Chlorination of Sulfonium Derivatives of closo-Decaborate Anion with Carboxyl-Containing Substituents
Tóm tắt
The reaction of sulfonium closo-decaborate derivatives containing carboxyl groups with sulfuryl chloride SO2Cl2 as a halogenating agent was studied. The reaction gave fully halogenated derivatives of the closo-decaborate anion, (n-Bu4N)[2-B10Cl9SR2] (R = –CH2COOEt, –CH2COOH), which was confirmed by 11B, 1H, and 13C NMR and IR spectral data. The structure of the [2-B10Cl9S(CH2COOEt)2]– anion was established using single crystal X-ray diffraction.
Tài liệu tham khảo
Sivaev, I.B., Prikaznov, A.V., and Naoufal, D., Collect. Czech. Chem. Commun., 2010, vol. 75, no. 11, pp. 1149–1199. https://doi.org/10.1135/cccc2010054
Avdeeva, V.V., Malinina, E.A., Sivaev, I.B., Bregadze, V.I., and Kuznetsov, N.T., Crystals, 2016, vol. 6, p. 60. https://doi.org/10.3390/cryst6050060
Avdeeva, V.V., Malinina, E.A., Zhizhin, K.Y., and Kuznetsov, N.T., Russ. J. Inorg. Chem., 2020, vol. 65, no. 4, pp. 514–534. https://doi.org/10.1134/S0036023620040026
Avdeeva, V.V., Polyakova, I.N., Churakov, A.V., Vologzhanina, A.V., Malinina, E.A., Zhizhin, K.Y., and Kuznetsov, N.T., Polyhedron, 2019, vol. 162, pp. 65–70. https://doi.org/10.1016/j.poly.2019.01.051
Kubasov, A.S., Golubev, A.V., Bykov, A.Yu., Matveev, E.Yu., Zhizhin, K.Yu., and Kuznetsov, N.T., J. Mol. Struct., 2021, vol. 1241, p. 130591. https://doi.org/10.1016/j.molstruc.2021.130591
Golubev, A.V., Kubasov, A.S., Bykov, A.Yu., Zhizhin, K.Yu., Kravchenko, E.A., Gippius, A.A., Zhurenko, S.V., Semenova, V.A., Korlyukov, A.A., and Kuznetsov, N.T., Inorg. Chem., 2021, vol. 60, no. 12, pp. 8592–8604. https://doi.org/10.1021/acs.inorgchem.1c00516
Kim, K.C., Reed, C.A., Long, G.S., and Sen, A., J. Am. Chem. Soc., 2002, vol. 124, no. 26, pp. 7662–7663. https://doi.org/10.1021/ja0259990
Reed, C.A., Acc. Chem. Res., 2010, vol. 43, no. 1, pp. 121–128. https://doi.org/10.1021/ar900159e
Ali, F., Hosmane, N.S., and Zhu, Y., Molecules, 2020, vol. 25, no. 4, p. 828. https://doi.org/10.3390/molecules25040828
Olejniczak, A.B., Nawrot, B., and Lesnikowski, Z.J., Int. J. Mol. Sci., 2018, vol. 19, p. 3501. https://doi.org/10.3390/ijms19113501
Kubasov, A.S., Matveev, E.Y., Turyshev, E.S., Polyakova, I.N., Nichugovskiy, A.I., Zhizhin, K.Y., and Kuznetsov, N.T., Inorg. Chim. Acta, 2018, vol. 477, pp. 277–283. https://doi.org/10.1016/j.ica.2018.03.013
Sheldrick, G.M., Acta Crystallogr., Sect. C: Struct. Chem., 2015, vol. 71, pp. 3–8. https://doi.org/10.1107/S2053229614024218
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J., Howard, J.A.K., and Puschmann, H., J. Appl. Crystallogr., 2009, vol. 42, no. 2, pp. 339–341. https://doi.org/10.1107/S0021889808042726