Direct hydrogenation of CO2-rich scrubbing solvents to formate/formic acid over heterogeneous Ru catalysts: A sustainable approach towards continuous integrated CCU

IEA (2021), Global Energy Review: CO2 Emissions in 2020, IEA, Paris. Olah, 2011, Anthropogenic chemical carbon cycle for a sustainable future, J. Am. Chem. Soc., 133, 12881, 10.1021/ja202642y Artz, 2018, Sustainable conversion of carbon dioxide: an integrated review of catalysis and life cycle assessment, Chem. Rev., 118, 434, 10.1021/acs.chemrev.7b00435 Hansen, 2006, Global temperature change, Proc. Natl. Acad. Sci. U. S. A., 103, 14288, 10.1073/pnas.0606291103 Fang, 2018, Climate change, human impacts, and carbon sequestration in China, Proc. Natl. Acad. Sci. U. S. A., 115, 4015, 10.1073/pnas.1700304115 Florides, 2009, Global warming and carbon dioxide through sciences, Environ. Int., 35, 390, 10.1016/j.envint.2008.07.007 McCarthy, 2010, Climate change in cities due to global warming and urban effects, Geophys. Res. Lett., 37, 10.1029/2010GL042845 World Economic Forum (2014) Towards the circular economy: accelerating the scale-up across global supply chains. World Economic Forum. Gao, 2020, Industrial carbon dioxide capture and utilization: state of the art and future challenges, Chem. Soc. Rev., 49, 8584, 10.1039/D0CS00025F Yu, 2008, Recent advances in CO2 capture and utilization, ChemSusChem, 1, 893, 10.1002/cssc.200800169 Jangam, 2020, Conversion of CO2 to C1 chemicals: Catalyst design, kinetics and mechanism aspects of the reactions, Catal. Today, 358, 3, 10.1016/j.cattod.2019.08.049 Li, 2022, Research progress and reaction mechanism of CO2 methanation over Ni-based catalysts at low temperature: a review, Catalysts, 12 Shukla, 2019, Ionic liquids: potential materials for carbon dioxide capture and utilization, Front. Mater., 6, 10.3389/fmats.2019.00042 Borhani, 2015, CO2 capture with potassium carbonate solutions: a state-of-the-art review, Int. J. Greenhouse Gas Control, 41, 142 Yeganeh, 2022, Solid with infused reactive liquid (SWIRL): a novel liquid-based separation approach for effective CO2 capture, Sci. Adv., 8, 10.1126/sciadv.abm0144 Sun, 2021, Heterogeneous catalysts for CO2 hydrogenation to formic acid/formate: from nanoscale to single atom, Energy Environ. Sci., 14, 1247, 10.1039/D0EE03575K Song, 2006, Global challenges and strategies for control, conversion and utilization of CO2 for sustainable development involving energy, catalysis, adsorption and chemical processing, Catal. Today, 115, 2, 10.1016/j.cattod.2006.02.029 Preti, 2012, Conversion of syngas into formic acid, ChemCatChem, 4, 469, 10.1002/cctc.201200046 Huang, 2014, A review: CO2 utilization, Aerosol Air Qual. Res, 14, 480, 10.4209/aaqr.2013.10.0326 Formic acid Market - Growth, Trends, COVID-19 Impact, and Forecasts (2022 - 2027). Moret, 2014, Direct synthesis of formic acid from carbon dioxide by hydrogenation in acidic media, Nat. Commun., 5, 4017, 10.1038/ncomms5017 Chen, 2020, Sustainable production of formic acid from biomass and carbon dioxide, Mol. Catal., 483 Gunasekar, 2016, Recent developments in the catalytic hydrogenation of CO2 to formic acid/formate using heterogeneous catalysts, Inorg. Chem. Front., 3, 882, 10.1039/C5QI00231A Su, 2015, Highly efficient hydrogen storage system based on ammonium bicarbonate/formate redox equilibrium over palladium nanocatalysts, ChemSusChem, 8, 813, 10.1002/cssc.201403251 Yao, 2017, Highly-efficient and autocatalytic reduction of NaHCO3 into formate by in situ hydrogen from water splitting with metal/metal oxide redox cycle, J. Energy Chem., 26, 881, 10.1016/j.jechem.2017.08.011 Filonenko, 2016, On the activity of supported Au catalysts in the liquid phase hydrogenation of CO2 to formates, J. Catal., 343, 97, 10.1016/j.jcat.2015.10.002 Alvarez, 2017, Challenges in the greener production of formates/formic acid, methanol, and DME by heterogeneously catalyzed CO2 hydrogenation processes, Chem. Rev., 117, 9804, 10.1021/acs.chemrev.6b00816 Filonenko, 2014, Highly efficient reversible hydrogenation of carbon dioxide to formates using a ruthenium PNP-pincer catalyst, ChemCatChem, 6, 1526, 10.1002/cctc.201402119 Tanaka, 2009, Catalytic hydrogenation of carbon dioxide using Ir(III) -pincer complexes, J. Am. Chem. Soc., 131, 14168, 10.1021/ja903574e Zaidman, 1986, Formate salts as chemical carriers in hydrogen storage and transportation, Int. J. Hydrog. Energy, 11, 341, 10.1016/0360-3199(86)90154-0 Zhang, 2019, Support-dependent rate-determining step of CO2 hydrogenation to formic acid on metal oxide supported Pd catalysts, J. Catal., 376, 57, 