Containerless Measurements of Density and Viscosity for a Cu $$_{48}$$ Zr $$_{52}$$ Liquid
Tóm tắt
The densities of solid and liquid Cu
$$_{48}$$
Zr
$$_{52}$$
and the viscosity of the liquid were measured in a containerless electrostatic levitation system using optical techniques. The measured density of the liquid at the liquidus temperature (1223 K) is (7.02
$$\pm $$
0.01) g
$$\cdot $$
cm
$$^{-3}$$
and the density of the solid extrapolated to that temperature is (7.15
$$\pm $$
0.01) g
$$\cdot $$
cm
$$^{-3}$$
. The thermal expansion coefficients measured at 1223 K are (6.4
$$\pm $$
0.1)
$$\,\times \,10^{-5}$$
K
$$^{-1}$$
in the liquid phase and (3.5
$$\pm $$
0.3)
$$\,\times \,10^{-5}$$
K
$$^{-1}$$
in the solid phase. The viscosity of the liquid, measured with the oscillating drop technique, is of the form
$$A\exp \left[ \left( {{E}_{0}}+{{E}_{1}}\left( 1/T-1/{{T}_{0}} \right) \right) \times \left( 1/T-1/{{T}_{0}} \right) \right] $$
, where
$${{T}_{0}}=1223$$
K,
$$A= (0.0254 \pm 0.0004)$$
Pa
$$\cdot $$
s,
$${{E}_{0}}$$
= (8.43
$$\pm $$
0.26)
$$\,\times \,10^3$$
K and
$${{E}_{1}}$$
= (1.7
$$\pm $$
0.2)
$$\,\times 10^7$$
K
$$^{2}$$
.