Dispersion and Exfoliation of Graphene in Rubber by an Ultrasonically‐Assisted Latex Mixing and In situ Reduction Process

Macromolecular Materials and Engineering - Tập 296 Số 7 - Trang 590-602 - 2011
Yanhu Zhan1, Jinkui Wu1, Hesheng Xia1, Ning Yan1, Guoxia Fei1, Guiping Yuan2
1State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu 610065, China
2Analytical & Testing Center, Sichuan University, Chengdu 610065, China

Tóm tắt

AbstractNR/GE composites were prepared by an ultrasonically‐assisted latex mixing and in situ reduction process. Graphene oxide was dispersed in NRL using an ultrasonic field and was then reduced in situ, followed by latex coagulation to obtain the NR/GE masterbatch. The results show that the process produces a much better dispersion and exfoliation of GE in the matrix and contributes to an increase in the tensile strength compared to conventional direct mixing. Compared to pure rubber, the tensile strength and tear strength for NR/(2 wt.‐%)GE composites were increased by ≈47 and 50%, respectively. With increasing GE content, the maximum torque, crosslink density, elastic modulus, and thermal conductivity of NR/GE composites were found to increase. magnified image

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Tài liệu tham khảo

10.1038/nnano.2009.58

10.1038/nmat1849

10.1021/nn9010472

10.1021/jp071761s

10.1002/adfm.200800954

10.1002/macp.200800395

10.1038/nature04969

10.1002/smll.200901480

10.1016/j.cplett.2009.11.024

10.1007/s10853-008-2755-2

10.1021/ja01539a017

Pojanavaraphan T., 2008, Eur. Polym. J., 4, 39

10.1016/j.polymdegradstab.2005.12.001

10.1021/ja800745y

10.1016/j.carbon.2007.02.034

10.1021/la8000027

10.1016/j.carbon.2004.08.025

10.1021/ma902862u

10.1038/nnano.2008.96

10.1016/j.eurpolymj.2008.04.039

10.1007/s10853-006-0792-2

10.1179/146580109X12473409436580

10.1126/science.1157996

10.1103/PhysRevB.76.064120

10.1007/978-3-642-74434-1

10.1063/1.1723785

Treloar L. R. G., 1975, The Physics of Rubber Elasticity

Guth E., 1938, Phys. Rev., 53, 322

10.1063/1.1707495

10.1002/app.1962.070061906

10.1021/ma060407

10.1021/cm020093e

10.1021/jp709977m

10.1021/ma0355608

10.1063/1.1746537

10.1021/ma0303566

Ha M., 2008, Proceedings of PPS‐24

10.1021/nl0731872

10.1038/nmat996

10.1016/j.polymer.2004.03.088