Dye-loaded zeolite L @silica core-shell composite functionalized with europium(III) complexes for dipicolinic acid detection

Photochemical & Photobiological Sciences - Tập 10 - Trang 128-132 - 2020
Yige Wang1, Yuping Yue2, Huanrong Li1, Qi Zhao1, Yi Fang1, Pengpeng Cao1
1Hebei ProvincialKey Lab ofGreen Chemical Technology and High Efficient Energy Saving, School of Chemical Engineering and Technology, Tianjin, China
2Chemistry group, Shandong Zhucheng Longcheng Middle School, Zhucheng, Shandong, China

Tóm tắt

Novel core-shell composites have been developed by immobilization of non-luminescent europium(III) complexes onto the surface of silica shells that are coated on the surface of luminescent dye-loaded zeolite L nano-crystals. The obtained core-shell composites were used for the ratiometric detection of dipicolinic acid (DPA) molecules. The dyes located in the channels of the zeolite L host are protected from any interaction with the environment of the particles and therefore provide a stable reference signal which can eliminate the need for instrument-specific calibration curves for DPA quantification in an analyte.

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