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Xây dựng cấu trúc dị hợp cobalt sulfide/molybdenum disulfide làm vật liệu anot cho pin ion natri
Tóm tắt
Molybdenum disulfide đã được coi là ứng viên lý tưởng cho vật liệu anot cho pin ion kiềm nhờ vào cấu trúc lớp độc đáo cũng như khả năng lý thuyết đáng kể. Tuy nhiên, độ dẫn điện kém và sự nở thể tích lớn trong quá trình sạc/xả nhiều lần đã cản trở ứng dụng thực tiễn của nó. Trong nghiên cứu này, chúng tôi chế tạo một vật liệu anot dựa trên cobalt sulfide/molybdenum disulfide với cấu trúc dị hợp cho pin ion natri (SIBs), có thể được tạo ra bằng cách kết hợp phương pháp thủy nhiệt một bước với bước sulfid hóa rắn. So với các vật liệu anot dựa trên cobalt sulfide nguyên chất và molybdenum disulfide nguyên chất, vật liệu anot dựa trên cobalt sulfide/molybdenum disulfide thể hiện sự ổn định chu kỳ vượt trội (ví dụ, 510,9 mAh g−1 @1 A g−1 tại chu kỳ thứ 1000) và hiệu suất tần suất phi thường (341 mAh g−1 @10 A g−1). Các phép phân tích vật liệu cho thấy vật liệu cobalt sulfide/molybdenum disulfide thu được có nhiều lỗ xốp dạng meso. Phân tích động học càng xác nhận rằng điện trở truyền tải điện giảm và hệ số khuếch tán ion natri tăng lên theo chu kỳ cho vật liệu này. Do đó, thiết kế hợp lý cấu trúc dị hợp của cobalt sulfide/molybdenum disulfide có thể cung cấp nhiều vị trí hoạt động cho việc lưu trữ ion natri và tạo điều kiện cho hành vi kiểm soát dung lượng bề mặt. Nghiên cứu này cung cấp những hiểu biết hữu ích về việc sử dụng những vật liệu cấu trúc dị hợp này cho SIBs.
Từ khóa
#Molybdenum disulfide #cobalt sulfide #vật liệu anot #pin ion natri #cấu trúc dị hợp #tính ổn định chu kỳ.Tài liệu tham khảo
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