Axit β-N-butyl amino propionic thân thiện với môi trường như chất ức chế ăn mòn xanh cho thép N80 trong nước muối bão hòa CO2

Journal of Materials Science - Trang 1-20 - 2024
Xintong Wang1,2, Jiang Yang1,2, Xu Chen3, Yefei Wang4, Zhen Yang4, Wei Ding2
1College of Chemistry and Chemical Engineering, China University of Petroleum (East China), Qingdao, China
2School of Petrochemical Engineering, Liaoning Petrochemical University, Fushun, China
3College of Petroleum Engineering, Liaoning Petrochemical University, Fushun, China
4Key Laboratory of Unconventional Oil and Gas Development, China University of Petroleum (East China), Ministry of Education, Qingdao, People’s Republic of China

Tóm tắt

Để giảm thiểu sự ăn mòn CO2 trong ngành dầu khí, axit β-N-butyl amino propionic (BAA) không độc hại đã được tổng hợp bằng một phương pháp một bước với năng lượng thấp và không phát sinh chất thải. Hiệu quả của BAA với vai trò là một chất ức chế ăn mòn cho thép N80 trong nước muối bão hòa CO2 đã được khảo sát thông qua các phép đo thực nghiệm và mô hình lý thuyết. Kết quả cho thấy BAA hoạt động như một chất ức chế ăn mòn hỗn hợp hiệu quả. Phân tử BAA tương tác với F (1 1 0) với nhóm –COO– và nhóm –NH2+ trong nhóm đầu ưa nước, và các nhóm kỵ nước được hấp phụ trên bề mặt thép ở cấu hình lệch 45° so với bề mặt thép. Quá trình hấp phụ là sự kết hợp của quá trình vật lý và hóa học và phù hợp với công thức hấp phụ đẳng nhiệt Langmuir. Khi nồng độ lớn hơn 50 ppm, một lớp phim ức chế ăn mòn hoàn chỉnh với độ kỵ nước cao có thể được hấp phụ trên bề mặt thép, điều này có thể ngăn cản hiệu quả sự khuếch tán của các loài ăn mòn từ nước muối vào bề mặt thép.

Từ khóa

#ăn mòn #ức chế ăn mòn #axit amin #nước muối bão hòa CO2 #thép N80

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