Efficient Way of Carbon Dioxide Utilization in a Gas-to-Methanol Process: From Fundamental Research to Industrial Demonstration

Appel AM, Bercaw JE, Bocarsly AB, Dobbek H, DuBois DL, Dupuis M et al (2013) Frontiers, opportunities, and challenges in biochemical and chemical catalysis of CO2 fixation. Chem Rev 113(8):6621–6658 Wei J, Ge Q, Yao R, Wen Z, Fang C, Guo L et al (2017) Directly converting CO2 into a gasoline fuel. Nat Commun 8:15174 Álvarez A, Bansode A, Urakawa A, Bavykina AV, Wezendonk TA, Makkee M et al (2017) Challenges in the greener production of formates/formic acid, methanol, and DME by heterogeneously catalyzed CO2 hydrogenation processes. Chem Rev 117(14):9804–9838 Rezayee NM, Huff CA, Sanford MS (2015) Tandem amine and ruthenium-catalyzed hydrogenation of CO2 to methanol. J Am Chem Soc 137(3):1028–1031 Zhang C, Jun K-W, Ha K-S, Lee Y-J, Kang SC (2014) Efficient utilization of greenhouse gases in a Gas-to-liquids process combined with CO2/Steam-mixed reforming and Fe-based Fischer–Tropsch synthesis. Environ Sci Technol 48(14):8251–8257 Gao P, Li S, Bu X, Dang S, Liu Z, Wang H et al (2017) Direct conversion of CO2 into liquid fuels with high selectivity over a bifunctional catalyst. Nat Chem 9:1019 Halmann MM, Steinberg M (1999) Green gas CO2 mitigation: science and technology. CRC Press, Florida Min J-E, Lee Y-J, Park H-G, Zhang C, Jun K-W (2015) Carbon dioxide reforming of methane on Ni–MgO–Al2O3 catalysts prepared by sol–gel method: effects of Mg/Al ratios. J Ind Eng Chem 26:375–383 Wang W, Wang S, Ma X, Gong J (2011) Recent advances in catalytic hydrogenation of carbon dioxide. Chem Soc Rev 40(7):3703–3727 Olah GA, Goeppert A, Czaun M, Prakash GS (2012) Bi-reforming of methane from any source with steam and carbon dioxide exclusively to metgas (CO–2H2) for methanol and hydrocarbon synthesis. J Am Chem Soc 135(2):648–650 Ha K-S, Bae JW, Woo K-J, Jun K-W (2010) Efficient utilization of greenhouse gas in a Gas-to-liquids process combined with carbon dioxide reforming of methane. Environ Sci Technol 44(4):1412–1417 Kang SC, Jun K-W, Lee Y-J (2013) Effects of the CO/CO2 ratio in synthesis gas on the catalytic behavior in Fischer–Tropsch synthesis using K/Fe–Cu–Al catalysts. Energy Fuels 27(11):6377–6387 Li Z, Li J, Dai M, Liu Y, Han D, Wu J (2014) The effect of preparation method of the Cu–La2O3–ZrO2/γ–Al2O3 hybrid catalysts on one-step synthesis of dimethyl ether from syngas. Fuel 121:173–177 Yang R, Yu X, Zhang Y, Li W, Tsubaki N (2008) A new method of low-temperature methanol synthesis on Cu/ZnO/Al2O3 catalysts from CO/CO2/H2. Fuel 87(4–5):443–450 Yao Y, Liu X, Hildebrandt D, Glasser D (2011) Fischer–Tropsch synthesis using H2/CO/CO2 syngas mixtures over an iron catalyst. Ind Eng Chem Res 50(19):11002–11012 Bertau M, Offermanns H, Plass L, Schmidt F, Wernicke H-J (2014) Methanol: the basic chemical and energy feedstock of the future. Springer, Berlin Olah GA (2005) Beyond oil and gas: the methanol economy. Angew Chem Int Ed 44(18):2636–2639 Olah GA, Goeppert A, Prakash GKS (2009) Beyond oil and gas: the methanol economy, 2nd edn., Wiley-VCH, Weinheim U.S. Energy Information Administration. (2015) Annual Energy Outlook 2015; https://www.eia.gov/forecasts/aeo/pdf/0383(2015).pdf. Accessed April 2015 Kerr RA (2010) Natural gas from shale bursts onto the scene. Science 328(5986):1624–1626 Julián-Durán LM, Ortiz-Espinoza AP, El-Halwagi MM, Jiménez-Gutiérrez A (2014) Techno-economic assessment and environmental impact of shale gas alternatives to methanol. ACS Sustain Chem Eng 2(10):2338–2344 Ehlinger VM, Gabriel KJ, Noureldin MM, El-Halwagi MM (2013) Process design and integration of shale gas to methanol. ACS Sustain Chem Eng 2(1):30–37 Oliveira