Chlorinated Effects of Double-Cable Conjugated Polymers on the Photovoltaic Performance in Single-Component Organic Solar Cells

Chinese Journal of Polymer Science - Tập 41 - Trang 187-193 - 2022
Han-Yi Bao1, Zhao-Fan Yang2, Yan-Jiao Zhao1, Xiang Gao1, Xin-Zhu Tong1, Yi-Nuo Wang1, Feng-Bo Sun1, Jian-Hong Gao1, Wei-Wei Li2, Zhi-Tian Liu1
1Hubei Engineering Technology Research Center of Optoelectronic and New Energy Materials, Hubei Key Laboratory of Plasma Chemistry and Advanced Materials, School of Materials Science and Engineering, Wuhan Institute of Technology, Wuhan, China
2Beijing Advanced Innovation Center for Soft Matter Science and Engineering & State Key Laboratory of Organic-Inorganic Composite, Beijing University of Chemical Technology, Beijing, China

Tóm tắt

The recently emerged double-cable conjugated polymers have come into focus due to their significantly improved power conversion efficiencies (PCEs) in single-component organic solar cells (SCOSCs). In this work, the effect of chlorination in double-cable conjugated polymers with linear benzodithiophene backbone and pendant perylene bisimide on the photovoltaic performance in SCOSCs has been studied. After introducing chlorine atoms into conjugated side chains, the highest occupied molecular orbital level of the conjugated polymers is down-shifted, thus resulting in a higher open-circuit voltage. As a result, the chlorinated double-cable conjugated polymer exhibits improved photovoltaic performance from 3.46% to 3.57%.

Tài liệu tham khảo

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