10.1016/j.jcat.2019.06.048 Preti, 2011, Carbon dioxide hydrogenation to formic acid by using a heterogeneous gold catalyst, Angew. Chem., Int. Ed., 50, 12551, 10.1002/anie.201105481 Shao, 2016, Pd@C3N4 nanocatalyst for highly efficient hydrogen storage system based on potassium bicarbonate/formate, AIChE J., 62, 2410, 10.1002/aic.15218 Park, 2016, A highly active and stable palladium catalyst on a g-C3N4 support for direct formic acid synthesis under neutral conditions, Chem. Commun., 52, 14302, 10.1039/C6CC07401D Tshuma, 2020, Palladium(II) immobilized on metal-organic frameworks for catalytic conversion of carbon dioxide to formate, Inorg. Chem., 59, 6717, 10.1021/acs.inorgchem.9b03654 Li, 2018, Aperture-opening encapsulation of a transition metal catalyst in a metal-organic framework for CO2 hydrogenation, J. Am. Chem. Soc., 140, 8082, 10.1021/jacs.8b04047 Maru, 2021, A ruthenium-inserted hydrotalcite (Ru-HT) heterogeneous catalyst: kinetic studies on the selective hydrogenation of carbon dioxide to formic acid, Mater. Adv., 2, 5443, 10.1039/D1MA00431J Mitchell, 2019, Liquid phase hydrogenation of CO2 to formate using palladium and ruthenium nanoparticles supported on molybdenum carbide, New J. Chem., 43, 13985, 10.1039/C9NJ02114K Zhou, 2018, Pd nanoclusters-based catalysts with schiff base modifying carrier for CO2 hydrogenation to formic acid, Ind. Eng. Chem. Res., 58, 44, 10.1021/acs.iecr.8b04047 Mori, 2017, Isolated single-atomic Ru catalyst bound on a layered double hydroxide for hydrogenation of CO2 to formic acid, ACS Catal., 7, 3147, 10.1021/acscatal.7b00312 Gunasekar, 2019, Hydrogenation of CO2 to formate using a simple, recyclable, and efficient heterogeneous catalyst, Inorg. Chem., 58, 3717, 10.1021/acs.inorgchem.8b03336 Jaleel, 2020, Hydrogenation of CO2 to formates on ruthenium(III) coordinated on melamine polymer network, J. CO2 Util., 35, 245, 10.1016/j.jcou.2019.10.003 Li, 2013, In situ hydrogenation of captured CO2 to formate with polyethyleneimine and Rh/monophosphine system, Green. Chem., 15, 10.1039/c3gc41265b Kar, 2018, Capture, conversion, and utilization cycle with low-temperature regeneration of sodium hydroxide, J. Am. Chem. Soc., 140, 16873, 10.1021/jacs.8b09325 Kar, 2018, Integrative CO2 capture and hydrogenation to methanol with reusable catalyst and amine: toward a carbon neutral methanol economy, J. Am. Chem. Soc., 140, 1580, 10.1021/jacs.7b12183 Sen, 2020, Hydroxide based integrated CO2 capture from air and conversion to methanol, J. Am. Chem. Soc., 142, 4544, 10.1021/jacs.9b12711 Mani, 2022, Continuous hydrocyclization of aqueous levulinic acid to γ-valerolactone over bi-functional Ru/NbOPO4/SBA-15 catalyst under mild conditions, Appl. Catal. A, 643, 10.1016/j.apcata.2022.118744 Bui, 2020, Mesoporous melamine-formaldehyde resins as efficient heterogeneous catalysts for continuous synthesis of cyclic carbonates from epoxides and gaseous CO2, ACS Sustain. Chem. Eng., 8, 12852, 10.1021/acssuschemeng.0c03123 Mani, 2022, Ru-supported mesoporous melamine polymers as efficient catalysts for selective hydrogenation of aqueous 5-hydroxymethylfurfural to 2,5-bis-(hydroxymethyl)furan, Biomass. Convers. Biorefin., 10.1007/s13399-022-02768-8 Awasthi, 2021, Low-temperature hydrogen production from methanol over a ruthenium catalyst in water, Catal. Sci. Technol., 11, 136, 10.1039/D0CY01470B Chen, 2015, Ultra-high-performance core-shell structured Ru@Pt/C catalyst prepared by a facile pulse electrochemical deposition method, Sci. Rep., 5, 11604, 10.1038/srep11604 Oh, 2013, Dopamine-mediated sclerotization of regenerated chitin in ionic liquid, Materials, 6, 3826, 10.3390/ma6093826 Yin, 2017, Simple synthesis of porous melamine-formaldehyde resins by low temperature solvothermal method and its CO2 adsorption properties, Express Polym. Lett., 11, 873, 10.3144/expresspolymlett.2017.84 Chowdhury, 2013, CO2 capture by tertiary amine absorbents: a performance comparison study, Ind. Eng. Chem. Res., 52, 8323, 10.1021/ie400825u Bui, 2018, Switchable aqueous pentaethylenehexamine system for CO2 capture: an alternative technology with industrial potential, ACS Sustain. Chem. Eng., 6, 10395, 10.1021/acssuschemeng.8b01758 Wang, 2015, CO2 hydrogenation to formate and methanol as an alternative to photo- and electrochemical CO2 reduction, Chem. Rev., 115, 12936, 10.1021/acs.chemrev.5b00197 Federsel, 2010, Ruthenium-catalyzed hydrogenation of bicarbonate in water, ChemSusChem, 3, 1048, 10.1002/cssc.201000151 Chatterjee, 2016, RuIII(edta) catalyzed hydrogenation of bicarbonate to formate, J. Coord. Chem., 69, 650, 10.1080/00958972.2015.1125476