Cracking of Cellulose over Supported Metal Catalysts
Tóm tắt
Cellulose is cracked over supported Pt or Ru catalysts under hydrogenolysis conditions in water to give sorbitol as a main product. Among the catalysts tested, Pt/γ-Al2O3 gave the highest yield and selectivity, and this catalyst was recyclable in repeated runs. It is proposed that cellulose is hydrolyzed by in situ generated acid sites to form glucose, and glucose is immediately reduced to sorbitol over the metal catalyst.
Tài liệu tham khảo
Klass DL (1998) Biomass for renewable energy, fuels, and chemicals. Academic Press, San Diego
Fan LT, Gharpuray MM, Lee Y-H (1987) Cellulose hydrolysis. Springer-Verlag, Berlin
Danner H, Braun R (1999) Chem Soc Rev 28:395
Zhang YP, Lynd LR (2004) Biotechnol Bioeng 88:797
Krässig HA (1993) Cellulose—structure, accessibility and reactivity. Gordon and Breach Science Pub., Yverdon
http://www1.eere.energy.gov/biomass/integrated_biorefineries.html
Dhepe PL, Ohashi M, Inagaki S, Ichikawa M, Fukuoka A (2005) Catal Lett 102:163
http://www.iogen.ca/
Saeman JF (1945) Ind Eng Chem 37:43
Asadullah M, Fujimoto K, Tomishige K (2001) Ind Eng Chem Res 40:5894
Garcia L, Salvador ML, Arauzo J, Bilbao R (1998) Ind Eng Chem Res 37:3812
Coughlan MP (1992) Biores Tech 39:107
Sasaki M, Fang Z, Fukushima Y, Adschiri T, Arai K (2000) Ind Eng Chem Res 39:2883
Sakaki T, Shibata M, Sumi T, Yasuda S (2002) Ind Eng Chem Res 41:661
Abbadi A, Gotlieb KF, van Bekkum H (1998) Starch 50:23
Fukuoka A, Dhepe PL (2006) Angew Chem Int Ed 45:5161
Jacobs P, Hinnekens H (Synfina-Oleofina), EP0329923 (1989)
Yan N, Zhao C, Luo C, Dyson P, Liu H, Kou Y (2006) J Am Chem Soc 128:8714
Hattori H, Shishido T (1997) Cata Surv Jpn 1:205
Werpy T, Petersen G (2004) Top value added chemicals from biomass, vol 1: results of screening for potential candidates from sugars and synthesis gas. US Department of Energy, Energy Efficiency and Renewable Energy, Battelle, http://www.eereweb.ee.doe.gov/biomass/pdfs/35523.pdf
Gallezot P, Cerino PJ, Blanc B, Flèche G, Fuertes P (1994) J Catal 146:93
Wulf PD, Soetaert W, Vandamme EJ (2000) Biotechnol Bioeng 69:339
Huber GW, Shabaker JW, Dumesic JA (2003) Science 300:2075
Davda RR, Dumesic JA (2004) Chem Commun 36
Brown AT, Patterson CE (1973) Archs Oral Biol 18:127
Kono H, Yunoki S, Shikano T, Fujiwara M, Erata T, Takai M (2002) J Am Chem Soc 124:7506
Zhao H, Kwak JH, Wang Y, Franz JA, White JM, Holladay JE (2006) Energy & Fuels 20:807