Complex Formation Equilibria of Amine-Bridged Dinuclearpalladium(II) Complexes with DNA Constituents

Journal of Solution Chemistry - Tập 40 - Trang 2023-2031 - 2011
Mahmoud M. A. Mohamed1, Mohamed M. Shoukry2
1Department of Sciences and Mathematics, Faculty of Education, Assiut University, New-Valley, Egypt
2Department of Chemistry, Faculty of Science, Cairo University, Giza, Egypt

Tóm tắt

The complex formation equilibria involving trans-diamminepalladium(II) chloride (PdII), 1,6-hexanediamine (HDA), and DNA constituents were investigated. The formation constant of all possible mononuclear and binuclear complexes were determined at 25 °C and 0.1 mol⋅L−1 NaNO3. The speciation diagrams of the binuclear complex of PdII–HDA–DNA reveal that these complexes predominate in the physiological pH range and the reaction of the binuclear complex PdII–HDA–PdII with DNA constituents is quite feasible.

Tài liệu tham khảo

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