Coriolis interaction between vibration and rotation in symmetric top molecules

The Royal Society - Tập 213 Số 1112 - Trang 55-73 - 1952
D. R. J. Boyd1, Hugh Christopher Longuet-Higgins2
1Physical Chemistry Laboratory, University of Oxford,
2Chemistry Department, University of Manchester.

Tóm tắt

The effect of Coriolis perturbations on the perpendicular infra-red bands of symmetric top molecules is studied in the first approximation. The sum of the Coriolis coefficients for the vibrations in any symmetry class is shown to assume an extremely simple form, and its value is given for the general case. A straightforward method is described for the calculation of first-order Coriolis coefficients, and rules are derived whereby the rotational spacing of an overtone or combination band may be calculated from the Coriolis coefficients of the component vibrations.

Từ khóa


Tài liệu tham khảo

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Thông tin
Thông tin xuất bản

The Royal Society

Tập 213 Số 1112

55-73

Thông tin tác giả