Chemical upgrade of carbon monoxide to acetate on an atomically dispersed copper catalyst via CO-insertion

Ross, 2019, Designing materials for electrochemical carbon dioxide recycling, Nat Catal, 2, 648, 10.1038/s41929-019-0306-7 Birdja, 2019, Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels, Nat Energy, 4, 732, 10.1038/s41560-019-0450-y Jiao, 2017, Molecular scaffolding strategy with synergistic active centers to facilitate electrocatalytic CO2 reduction to hydrocarbon/alcohol, J. Am. Chem. Soc., 139, 18093, 10.1021/jacs.7b10817 Tackett, 2019, Net reduction of CO2 via its thermocatalytic and electrocatalytic transformation reactions in standard and hybrid processes, Nat Catal, 2, 381, 10.1038/s41929-019-0266-y Larrazabal, 2017, Building blocks for high performance in electrocatalytic CO2 reduction: materials, optimization strategies, and device engineering, J. Phys. Chem. Lett., 8, 3933, 10.1021/acs.jpclett.7b01380 Wu, 2019, Domino electroreduction of CO2 to methanol on a molecular catalyst, Nature, 575, 639, 10.1038/s41586-019-1760-8 Nitopi, 2019, Progress and perspectives of electrochemical CO2 reduction on copper in aqueous electrolyte, Chem. Rev., 119, 7610, 10.1021/acs.chemrev.8b00705 Li, 2020, Molecular tuning of CO2-to-ethylene conversion, Nature, 577, 509, 10.1038/s41586-019-1782-2 Peterson, 2012, Activity descriptors for CO2 electroreduction to methane on transition-metal catalysts, J. Phys. Chem. Lett., 3, 251, 10.1021/jz201461p Montoya, 2015, Theoretical insights into a CO dimerization mechanism in CO2 electroreduction, J. Phys. Chem. Lett., 6, 2032, 10.1021/acs.jpclett.5b00722 Karamad, 2014, Intermetallic alloys as CO electroreduction catalysts-role of isolated active sites, ACS Catal., 4, 2268, 10.1021/cs500328c Jouny, 2018, High-rate electroreduction of carbon monoxide to multi-carbon products, Nat Catal, 1, 748, 10.1038/s41929-018-0133-2 Cuellar, 2019, Advantages of CO over CO2 as reactant for electrochemical reduction to ethylene, ethanol and n-propanol on gas diffusion electrodes at high current densities, Electrochim. Acta, 307, 164, 10.1016/j.electacta.2019.03.142 Raciti, 2017, Low-overpotential electroreduction of carbon monoxide using copper nanowires, ACS Catal., 7, 4467, 10.1021/acscatal.7b01124 Luc, 2019, Two-dimensional copper nanosheets for electrochemical reduction of carbon monoxide to acetate, Nat Catal, 2, 423, 10.1038/s41929-019-0269-8 Jouny, 2019, Carbon monoxide electroreduction as an emerging platform for carbon utilization, Nat Catal, 2, 1062, 10.1038/s41929-019-0388-2 Fu, 2021, Engineering, Electrochemical reduction of CO2 towards multi-carbon products via a two-step process, React Chem Eng, 10.1039/D1RE00001B Wang, 2019, Ensemble effect in bimetallic electrocatalysts for CO2 reduction, J. Am. Chem. Soc., 141, 16635, 10.1021/jacs.9b05766 Zhang, 2018, Electrochemical reduction of carbon dioxide to methanol on hierarchical Pd/SnO2 nanosheets with abundant Pd-O-Sn interfaces, Angew. Chem. Int. Ed., 57, 9475, 10.1002/anie.201804142 Wang, 2019, Copper nanocubes for CO2 reduction in gas diffusion electrodes, Nano Lett., 19, 8461, 10.1021/acs.nanolett.9b02748 Xie, 2018, Cu-based nanocatalysts for electrochemical reduction of CO2, Nano Today, 21, 41, 10.1016/j.nantod.2018.05.001 Reske, 2014, Particle size effects in the catalytic electroreduction of CO2 on Cu nanoparticles, J. Am. Chem. Soc., 136, 6978, 10.1021/ja500328k de Arquer, 2020, CO2 electrolysis to multicarbon products at activities greater than 1 A cm-2, Science, 367, 661, 10.1126/science.aay4217 Li, 2020, Electrochemically scrambled nanocrystals are catalytically active for CO2-to-multicarbons, P Natl Acad Sci USA, 117, 9194, 10.1073/pnas.1918602117 Liu, 2017, Shape-dependent electrocatalytic reduction of CO2 to CO on triangular silver nanoplates, J. Am. Chem. Soc., 139, 2160, 10.1021/jacs.6b12103 Feng, 2015, Grain-boundary-dependent CO2 electroreduction activity, J. Am. Chem. Soc., 137, 4606, 10.1021/ja5130513 Zhang, 2019, A graphene-supported single-atom FeN5 catalytic site for efficient electrochemical CO2 reduction, Angew. Chem. Int. Ed., 58, 14871, 10.1002/anie.201906079 Lu, 2020, Electrocatalysis of single-atom sites: impacts of atomic coordination, ACS Catal., 10, 7584, 10.1021/acscatal.0c01950 Liu, 2020, Recent advances in atomic-level engineering of nanostructured catalysts for electrochemical CO2 reduction, Adv. Funct. Mater., 30, 