Digital light processing 3D printing of barium titanate/1,6-ethylene glycol diacrylate/polyethylene glycol (400) diacrylate nanocomposites

Springer Science and Business Media LLC - Tập 6 - Trang 1-9 - 2023
Cheng Chen1, Xi Wang1, Yan Wang1, Hongxi Gu1, Weixing Zhao1, Wenxiong Zhang2, Galhenage Asha Sewvandi3, Bo Wang4, Chunrui Ma5, Ming Liu5, Dengwei Hu1
1Faculty of Chemistry and Chemical Engineering, Key Laboratory of Functional Materials of Baoji, Engineering Research Center of Advanced Ferroelectric Functional Materials, Baoji University of Arts and Sciences, Baoji, People’s Republic of China
2Institute for Solid State Physics, The University of Tokyo, Koto, Japan
3Department of Materials Science and Engineering, Faculty of Engineering, University of Moratuwa, Katubedda, Sri Lanka
4State Key Laboratory for Mechanical Behavior of Materials, School of Materials Science and Engineering, Xi’an Jiaotong University, Xi’an, China
5School of Microelectronics, Xi’an Jiaotong University, Xi’an, China

Tóm tắt

Digital light processing (DLP) 3D printing technology is widely applied in the fabrication of ceramics owing to the good printing precision and printing speed. Barium titanate (BaTiO3, BT) has attracted extensive attention of researchers due to the good piezoelectric constant, strong dielectric constant, and ease of integration. Therefore, DLP 3D printing technology is combined with the production of BaTiO3/1,6-ethylene glycol diacrylate/Polyethylene glycol (400) diacrylate (BT/HDDA/PEG(400)DA) nanocomposites to improve the electrical properties. A preparation method for composite slurry with high fluidity, high solid content, and low viscosity is proposed by comparing the electrical properties of BT/HDDA/PEG(400)DA nanocomposite fabrication with different solid content. The work demonstrates that 67 wt% BT/HDDA/PEG(400)DA nanocomposites are better solid content to DLP 3D printing technology and the printed nanocomposite has the excellent electric properties. After a post-processing, the 67 wt% nanocomposite slurry shows the higher relative density (91.69%) and exhibits piezoelectric constant, remnant polarization, and dielectric constant of 151 pC/N, 17.4 μC/cm2, and 7712, respectively. The results suggest that the DLP 3D printing technology provides an alternative method for the fabrication of complex functionality nanocomposite piezoelectric elements.

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