Degradation of rhodamine B photocatalyzed by hydrothermally prepared Pd-doped Bi2MoO6 nanoplates

Journal of the Australian Ceramic Society - Tập 58 Số 1 - Trang 71-82 - 2022
Phuruangrat, Anukorn1, Buapoon, Saowaluk1, Bunluesak, Thanaporn1, Suebsom, Piyada1, Thongtem, Somchai2,3, Thongtem, Titipun3,4
1Division of Physical Science, Faculty of Science, Prince of Songkla University, Hat Yai, Thailand
2Department of Physics and Materials Science, Faculty of Science, Chiang Mai University, Chiang Mai, Thailand
3Materials Science Research Center, Faculty of Science, Chiang Mai University, Chiang Mai, Thailand
4Department of Chemistry, Faculty of Science, Chiang Mai University, Chiang Mai, Thailand

Tóm tắt

0–5% Pd-doped Bi2MoO6 nanoplates as visible-light-driven photocatalysts were successfully prepared in this research. The XRD patterns of as-prepared Pd-doped Bi2MoO6 samples were indexed to pure orthorhombic Bi2MoO6 phase with no impurity detection. The Raman and FTIR wavenumbers of Pd-doped Bi2MoO6 nanoplates were significantly shifted by the change of energy bonds in Bi2MoO6 nanoplates, including the TEM characterization of the growth of nanoplates through the exposure {020} facet. Main symmetric stretching vibration of MoO6 containing in Pd-doped Bi2MoO6 nanoplates were also detected. XPS of 3% Pd-doped Bi2MoO6 nanoplates revealed the binding energies of Pd 3d5/2 and Pd 3d3/2 core levels, which are indicative of incorporated Pd2+ ions in Bi2MoO6 lattice. The photocatalytic activities of Bi2MoO6 with and without being loaded with Pd dopant monitored through the degradation of rhodamine B were increased from 38.36% for Bi2MoO6 to 97.12% for 3% Pd-doped Bi2MoO6 photodegraded by h+ and ·O2− main active radicals. The 3% Pd-doped Bi2MoO6 nanoplates were very stable and reusable for wastewater treatment.

Tài liệu tham khảo

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