Construction of nitrogen-doped carbon cladding LiMn2O4 film electrode with enhanced stability for electrochemically selective extraction of lithium ions

Springer Science and Business Media LLC - Tập 17 - Trang 2050-2060 - 2023
Jiahui Ren1, Yongping He2, Haidong Sun2, Rongzi Zhang2, Juan Li2, Wenbiao Ma1, Zhong Liu3, Jun Li3, Xiao Du1, Xiaogang Hao1
1College of Chemical Engineering and Technology, Taiyuan University of Technology, Taiyuan, China
2Academia Sinica, Qinghai Salt Lake Industry Group Company Limited, Golmud, China
3Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining, China

Tóm tắt

Reducing the dissolution of Mn from LiMn2O4 (LMO) and enhancing the stability of film electrodes are critical and challenging for Li+ ions selective extraction via electrochemically switched ion exchange technology. In this work, we prepared a nitrogen-doped carbon cladding LMO (C-N@LMO) by polymerization of polypyrrole and high-temperature annealing in the N2 gas to achieve the above purpose. The modified C-N@LMO film electrode exhibited lower Mn dissolution and better cyclic stability than the LMO film electrode. The dissolution ratio of Mn from the C-N@LMO film electrode decreased by 42% compared to the LMO film electrode after 10 cycles. The cladding layer not only acted as a protective layer but also functioned as a conductive shell, accelerating the migration rate of Li+ ions. The intercalation equilibrium time of the C-N@LMO film electrode reached within an hour during the extraction of Li+ ions, which was 33% less compared to the pure LMO film electrode. Meanwhile, the C-N@LMO film electrode retained evident selectivity toward Li+ ions, and the separation factor was 118.38 for Li+ toward Mg2+ in simulated brine. Therefore, the C-N@LMO film electrode would be a promising candidate for the recovery of Li+ ions from salt lakes.

Tài liệu tham khảo

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