Chất xúc tác Mn-Co tương quan vượt trội hơn Pt trong phản ứng khử oxy của pin zinc-air bán rắn

Sun, W.; Wang, F.; Zhang, B.; Zhang, M. Y.; Küpers, V.; Ji, X.; Theile, C.; Bieker, P.; Xu, K.; Wang, C. S. et al. A rechargeable zinc-air battery based on zinc peroxide chemistry. Science 2021, 371, 46–51. Lyu, Z.; Koh, J. J.; Lim, G. J. H.; Zhang, D. W.; Xiong, T.; Zhang, L.; Liu, S. Q.; Duan, J. F.; Ding, J.; Wang, J. et al. Direct ink writing of programmable functional silicone-based composites for 4D printing applications. Interdiscip. Mater. 2022, 1, 507–516. Zhou, T. P.; Xu, W. F.; Zhang, N.; Du, Z. Y.; Zhong, C. G.; Yan, W. S.; Ju, H. X.; Chu, W. S.; Jiang, H.; Wu, C. Z. et al. Ultrathin cobalt oxide layers as electrocatalysts for high-performance flexible Zn-air batteries. Adv. Mater. 2019, 31, 1807468. Zhang, L.; Zhu, J. W.; Li, X.; Mu, S. C.; Verpoort, F.; Xue, J. M.; Kou, Z. K.; Wang, J. Nurturing the marriages of single atoms with atomic clusters and nanoparticles for better heterogeneous electrocatalysis. Interdiscip. Mater. 2022, 1, 51–87. Chen, M. X.; Zhu, M. Z.; Zuo, M.; Chu, S. Q.; Zhang, J.; Wu, Y. E.; Liang, H. W.; Feng, X. L. Identification of catalytic sites for oxygen reduction in metal/nitrogen-doped carbons with encapsulated metal nanoparticles. Angew. Chem., Int. Ed. 2020, 59, 1627–1633. Paul, R.; Zhai, Q. F.; Roy, A. K.; Dai, L. M. Charge transfer of carbon nanomaterials for efficient metal-free electrocatalysis. Interdiscip. Mater. 2022, 1, 28–50 Yang, Q.; Jia, Y.; Wei, F. F.; Zhuang, L. Z.; Yang, D. J.; Liu, J. Z.; Wang, X.; Lin, S.; Yuan, P.; Yao, X. D. Understanding the activity of Co−N4−xCx in atomic metal catalysts for oxygen reduction catalysis. Angew. Chem., Int. Ed. 2020, 59, 6122–6127. Zhao, M. Q.; Liu, H. R.; Zhang, H. W.; Chen, W.; Sun, H. Q.; Wang, Z. H.; Zhang, B.; Song, L.; Yang, Y.; Ma, C. et al. A pH-universal ORR catalyst with single-atom iron sites derived from a double-layer MOF for superior flexible quasi-solid-state rechargeable Zn-air batteries. Energy Environ. Sci. 2021, 14, 6455–6463. Sun, H. Q.; Zhao, M. Q.; Ma, C.; Chen, W.; Yang, Y.; Han, Y. H. Construction of ultra-stable NiFe armored catalyst for liquid and flexible quasi-solid-state rechargeable Zn-air batteries. Nano Res. 2023, 16, 4980–4986. Xu, Z. A.; Zhu, J.; Shao, J. Z.; Xia, Y.; Tseng, J.; Jiao, C. L.; Ren, G. Y.; Liu, P. F.; Li, G. S.; Chen, R. X. et al. Atomically dispersed cobalt in core–shell carbon nanofiber membranes as super-flexible freestanding air-electrodes for wearable Zn-air batteries. Energy Storage Mater. 2022, 47, 365–375. Pan, J.; Xu, Y. Y.; Yang, H.; Dong, Z. H.; Liu, H. F.; Xia, B. Y. Advanced architectures and relatives of air electrodes in Zn-air batteries. Adv. Sci. 2018, 5, 1700691. Han, J. X.; Meng, X. Y.; Lu, L.; Bian, J. J.; Li, Z. P.; Sun, C. W. Single-atom Fe−Nx−C as an efficient electrocatalyst for zinc-air batteries. Adv. Funct. Mater. 2019, 29, 1808872. Zhou, C. H.; Chen, X.; Liu, S.; Han, Y.; Meng, H. B.; Jiang, Q. Y.; Zhao, S. M.; Wei, F.; Sun, J.; Tan, T. et al. Superdurable bifunctional oxygen electrocatalyst for high-performance zinc-air batteries. J. Am. Chem. Soc. 2022, 144, 2694–2704. Lazaridis, T.; Stühmeier, B. M.; Gasteiger, H. A.; El-Sayed, H. A. Capabilities and limitations of rotating disk electrodes versus membrane electrode assemblies in the investigation of electrocatalysts. Nat. Catal. 