Dissolved and particulate forms of iron and manganese in the redox zone of the Black Sea

O. Bashtyurk, I. I. Volkov, S. Gekmen, et al., “International Expedition on Board R/V Bilim in July 1997 in the Black Sea,” Okeanologiya 38(3), 473–476 (1998) [Oceanology 38 (3), 429–432 (1998)].

I. I. Volkov, A. G. Rozanov, and T. P. Demidova, “Inorganic Reduced Sulfur Compounds and Dissolved Manganese in the Black Sea Water,” in Winter Condition of the Ecosystem of the Open Part of the Black Sea (IO RAN, Moscow, 1992), pp. 38–50 [in Russian].

I. I. Volkov, E. A. Kontar’, Yu. F. Lukashev, et al., “Upper Hydrogen Sulfide Boundary and Origin of the Nepheloid Redox Layer in the Waters of the Caucasian Slope of the Black Sea,” Geokhimiya, No. 7, 540–550 (1997).

A. V. Egorov, “Methane Distribution in the Water Column of the Black Sea,” in Multidisciplinary Studies of the Northeastern Part of the Black Sea, Ed. by A. G. Zatsepin and M. V. Flint (Nauka, Moscow, 2002), pp. 144–147 [in Russian].

M. Yu. Kononets, S. V. Pakhomova, A. G. Rozanov, and M. A. Proskurnin, “Determination of Soluble Iron Species in Seawater Using Ferrozine,” Zh. Anal. Khim. 57(7), 704–708 (2002) [J. Anal. Chem. 57 (7), 586–589 (2002)].

S. V. Pakhomova, Soluble Forms of Iron and Manganese in the Sea Water, Sediments, and on the Water-Bottom Interface, Candidate’s Dissertation in Geology and Mineralogy (IO RAN, 2005).

A. G. Rozanov, “Interstitial Waters, Sediment Diagenesis, and Exchange of Chemical Components at the Water-Bottom Interface,” in Chemistry of Seas and Oceans (Nauka, Moscow, 1995), pp. 307–329 [in Russian].

A. G. Rozanov and A. V. Sivtsov, “On the Suspended Matter from the Boundary O2-H2S Zone of the Black Sea,” Dokl. Akad. Nauk 362(2), 261–265 (1998).

A. G. Rozanov and I. I. Volkov, “Manganese in the Black Sea,” in Multidisciplinary Studies of the Northeastern Part of the Black Sea (Nauka, Moscow, 2002), pp. 190–200 [in Russian].

Modern Methods for Hydrochemical Studies in the Ocean, Ed. by O. K. Bordovskii and A. M. Chernyakova (IO RAN, Moscow, 1992) [in Russian].

B. A. Skopintsev, Formation of the Present-Day Composition of the Black Sea Waters (Gidrometeoizdat, Leningrad, 1975) [in Russian].

B. A. Skopintsev and T. P. Popova, “Manganese Accumulation in Waters of Hydrogen Sulfide Basins As Exemplified by the Black Sea,” Tr. Geol. Inst. AN SSSR 97, 165–181 (1963).

P. A. Stunzhas, “On the Structure of the Zone of Interaction of Aerobic and Anaerobic Waters of the Black Sea on the Basis of Measurements with a Membrane-Free Sensor of Oxygen,” Okeanologiya 40(4), 539–545 (2000) [Oceanology 40 (4), 503–509 (2000)].

P. A. Stunzhas and E. V. Yakushev, “Fine Hydrochemical Structure of the Redox Zone in the Black Sea according to the Results of Measurements with an Open Oxygen Sensor and with Bottle Samplers,” Okeanologiya 46(5), 672–684 (2006) [Oceanology 46 (5), 629–641 (2006)].

Y. Coban-Yildiz, V. Baravelli, D. Fabbri, et al., Oceanography of the Eastern Mediterranean and Black Sea. Similarities and Differences of Two Interconnected Basins, Ed. by A. Yilmaz (Tubitak Publishers, Ankara, 2003), pp. 529–535.

S. Erdogan, S. Yemenicioglu, and S. Tugrul, “Distribution of Dissolved and Particulate Forms of Iron and Manganese in the Black Sea,” in Oceanography of the Eastern Mediterranean and Black Sea. Similarities and Differences of Two Interconnected Basins, Ed. by A. Yilmaz (Tubitak publishers, Ankara, 2003), pp. 447–451.

H. P. Hansen and F. Koroleff, Methods of Seawater Analysis, 3rd, Completely Revised and Extended Edition, Ed. by K. Grashoff et al. (Wiley, Weinheim, 1999), pp. 149–228.

C. Haraldsson and S. Westerlund, “Trace Metals in the Water Columns of the Black Sea and Framvaren Fjord,” Mar. Chem. 23(3–4), 417–424 (1988).

B. L. Lewis and W. M. Landing, “The Biochemistry of Manganese and Iron in the Black Sea,” Deep-Sea Res. 38(Suppl. 2), S773–S803 (1991).

B. L. Lewis, P. D. Holt, S. W. Taylor, et al., “Voltammetric Estimation of Iron(III) Thermodynamic Stability Constants for Catecholate Siderophores Isolated from Marine Bacteria and Cyanobacteria,” Mar. Chem. 50, 176–188 (1995).

