Density and Viscosity of Mixtures of n-Hexane and 1-Hexanol from 303 to 423 K up to 50 MPa

International Journal of Thermophysics - Tập 23 - Trang 1537-1550 - 2002
F. Audonnet1, A. A. H. Pádua1
1Laboratoire de Thermodynamique des Solutions et des Polymères, Université Blaise Pascal, Clermont-Ferrand/CNRS, Aubière, France

Tóm tắt

Experimental results for the density and viscosity of n-hexane+1-hexanol mixtures are reported at temperatures from 303 to 423 K and pressures up to 50 MPa. The binary mixture was studied at three compositions, and measurements on pure 1-hexanol are also reported. The two properties were measured simultaneously using a single vibrating-wire sensor. The present results for density have a precision of ±0.07% and an estimated uncertainty of ±0.3%. The viscosity measurements have a precision of ±1% and an estimated uncertainty of ±4%. Representations of the density and viscosity of the mixture as a function of temperature and pressure are proposed using correlation schemes.

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Tài liệu tham khảo

C. Franjo, E. Jiménez, T. P. Iglesias, J. L. Legido, and M. I. Paz Andrade. J. Chem. Eng. Data 40:68 (1995).

M. A. Chowdhury, M. A. Majid, and M. A. Saleh. J. Chem. Thermodyn. 33:347 (2001).

A. Heintz, B. Schmittecker, D. Wagner, and R. N. Lichtenthaler. J. Chem. Eng. Data 31:487 (1986).

E. Jiménez, H. Casas, L. Segade, and C. Franjo. J. Chem. Eng. Data 45:862 (2000).

B. E. de Cominges, M. M. Piñeiro, L. Mosteiro, T. P. Iglesias, J. L. Legido, and M. I. Paz Andrade. J. Chem. Eng. Data 46:1206 (2001).

M. J. Assael, J. H. Dymond, and D. Exadaktilou. Int. J. Thermophys. 15:155 (1994).

I. Cibulka and L. Hn?dkovský. J. Chem. Eng. Data 41:657 (1996).

M. J. Assael, J. H. Dymond, M. Papadaki, and P. M. Patterson. Int. J. Thermophys. 13:269 (1992).

J. H. Dymond and M. J. Assael, in Transport Properties of Fluids-Their Correlation, Prediction and Estimation, J. Millat, J. H. Dymond, and C. A. Nieto de Castro, eds. (IUPAC, Cambridge University Press, Cambridge, 1996), Chap. 10, pp. 226–249.

A. A. Gylmanov, T. A. Apaev, L. A. Akhmedov, and S. I. Lipovetskii. Izv. Vyssh. Uchebn. Zaved. Neft Gaz 22:55 (1979).

S. K. Garg, T. S. Banipal, and J. C. Ahluwalia. J. Chem. Eng. Data 38:227 (1993).

S. Matsuo and T. Makita. Int. J. Thermophys. 10:885 (1989).

S. Matsuo and T. Makita. Int. J. Thermophys. 10:833 (1989).

A. A. H. Pádua, J. M. N. A. Fareleira, J. C. G. Calado, and W. A. Wakeham. Int. J. Thermophys. 15:229 (1994).

A. A. H. Pádua, J. M. N. A. Fareleira, J. C. G. Calado, and W. A. Wakeham. Int. J. Thermophys. 17:781 (1996).

A. A. H. Pádua, J. M. N. A. Fareleira, J. C. G. Calado, and W. A. Wakeham. J. Chem. Eng. Data 41:1488 (1996).

A. A. H. Pádua, J. M. N. A. Fareleira, J. C. G. Calado, and W. A. Wakeham. J. Chem. Eng. Data 41:731 (1996).

A. A. H. Pádua, J. M. N. A. Fareleira, J. C. G. Calado, and W. A. Wakeham. Rev. Sci. Instrum. 69:2392 (1998).

F. Audonnet and A. A. H. Pádua. Fluid Phase Equil. 181:147 (2001).

T. Retsina, S. M. Richardson, and W. A. Wakeham. Appl. Sci. Res. 43:127 (1986).

M. Dix, J. M. N. A. Fareleira, Y. Takaishi, and W. A. Wakeham. Int. J. Thermophys. 12:357 (1991).

J. H. Dymond and R. Malhotra. Int. J. Thermophys. 8:541 (1987).

I. Cibulka and M. Ziková. J. Chem. Eng. Data 39:876 (1994).

M. J. Assael, J. H. Dymond, and S. K. Polimatidou. Int. J. Thermophys. 15:189 (1994).