2022, 5, 363–373. Ma, Q. L.; Mu, S. C. Acidic oxygen evolution reaction: Mechanism, catalyst classification, and enhancement strategies. Interdiscip. Mater. 2023, 2, 53–90 Zheng, X. R.; Cao, Y. H.; Wang, H. Z.; Zhang, J. F.; Zhao, M. H.; Huang, Z.; Wang, Y.; Zhang, L.; Deng, Y. D.; Hu, W. B. et al. Designing breathing air-electrode and enhancing the oxygen electrocatalysis by thermoelectric effect for efficient Zn-air batteries. Angew. Chem., Int. Ed. 2023, 62, e202302689. Li, Y. G.; Dai, H. J. Recent advances in zinc-air batteries. Chem. Soc. Rev. 2014, 43, 5257–5275. Wang, Y.; Yang, Y.; Jia, S. F.; Wang, X. M.; Lyu, K. J.; Peng, Y. Q.; Zheng, H.; Wei, X.; Ren, H.; Xiao, L. et al. Synergistic Mn−Co catalyst outperforms Pt on high-rate oxygen reduction for alkaline polymer electrolyte fuel cells. Nat. Commun. 2019, 10, 1506. Sun, S.; Yu, H. R.; Li, L. L.; Yu, X. F.; Zhang, X. H.; Lu, Z. M.; Yang, X. J. Sodium borohydride treatment to prepare manganese oxides with oxygen vacancy defects for efficient oxygen reduction. Metals 2022, 12, 1059. Guo, D. H.; Shibuya, R.; Akiba, C.; Saji, S.; Kondo, T.; Nakamura, J. J. Active sites of nitrogen-doped carbon materials for oxygen reduction reaction clarified using model catalysts. Science 2016, 351, 361–365. Xu, J. S.; Li, R.; Xu, C. Q.; Zeng, R. G.; Jiang, Z.; Mei, B. B.; Li, J.; Meng, D. Q.; Chen, J. Underpotential-deposition synthesis and inline electrochemical analysis of single-atom copper electrocatalysts. Appl. Catal. B: Environ. 2021, 289, 120028. Kimoto, K.; Asaka, T.; Nagai, T.; Saito, M.; Matsui, Y.; Ishizuka, K. Element-selective imaging of atomic columns in a crystal using STEM and EELS. Nature 2007, 450, 702–704. Liu, M. R.; Hong, Q. L.; Li, Q. H.; Du, Y. H.; Zhang, H. X.; Chen, S. M.; Zhou, T. H.; Zhang, J. Cobalt boron imidazolate framework derived cobalt nanoparticles encapsulated in B/N codoped nanocarbon as efficient bifunctional electrocatalysts for overall water splitting. Adv. Funct. Mater. 2018, 28, 1801136. Zhang, M. D.; Dai, Q. B.; Zheng, H. G.; Chen, M. D.; Dai, L. M. Novel MOF-derived Co@N−C bifunctional catalysts for highly efficient Zn-air batteries and water splitting. Adv. Mater. 2018, 30, 1705431. Wu, L. P.; Li, B.; Li, Y.; Fan, X. B.; Zhang, F. B.; Zhang, G. L.; Xia, Q.; Peng, W. C. Preferential growth of the cobalt (200) facet in Co@N−C for enhanced performance in a Fenton-like reaction. ACS Catal. 2021, 11, 5532–5543. Fernandes, C.; Pereira, C.; Fernández-García, M. P.; Pereira, A. M.; Guedes, A.; Fernández-Pacheco, R. F.; Ibarra, A.; Ibarra, M. R.; Araújo, J. P.; Freire, C. Tailored design of CoxMn1−xFe2O4 nanoferrites: A new route for dual control of size and magnetic properties. J. Mater. Chem. C 2014, 2, 5818–5828. Kou, Z. K.; Meng, T.; Guo, B. B.; Amiinu, I. S.; Li, W. Q.; Zhang, J.; Mu, S. C. A generic conversion strategy: From 2D metal carbides (MxCy) to M-self-doped graphene toward high-efficiency energy applications. Adv. Funct. Mater. 