Catalytic oxidation of alkanes by a (salen)osmium(<scp>vi</scp>) nitrido complex using H<sub>2</sub>O<sub>2</sub>as the terminal oxidant

Chemical Communications - Tập 51 Số 71 - Trang 13686-13689
Man Chen1,2,3,4,5, Yi Pan6,7,2,8, Hoi‐Ki Kwong6,7,2,8, Raymond Jianxiong Zeng1,9,3,4,5, Kai‐Chung Lau6,7,2,8, Tai‐Chu Lau1,10,2,4,5
1Advanced Laboratory for Environmental Research & Technology (ALERT), USTC-CityU, Suzhou 215123, China
2Department of Biology and Chemistry and Institute of Molecular Functional Materials, City University of Hong Kong, Tat Chee Avenue, Kowloon Tong, Hong Kong SAR, China
3Department of Chemistry, University of Science & Technology of China, Hefei 230026, China
4Suzhou 215123
5USTC-CityU
6China
7City University of Hong Kong,
8Hong Kong SAR
9Department of Chemistry
10Department of Biology and Chemistry and Institute of Molecular Functional Materials

Tóm tắt

A (salen)osmium(vi) nitrido complex functions as an efficient catalyst for the oxidation of alkanes under ambient conditions using H2O2as the oxidant.

Từ khóa


Tài liệu tham khảo

A. E. Shilov and G. B.Shul’pin, Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes, Kluwer, Boston, 2000

K. I. Goldberg and A. S.Goldman, Activation and Functionalization of C–H Bonds, ACS Symposium Series 885, American Chemical Society, Washington, DC, 2004

P. R. Ortiz de Montellano , Cytochrome P450. Structure, Mechanism and Biochemistry, Plenum Press, New York, 2005

J. L. McLain , J.Lee and J. T.Groves, in Biomimetic Oxidations Catalyzed by Transition Metal Complexes, ed. B. Meunier, Imperial College Press, London, 2000, pp. 91–170

Baik, 2003, Chem. Rev., 103, 2385, 10.1021/cr950244f

Kamata, 2010, Nat. Chem., 2, 478, 10.1038/nchem.648

Shul’pin, 2009, Inorg. Chem., 48, 10480, 10.1021/ic901576r

Gomez, 2009, Angew. Chem., Int. Ed., 48, 5720, 10.1002/anie.200901865

Chen, 2007, Science, 318, 783, 10.1126/science.1148597

Kirillov, 2005, Angew. Chem., Int. Ed., 44, 4345, 10.1002/anie.200500585

Kim, 1997, J. Am. Chem. Soc., 119, 5964, 10.1021/ja9642572

Yiu, 2008, J. Am. Chem. Soc., 130, 10821, 10.1021/ja802625e

Ma, 2014, J. Am. Chem. Soc., 136, 7680, 10.1021/ja5019546

Samsel, 1985, J. Am. Chem. Soc., 107, 7606, 10.1021/ja00311a064

Srinivasan, 1986, J. Am. Chem. Soc., 108, 2309, 10.1021/ja00269a029

Zhang, 1990, J. Am. Chem. Soc., 112, 2801, 10.1021/ja00163a052

Irie, 1991, Tetrahedron Lett., 32, 1055, 10.1016/S0040-4039(00)74486-8

Man, 2010, Dalton Trans., 39, 11163, 10.1039/c0dt00481b

R. A. Sheldon and J. K.Kochi, Metal-Catalyzed Oxidations of Organic Compounds, Academic Press, New York, 1981, pp. 17–32

Arends, 1995, J. Am. Chem. Soc., 117, 4710, 10.1021/ja00121a031

MacFaul, 1997, J. Am. Chem. Soc., 119, 10594, 10.1021/ja963627j

K. U. Ingold and P. A.MacFaul, in Biomimetic Oxidations Catalyzed by Transition Metal Complexes, ed. B. Meunier, Imperial College Press, London, 2000, pp. 45–89

DiPasquale, 2008, J. Am. Chem. Soc., 130, 1812, 10.1021/ja077598w

Kwong, 2011, Chem. Commun., 47, 4273, 10.1039/c0cc05487a