B.A. Abd-El-Nabey, A.M. Abdel-Gaber, M. El, E. Said Ali, S.El-Housseiny Khamis, Cannabis plant extract as inhibitor for the corrosion of nickel in 0.5 M H2SO4. Int. J. Electrochem. Sci. 7, 11811–11826 (2012)
M. Stern, A.L. Geary, Electrochemical polarization. I A theoretical analysis of the shape of polarization curves. J. Electrochem. Soc. 104, 56 (1957)
B. Mezhoud, M. Bouchouit, M.E. Said, L. Messaadia, A. Belfaitah, H. Merazig, A. Chibani, S. Bouacida, A. SofianeBouraiou, Synthesis, x-ray structure and theoretical study of benzazole thioether and its zinc complex as corrosion inhibitors for steel in acidic medium. Res. Chem. Intermed. 42, 7447–7470 (2016)
D.-Q. Zhang, Q.-R. Cai, L.-X. Gao, K.Y. Lee, Effect of serine, threonine and glutamic acid on the corrosion of copper in aerated hydrochloric acid solution. Corros. Sci. 50, 3615–3621 (2008)
G.J. Brug, A.L.G. Van den Eeden, M. Sluyters-Rehbach, J.H. Sluyters, The analysis of electrode impedances complicated by the presence of a constant phase element. J. Electroanal. Chem. 176, 275–295 (1984)
D.Q. Zhang, L.X. Gao, G.D. Zhou, Inhibition of copper corrosion in aerated hydrochloric acid solution by amino-acid compounds. J. Appl. Eletrochem. 35, 1081 (2005)
M.B. Petrović, M.B. Radovanović, A.T. Simonović, S.M. Milić, M.M. Antonijević, The effect of cysteine on the behaviour of copper in neutral and alkaline sulphate solutions. Int. J. Electrochem. Sci. 7, 9043–9905 (2012)
C. Monticelli, G. Brunoro, A. Frignani, F. Zucchi, Surface-active substances as inhibitors of localized corrosion of the aluminium alloy AA 6351. Corros. Sci. 32, 693 (1991)
Q.B. Zhang, Y.X. Hua, Corrosion inhibition of Mild steel by alkylimidazolium ionic liquids in hydrocholoric acid. Electrochim. Acta 54, 1881–1887 (2009)
A.A. El-shafei, M.N.H. Moussa, A.A. El-Far, Inhibitory effect of amino acids on Al pitting corrosion in 0.1 M NaCl. J. Appl. Electrochem. 27, 1075 (1997)
E. Hamed, S.S. Abd El-REhim, M.F. El-Shahat, A.M. Shaltot, Corrosion inhibition of nickel in H2SO4 solution by alanine. Mater. Sci. Eng., B 177, 441–448 (2012)