2017, 27, 1604904. Saka, C. Oxygen and nitrogen-doped metal-free microalgae carbon nanoparticles for efficient hydrogen production from sodium borohydride in methanol. Int. J. Hydrogen Energy 2021, 46, 26298–26307. Yuan, K.; Sfaelou, S.; Qiu, M.; Lützenkirchen-Hecht, D.; Zhuang, X. D.; Chen, Y. W.; Yuan, C.; Feng, X. L.; Scherf, U. Synergetic contribution of boron and Fe−Nx species in porous carbons toward efficient electrocatalysts for oxygen reduction reaction. ACS Energy Lett. 2018, 3, 252–260. Xie, Z. Z.; Shang, X. H.; Yang, J. M.; Hu, B.; Nie, P. F.; Jiang, W. W.; Liu, J. Y. 3D interconnected boron- and nitrogen-codoped carbon nanosheets decorated with manganese oxides for high-performance capacitive deionization. Carbon 2020, 158, 184–192 Zhao, Y.; Yang, L. J.; Chen, S.; Wang, X. Z.; Ma, Y. W.; Wu, Q.; Jiang, Y. F.; Qian, W. J.; Hu, Z. Can boron and nitrogen Co-doping improve oxygen reduction reaction activity of carbon nanotubes. J. Am. Chem. Soc. 2013, 135, 1201–1204. Zhao, R. P.; Chen, J. Y.; Chen, Z. J.; Jiang, X.; Fu, G. T.; Tang, Y. W.; Jin, W.; Lee, J. M.; Huang, S. M. Atomically dispersed CoN4/B, N-C nanotubes boost oxygen reduction in rechargeable Zn-air batteries. ACS Appl. Energy Mater. 2020, 3, 4539–4548. He, W. H.; Jiang, C. H.; Wang, J. B.; Lu, L. H. High-rate oxygen electroreduction over graphitic-N species exposed on 3D hierarchically porous nitrogen-doped carbons. Angew. Chem., Int. Ed. 2014, 53, 9503–9507. Yu, P.; Wang, L.; Sun, F. F.; Xie, Y.; Liu, X.; Ma, J. Y.; Wang, X. W.; Tian, C. G.; Li, J. H.; Fu, H. G. Co nanoislands rooted on Co−N−C nanosheets as efficient oxygen electrocatalyst for Zn-air batteries. Adv. Mater. 2019, 31, 1901666. Zeng, M.; Liu, Y. L.; Zhao, F. P.; Nie, K. Q.; Han, N.; Wang, X. X.; Huang, W. J.; Song, X. N.; Zhong, J.; Li, Y. G. Metallic cobalt nanoparticles encapsulated in nitrogen-enriched graphene shells: Its bifunctional electrocatalysis and application in zinc-air batteries. Adv. Funct. Mater. 2016, 26, 4397–4404. Liu, Z. J.; Zhao, Z. H.; Wang, Y. Y.; Dou, S.; Yan, D. F.; Liu, D. D.; Xia, Z. H.; Wang, S. Y. In situ exfoliated, edge-rich, oxygen-functionalized graphene from carbon fibers for oxygen electrocatalysis. Adv. Mater. 2017, 29, 1606207 Kurbatov, G.; Darque-Ceretti, E.; Aucouturier, M. Characterization of hydroxylated oxide film on iron surfaces and its acid-base properties using XPS. Surf. Interface Anal. 1992, 18, 811–820. Kang, D.; Rahimi, N.; Gordon, M. J.; Metiu, H.; McFarland, E. W. Catalytic methane pyrolysis in molten MnCl2−KCl. Appl. Catal. B: Environ. 2019, 254, 659–666. Andreev, A. S.; Kazakova, M. A.; Ishchenko, A. V.; Selyutin, A. G.; Lapina, O. B.; Kuznetsov, V. L.; De Lacaillerie, J. B. D. Magnetic and dielectric properties of carbon nanotubes with embedded cobalt nanoparticles. Carbon 2017, 114, 39–49. Zhang, W. M.; Yao, X. Y.; Zhou, S. N.; Li, X. W.; Li, L.; Yu, Z.; Gu, L. ZIF-8/ZIF-67-derived Co−Nx-embedded 1D porous carbon nanofibers with graphitic carbon-encased Co nanoparticles as an efficient bifunctional electrocatalyst. Small 2018, 14, 1800423. Zhou, Q. Y.; Cai, J. J.; Zhang, Z.; Gao, R.; Chen, B.; Wen, G. B.; Zhao, L.; Deng, Y. P.; Dou, H. Z.; Gong, X. F. et al. A gas-phase migration strategy to synthesize atomically dispersed Mn−N−C catalysts for Zn-air batteries. Small Methods 2021, 5, 2100024. Jiang, H.; Gu, J. X.; Zheng, X. S.; Liu, M.; Qiu, X. Q.; Wang, L. B.; Li, W. Z.; Chen, Z. F.; Ji, X. B.; Li, J. Defect-rich and ultrathin N doped carbon nanosheets as advanced trifunctional metal-free electrocatalysts for the ORR, OER and HER. Energy Environ. Sci. 2019, 12, 322–333.