EL, Grande CA, Rodrigues AE (2010) Methane steam reforming in large pore catalyst. Chem Eng Sci 65(5):1539–1550 Kathiraser Y, Thitsartarn W, Sutthiumporn K, Kawi S (2013) Inverse NiAl2O4 on LaAlO3–Al2O3: unique catalytic structure for stable CO2 reforming of methane. J Phys Chem C 117(16):8120–8130 Velasco JA, Fernandez C, Lopez L, Cabrera S, Boutonnet M, Järås S (2015) Catalytic partial oxidation of methane over nickel and ruthenium based catalysts under low O2/CH4 ratios and with addition of steam. Fuel 153:192–201 Wang Y, Peng J, Zhou C, Lim Z-Y, Wu C, Ye S et al (2014) Effect of Pr addition on the properties of Ni/Al2O3 catalysts with an application in the autothermal reforming of methane. Int J Hydrogen Energy 39(2):778–787 Zhang C, Jun K-W, Gao R, Lee Y-J, Kang SC (2015) Efficient utilization of carbon dioxide in gas-to-liquids process: process simulation and techno-economic analysis. Fuel 157:285–291 Zhang C, Jun K-W, Gao R, Kwak G, Kang SC (2016) Efficient utilization of associated natural gas in a modular gas-to-liquids process: technical and economic analysis. Fuel 176:32–39 Zhang C, Jun K-W, Kwak G, Lee Y-J, Park H-G (2016) Efficient utilization of carbon dioxide in a gas-to-methanol process composed of CO2/steam–mixed reforming and methanol synthesis. J CO2 Util 16:1–7 Zhang C, Jun K-W, Gao R, Kwak G, Park H-G (2017) Carbon dioxide utilization in a gas-to-methanol process combined with CO2/Steam-mixed reforming: techno-economic analysis. Fuel 190:303–311 Nagaoka K, Seshan K, Aika K-i, Lercher JA (2001) Carbon deposition during carbon dioxide reforming of methane—comparison between Pt/Al2O3 and Pt/ZrO2. J Catal 197(1):34–42 Pakhare D, Spivey J (2014) A review of dry (CO2) reforming of methane over noble metal catalysts. Chem Soc Rev 43(22):7813–7837 Ma J, Sun N, Zhang X, Zhao N, Xiao F, Wei W et al (2009) A short review of catalysis for CO2 conversion. Catal Today 148(3):221–231 Carrara C, Múnera J, Lombardo EA, Cornaglia LM (2008) Kinetic and stability studies of Ru/La2O3 used in the dry reforming of methane. Top Catal 51(1):98–106 Ferreira-Aparicio P, Márquez-Alvarez C, Rodríguez-Ramos I, Schuurman Y, Guerrero-Ruiz A, Mirodatos C (1999) A transient kinetic study of the carbon dioxide reforming of methane over supported Ru catalysts. J Catal 184(1):202–212 Hu YH (2010) Advances in CO2 conversion and utilization. ACS Publications, Washington, D.C. Hu YH, Ruckenstein E (2004) Catalytic conversion of methane to synthesis gas by partial oxidation and CO2 reforming. Adv Catal 48:297–345 Ruckenstein E, Hu YH (1998) Role of lattice oxygen during CO2 reforming of methane over NiO/MgO solid solutions. Catal Lett 51(3):183–185 Chang J-S, Park S-E, Chon H (1996) Catalytic activity and coke resistance in the carbon dioxide reforming of methane to synthesis gas over zeolite-supported Ni catalysts. Appl Catal A 145(1):111–124 Chang J-S, Park S-E, Yoo JW, Park J-N (2000) Catalytic behavior of supported KNiCa catalyst and mechanistic consideration for carbon dioxide reforming of methane. J Catal 195(1):1–11 Luo J, Yu Z, Ng C, Au C (2000) CO2/CH4 reforming over Ni–La2O3/5A: an investigation on carbon deposition and reaction steps. J Catal 194(2):198–210 Chen Y-G, Tomishige K, Yokoyama K, Fujimoto K (1999) Catalytic performance and catalyst structure of nickel–magnesia catalysts for CO2 reforming of methane. J Catal 184(2):479–490 Rostrupnielsen J, Hansen JB (1993) CO2-reforming of methane over transition metals. J Catal 144(1):38–49 Lima S, Assaf J, Pena M, Fierro J (2006) Structural features of La1 – xCexNiO3 mixed oxides and performance for the dry reforming of methane. Appl Catal A 311:94–104 Singha RK, Yadav A, Agrawal A, Shukla A, Adak S, Sasaki T et al (2016) Synthesis