1910534, 10.1002/adfm.201910534 Xiong, 2020, Single-atom Rh/N-doped carbon electrocatalyst for formic acid oxidation, Nat. Nanotechnol., 15, 390, 10.1038/s41565-020-0665-x Duchesne, 2018, Golden single-atomic-site platinum electrocatalysts, Nat. Mater., 17, 1033, 10.1038/s41563-018-0167-5 Zhao, 2020, Atomic site electrocatalysts for water splitting, oxygen reduction and selective oxidation, Chem. Soc. Rev., 49, 2215, 10.1039/C9CS00869A Li, 2018, Atomically dispersed manganese catalysts for oxygen reduction in proton-exchange membrane fuel cells, Nat Catal, 1, 935, 10.1038/s41929-018-0164-8 Zhao, 2020, Selective electroreduction of CO2 to acetone by single copper atoms anchored on N-doped porous carbon, Nat. Commun., 11, 2455, 10.1038/s41467-020-16381-8 Rong, 2021, Size-dependent activity and selectivity of atomic-level copper nanoclusters during CO/CO2 electroreduction, Angew. Chem. Int. Ed., 60, 466, 10.1002/anie.202011836 Jiao, 2019, Copper atom-pair catalyst anchored on alloy nanowires for selective and efficient electrochemical reduction of CO2, Nat. Chem., 11, 222, 10.1038/s41557-018-0201-x Zheng, 2020, Atomically defined undercoordinated active sites for highly efficient CO2 electroreduction, Adv. Funct. Mater., 30, 1907658, 10.1002/adfm.201907658 Ma, 2020, Covalent triazine framework confined copper catalysts for selective electrochemical CO2 reduction: operando diagnosis of active sites, ACS Catal., 10, 4534, 10.1021/acscatal.0c00243 Zhang, 2020, Highly dispersed, single-site copper catalysts for the electroreduction of CO2 to methane, J. Electroanal. Chem., 113862, 10.1016/j.jelechem.2020.113862 Wang, 2018, Single-atomic Cu with multiple oxygen vacancies on ceria for electrocatalytic CO2 reduction to CH4, ACS Catal., 8, 7113, 10.1021/acscatal.8b01014 Zhang, 2018, Preassembly strategy to fabricate porous hollow carbonitride spheres inlaid with single Cu-N3 sites for selective oxidation of benzene to phenol, J. Am. Chem. Soc., 140, 16936, 10.1021/jacs.8b10703 Li, 2018, Boosting oxygen reduction catalysis with abundant copper single atom active sites, Energy Environ. Sci., 11, 2263, 10.1039/C8EE01169A Yin, 2016, Single cobalt atoms with precise N-coordination as superior oxygen reduction reaction catalysts, Angew. Chem. Int. Ed., 55, 10800, 10.1002/anie.201604802 Qin, 2018, Strategies for stabilizing atomically dispersed metal catalysts, Small Methods, 2, 1700286, 10.1002/smtd.201700286 Zheng, 2019, Understanding the roadmap for electrochemical reduction of CO2 to multi-carbon oxygenates and hydrocarbons on copper-based catalysts, J. Am. Chem. Soc., 141, 7646, 10.1021/jacs.9b02124 Hori, 1997, Electrochemical reduction of CO at a copper electrode, J. Phys. Chem. B, 101, 7075, 10.1021/jp970284i Ma, 2016, One-step electrosynthesis of ethylene and ethanol from CO2 in an alkaline electrolyzer, J. Power Sources, 301, 219, 10.1016/j.jpowsour.2015.09.124 Shan, 2017, Mild oxidation of methane to methanol or acetic acid on supported isolated rhodium catalysts, Nature, 551, 605, 10.1038/nature24640 Ren, 2016, Tuning the selectivity of carbon dioxide electroreduction toward ethanol on oxide-derived CuxZn catalysts, ACS Catal., 6, 8239, 10.1021/acscatal.6b02162 Handoko, 2017, CH3 mediated pathway for the electroreduction of CO2 to ethane and ethanol on thick oxide-derived copper catalysts at low overpotentials, ACS Energy Lett, 2, 2103, 10.1021/acsenergylett.7b00514 Li, 2019, Effectively increased efficiency for electroreduction of carbon monoxide using supported polycrystalline copper powder electrocatalysts, ACS Catal., 9, 4709, 10.1021/acscatal.9b00099 Li, 2019, Constraining CO coverage on copper promotes high-efficiency ethylene electroproduction, Nat Catal, 2, 1124, 10.1038/s41929-019-0380-x Liu, 2019, pH effects on the electrochemical reduction of CO2 towards C2 products on stepped copper, Nat. Commun., 10, 32, 10.1038/s41467-018-07970-9 Zhi, 2021, Directing selectivity of CO2 electroreduction to target C2 products via non-metal doping on Cu surfaces, J. Mater. Chem., 9, 6345, 10.1039/D0TA11604A Li, 2019, Atomically dispersed platinum supported on curved carbon supports for efficient electrocatalytic hydrogen evolution, Nat Energy, 4, 512, 10.1038/s41560-019-0402-6 Yang, 2019, Directly transforming copper (I) oxide bulk into isolated single-atom copper sites catalyst through gas-transport approach, Nat. Commun., 10, 3734, 10.1038/s41467-019-11796-4