J. Muramoto, S. Honjo, B. Fry, et al., “Sulfur, Iron and Organic Carbon Fluxes in the Black Sea: Sulfur Isotopic Evidance for Origin of Sulfur Fluxes,” Deep-Sea Res. 38(Suppl. 2), S1151–S1187 (1991).

J. W. Murray, L. A. Codispoti, and G. E. Friederich, Oxidation-Reduction Environments. The Suboxic Zone in the Black Sea, in Aquatic Chemistry: Interfacial and Interspecies Processes. ACS Advances in Chemistry, Series 244, Ed. by C. P. Huang et al. (1995), pp. 157–176.

J. W. Murray, S. K. Konovalov, A. Romanov, et al., Oceanography of the Eastern Mediterranean and Black Sea. Similarities and Differences of Two Interconnected Basins, Ed. by A. Yilmaz (Tubitak publishers, Ankara, 2003), pp. 545–557.

M. Ozturk, “Trends of Trace Metal (Mn, Fe, Co, Ni, Cu, Zn, Cd and Pb) Distributions at the Oxic-Anoxic Interface and in Sulfidic Water of the Drammensfjord,” Mar. Chem. 48, 329–342 (1995).

D. L. Parker, G. Sposito, and B. M. Tebo, “Manganese( III) Binding to a Pyoverdine Siderophore Produced by a Manganese(II)-Oxidizing Bacterium,” Geochim. Cosmochim. Acta 68, 4809–4820 (2004).

C. Pohl, A. Loffler, and U. Hennings, “A Sediment Trap Study for Trace Metals under Seasonal Aspects in the Stratified Baltic Sea (Gotland Basin; 57′19.20°N; 20′03.00°E),” Mar. Chem. 84, 143–160 (2004).

R. T. Powell, W. M. Landing, and J. E. Bauer, “Colloidal Trace Metals, Organic Carbon and Nitrogen in a Southeastern U.S. Estuary,” Mar. Chem. 55, 165–176 (1996).

E. L. Rue and K. W. Bruland, “Complexation of Iron(III) by Natural Organic Ligands in the Central North Pacific As Determined by a New Competitive Ligand Equilibration/Adsorptive Cathodic Stripping Voltammetric Method,” Mar. Chem. 50, 117–138 (1995).

D. W. Spenser and P. G. Brewer, “Aspect of the Distribution and Trace Element Composition of Suspended Matter in the Black Sea,” Geochim. Cosmochim. Acta 36(1), 71–86 (1972).

W. Stumm and J. J. Morgan, Aquatic Chemistry (Wiley, New York, 1981).

S. P. C. Tankere, F. L. L. Muller, J. D. Burton, et al., “Trace Metal Distributions in Shelf Waters of Northwestern Black Sea,” Continental Shelf Res. 21, 1501–1532 (2001).

B. M. Tebo, “Manganese(II) Oxidation in the Suboxic Zone of the Black Sea,” Deep-Sea Res. 38(Suppl. 2), S883–S905 (1991).

B. M. Tebo, B. G. Clement, G. W. Luther III, et al., “The Mechanism of Bacterial Manganese(II) Oxidation and Its Implication for Maintenance of the Suboxic Zone in the Black Sea,” in Program and Abstracts of International Ocean Research Conference, June 5–10, 2005, France, Paris, (Paris, 2005), p. 154.

R. E. Trouwborst, B. G. Clement, B. M. Tebo, et al., “Soluble Mn(III) in Suboxic Zones,” Science 313, 1955–1957 (2006).

C. M. G. Van den Berg, “Evidence for Organic Complexation of Iron in Seawater,” Mar. Chem. 50, 139–157 (1995).

S. M. Webb, G. J. Dick, J. R. Bargar, and B. M. Tebo, “Evidence for the Presence of Mn(III) Intermediates in the Bacterial Oxidation of Mn(II),” Proc. Natl. Acad. Sci. USA 102, 5558–5563 (2005).

E. V. Yakushev and E. I. Debolskaya, “Particulate Manganese as a Main Factor of Oxidation of Hydrogen Sulfide in Redox Zone of the Black Sea,” in Oceanic Fronts and Related Phenomena. Konstantin Fedorov Memorial Symposium. Pushkin, St.-Petersburg, Russia, May 18–22, 1998. Proceedings of IOC Workshop, Report No. 159 (Kluwer, 2000), pp. 592–597.

E. V. Yakushev, F. Pollehne, G. Jost, et al., “Analysis of the Water Column Oxic/Anoxic Interface in the Black and Baltic Seas with a Redox-Layer Model,” Mar. Chem. 107, 388–410 (2007).

E. V. Yakushev, V. K. Chasovnikov, E. I. Debolskaya, et al., “The Northeastern Black Sea Redox Zone: Hydrochemical Structure and Its Temporal Variability,” Deep-Sea Res. II 53, 1764–1786 (2006).

S. Yemenicioglu, S. Erdogan, and S. Tugrul, “Distribution of Dissolved Forms of Iron and Manganese in the Black Sea,” Deep-Sea Res. II 53, 1842–1855 (2006).