Effects of sub-/super-critical CO2 on the fracture-related mechanical characteristics of bituminous coal

Frontiers of Earth Science - Tập 17 - Trang 760-775 - 2023
Zedong Sun1,2, Hongqiang Xie3, Gan Feng3, Xuanmin Song1, Mingbo Chi4, Tao Meng5, Bole Sun6
1Key Laboratory of In-situ Property Improving Mining (Ministry of Education), Taiyuan University of Technology, Taiyuan, China
2College of Coal Engineering, Shanxi Datong University, Datong, China
3State Key Laboratory of Hydraulics and Mountain River Engineering, College of Water Resource & Hydropower, Sichuan University, Chengdu, China
4State Key Laboratory of Water Resource Protection and Utilization in Coal Mining, Beijing, China
5School of Chemical and Biological Engineering, Taiyuan University of Science and Technology, Taiyuan, China
6China Railway Third Bureau Group Co., Ltd., Taiyuan, China

Tóm tắt

Injecting carbon dioxide CO2 into a coal seam is an important way to improve coalbed methane recovery and to store geological carbon. The fracture mechanical characteristics of bituminous coal determine the propagation and evolution of cracks, which directly affect CO2 storage in coal seams and the efficiency of resource recovery. This study applied CO2 adsorption and three-point bending fracture experiments using bituminous coal samples in a gaseous state (4 MPa), subcritical state (6 MPa), and supercritical state (8 and 12 MPa) to investigate the influence of CO2 state and anisotropy on the fracture-related mechanical response of bituminous coal. The results show that the change in mechanical properties caused by CO2 adsorption is CO2 state-dependent. The supercritical CO2 adsorption at 8 MPa causes the largest decrease in the mode-I fracture toughness (KIC), which is 63.6% lower than the toughness before CO2 adsorption. The instability characteristics of bituminous coal show the transformation trend of “sudden-gradual-sudden fracture”. With or without CO2 adsorption, the order of the KIC associated with three types of bituminous coal specimens is crack-divider type > crack-arrester type > crack-short transverse type. Phenomenologically, the fracture toughness of bituminous coal is positively correlated with its specific surface area and total pore volume; the toughness is negatively correlated with its average pore size.

Tài liệu tham khảo

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