Effect of Sound Waves on Decarburization Rate of Fe-C Melt

Metallurgical and Materials Transactions B - Tập 49 - Trang 264-273 - 2017
Sergey V. Komarov1, Masamichi Sano2
1Graduate School of Environmental Studies, Tohoku University, Sendai, Japan
2Department of Materials Processing Engineering, School of Engineering, Nagoya University, Nagoya, Japan

Tóm tắt

Sound waves have the ability to propagate through a gas phase and, thus, to supply the acoustic energy from a sound generator to materials being processed. This offers an attractive tool, for example, for controlling the rates of interfacial reactions in steelmaking processes. This study investigates the kinetics of decarburization in molten Fe-C alloys, the surface of which was exposed to sound waves and Ar-O2 gas blown onto the melt surface. The main emphasis is placed on clarifying effects of sound frequency, sound pressure, and gas flow rate. A series of water model experiments and numerical simulations are also performed to explain the results of high-temperature experiments and to elucidate the mechanism of sound wave application. This is explained by two phenomena that occur simultaneously: (1) turbulization of Ar-O2 gas flow by sound wave above the melt surface and (2) motion and agitation of the melt surface when exposed to sound wave. It is found that sound waves can both accelerate and inhibit the decarburization rate depending on the Ar-O2 gas flow rate and the presence of oxide film on the melt surface. The effect of sound waves is clearly observed only at higher sound pressures on resonance frequencies, which are defined by geometrical features of the experimental setup. The resonance phenomenon makes it difficult to separate the effect of sound frequency from that of sound pressure under the present experimental conditions.

Tài liệu tham khảo

N. Dogan, G.A. Brooks, and M.A. Rhamdhani: ISIJ Int., 2011, vol. 51, pp. 1102–09. H. Jalkanen and L. Holappa: VII Int. Conf. on Molten Slags, Fluxes and Salts, Cape Town, South Africa, 2004. L. Nedar: Steel Res., 1996, vol. 67, pp. 320–27. M.J. Luomala, T.M.J. Fabritius, E.O. Virtanen, T.P. Siivola, and J.J. Härkki: ISIJ Int., 2002, vol. 42, pp. 944–49. T.M.J. Fabritius, M.J. Luomala, E.O. Virtanen, H. Tenkku, T.L.J. Fabritius, T.P. Siivola, and J.J. Härkki: ISIJ Int., 2002, vol. 42, pp. 861–67. S. Komarov, M. Kuwabara, and O. Abramov: ISIJ Int., 2005, vol. 45, pp. 1765–82. S.V. Komarov: in Advanced Topics in Mass Transfer, InTech-Open Access Publisher, 2011, pp. 61–86. K.A. Blinov: Application of Acoustic Oscillations for Steelmaking Processes, Metallurgia, Chelyabinsk, Russia, 1991, pp. 49–61 (in Russian). S.V. Komarov, N. Noriki, K. Osada, M. Kuwabara, and M. Sano: Metall. Mater. Trans. B, 2007, vol. 38B, pp. 809–18. P.P. Ermakov: Theoretical Basis of Chemical Technology, 1991, vol. 25, pp. 198–203 (in Russian). D.R. Sain and G.G. Belton: Metall. Trans. B, 1978, vol. 9B, pp. 403–07. U. Maas and J. Warnatz: Twenty-Second Symposium (International) on Combustion, The Combustion Institute, Pittsburgh, PA,1988, pp. 1695–1704. C. Tverino and J.C. Prince: Surf. Sci., 2000, vol. 449, pp. 61–74. J.W.S. Rayleigh: Theory of Sound, Dover Publications, New York, NY, 1945, pp. 170–235. R.B. Bird, W.E. Stewart, and E.N. Lightfoot: Transport Phenomena, John Wiley and Sons, New York, NY, 2006, pp. 23–29. V.A. Mourga: Acoust. Phys., 2003, vol. 49, pp. 339–43. E. Prestes, A.S.A. Chinelatto, and W.S. Resende: Cerâmica, 2009, vol. 55, pp. 61–66.