Crystal structure of tris-(2,2′,2″)-triaminoethylamino-salicylidene iron(III) complex
Tóm tắt
Tris-(2,2′,2″)-triaminoethylamino-salicylidene iron(III) crystallizes in the monoclinic crystal system witha=7.766(2),b=25.423(5),c=13.318(5) Å, β=118.04(3)°, space group P21/c,V=2320.8(6) Å3,Z=4, andD
x=1.464 g cm−3. The center of the axially distorted octahedron is occupied by the Fe atom which is coordinated by six donor nitrogen and oxygen atoms infac positions. The planes of coordinated atoms (N and O) with the Fe(III) atom are almost planar and the maximum elevated atom from these planes is O(1) (−0.1065 Å).
Tài liệu tham khảo
Tweedle, M.F.; Wilson, L.J.,J. Am. Chem. Soc. 1976,98, 4824.
Calligaris, M.; Nardin, G.; Randaccio, C.,Coord, Chem. Rev. 1972,7, 385 and refs. therein.
Gündüz, N.; Gündüz, T.; Hursthouse, M.B.; Parkers, H.G.; Shaw, L.S.; Shaw, R.A.; Tüzün, M.J. Chem. Soc. Perkin Trans. II,1985, 899.
Sheldrick, G.M.,SHELXS-86: Program for crystal structure solution; Max Planck Institüt für Festkörperforschung: Stuttgart, Germany,1986.
Sheldrick, G.M.,SHELXL-93: Program for the refinement of crystal structures; Univ. of Göttingen: Germany,1993.
Ghiari, B.; Piovesana, O.; Tarantelli, T.; Zanazzi, P.F.Inorg. Chem. 1982,21, 1396.
Timken, M.D.; Marritt, W.A.; Hendrickson, D.N.; Gagne, R.A.; Sinn, E.Inorg. Chem. 1985,24, 4202.
Cook, F.D.; Cummins, D.; McKenzie, D.E.J. C. S. Dalton. 1976, 1369.
Huhey, J.E.Inorganic Chemistry. Harper Row Publishers: New York,1983; p 230.
Hoselton, M.A.; Wilson, L.J.; Drago, R.S.J. Am. Chem. Soc. 1975,97, 1722.
Broomhead, J.A.; Robinson, D.J.Aust. J. Chem. 1968,21, 1365.
Johnson, C.K.ORTEP II: Report-5138; Oak-Ridge National Laboratory: TN,1976.