of highly coke resistant Ni nanoparticles supported MgO/ZnO catalyst for reforming of methane with carbon dioxide. Appl Catal B 191:165–178 Zhang J, Li F (2015) Coke-resistant Ni@SiO2 catalyst for dry reforming of methane. Appl Catal B 176:513–521 Li Z, Mo L, Kathiraser Y, Kawi S (2014) Yolk–satellite–shell structured Ni–yolk@Ni@SiO2 nanocomposite: superb catalyst toward methane CO2 reforming reaction. ACS Catal 4(5):1526–1536 Bian Z, Kawi S (2017) Highly carbon-resistant Ni–Co/SiO2 catalysts derived from phyllosilicates for dry reforming of methane. J CO2 Util 18:345–352 Erdogan B, Arbag H, Yasyerli N (2018) SBA-15 supported mesoporous Ni and Co catalysts with high coke resistance for dry reforming of methane. Int J Hydrog Energy 43(3):1396–1405 Potdar H, Roh H-S, Jun K-W, Ji M, Liu Z-W (2002) Carbon dioxide reforming of methane over co-precipitated Ni–Ce–ZrO2 catalysts. Catal Lett 84(1):95–100 Roh H-S, Jun K-W, Baek S-C, Park S-E (2002) A Highly active and stable catalyst for carbon dioxide reforming of methane: Ni/Ce–ZrO2/θ–Al2O3. Catal Lett 81(3):147–151 Roh H-S, Potdar H, Jun K-W, Kim J-W, Oh Y-S (2004) Carbon dioxide reforming of methane over Ni incorporated into Ce–ZrO2 catalysts. Appl Catal A 276(1):231–239 Roh H-S, Potdar H, Jun K-W (2004) Carbon dioxide reforming of methane over co-precipitated Ni–CeO2, Ni–ZrO2 and Ni–Ce–ZrO2 catalysts. Catal Today 93:39–44 Roh H-S, Jun K-W, Park S-E (2003) Methane reforming reactions over Ni/Ce–ZrO2, Ni/La–ZrO2 and Ni/Si–ZrO2 catalysts. J Ind Eng Chem 9(3):261–266 Liu Z-W, Roh H-S, Jun K-W (2003) Carbon dioxide reforming of methane over Ni/La2O3/Al2O3. J Ind Eng Chem 9(3):267–274 Jun K-W, Roh H-S, Chary KV (2007) Structure and catalytic properties of ceria-based nickel catalysts for CO2 reforming of methane. Catal Surv Asia 11(3):97–113 Roh H-S, Jun K-W (2008) Carbon dioxide reforming of methane over Ni catalysts supported on Al2O3 modified with La2O3, MgO, and CaO. Catal Surv Asia 12(4):239–252 Li X, Chang J-S, Park S-E (1999) Carbon as an intermediate during the carbon dioxide reforming of methane over zirconia-supported high nickel loading catalysts. Chem Lett 28(10):1099–1100 Roh H-S, Jun K-W, Dong W-S, Baek S-C, Park S-E (2002) Methane reforming reactions over stable Ni/θ–Al2O3 catalysts. J Ind Eng Chem 8(5):464–471 Roh H-S, Liu Z-W, Potdar H, Kim J-W, Jun K-W (2003) Carbon dioxide reforming of methane over Ni/CaO/Al2O3. J Ind Eng Chem 9(6):762–767 Liu Z-W, Roh H-S, Jun K-W, Potdar H, Ji M (2003) CO2 reforming of methane over Ni on MgO-precoated Al2O3. J Ind Eng Chem 9(5):576–583 Jun KW, Baek S-C, Bae JW, Min K-S, Song S-L, Oh T-Y (2013) Catalyst for preparing synthesis gas from natural gas and carbon dioxide, and preparation method thereof. US 8524119B2 Lee C-J, Lim Y, Kim HS, Han C (2009) Optimal Gas-to-liquid product selection from natural gas under uncertain price scenarios. Ind Eng Chem Res 48(2):794–800 Lim H-W, Park M-J, Kang S-H, Chae H-J, Bae JW, Jun K-W (2009) Modeling of the kinetics for methanol synthesis using Cu/ZnO/Al2O3/ZrO2 catalyst: influence of carbon dioxide during hydrogenation. Ind Eng Chem Res 48(23):10448–10455 Park N, Park M-J, Baek S-C, Ha K-S, Lee Y-J, Kwak G et al (2014) Modeling and optimization of the mixed reforming of methane: Maximizing CO2 utilization for non-equilibrated reaction. Fuel 115:357–365 Park N, Park M-J, Lee Y-J, Ha K-S, Jun K-W (2014) Kinetic modeling of methanol synthesis over commercial catalysts based on three-site adsorption. Fuel Process Technol 125:139–147 Park N, Park M-J, Ha K-S, Lee Y-J, Jun K-W (2014) Modeling and analysis of a methanol synthesis process using a mixed reforming reactor: perspective on methanol production and CO2 utilization. Fuel 129:163–172