Catalytic deoxygenation of fatty acids and their derivatives to hydrocarbon fuels via decarboxylation/decarbonylation

Journal of Chemical Technology and Biotechnology - Tập 87 Số 8 - Trang 1041-1050 - 2012
Eduardo Santillan‐Jimenez1, Mark Crocker1
1Center for Applied Energy Research; University of Kentucky; Lexington KY 40511 USA

Tóm tắt

AbstractFatty acids and their derivatives can be converted to renewable and carbon‐neutral fuel‐like hydrocarbons that are entirely fungible with fossil fuels. Typically, these hydrocarbon‐based biofuels are obtained through hydrotreating, a method which has the significant disadvantages of requiring problematic sulfided catalysts and high pressures of hydrogen. In recent years, decarboxylation/decarbonylation has been proposed as an alternative method, as this approach has the advantages of permitting the use of simpler catalysts and requiring less hydrogen than hydrotreating. In this contribution, the deoxygenation of fatty acids and their derivatives to fuel‐like hydrocarbons via decarboxylation/decarbonylation is critically reviewed. The main aspects discussed include the influence of the feed, catalyst, reactor system and reaction conditions on the decarboxylation/decarbonylation reaction, as well as the reaction mechanism and catalyst deactivation/regeneration. Copyright © 2012 Society of Chemical Industry

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Tài liệu tham khảo

Goodall BL, 2010, Thermochemical Conversion of Biomass to Liquid Fuels and Chemicals, v

10.1039/B814123A

Bertram SH, 1936, Action of selenium on stearic acid, Chem Week, 33, 457

10.1007/BF02635473

10.1002/cber.19821150245

SternRandHillionG Process for manufacturing a linear olefin from a saturated fatty acid or fatty acid ester. US Patent Number 4554397 (1985).

10.1007/s11244-008-9159-z

10.1016/j.apcata.2007.07.002

10.1134/S0965544110040080

10.1021/ef100576z

10.1002/cssc.200900107

10.1007/s11244-010-9581-x

10.1021/ef200380w

Na J‐G, Decarboxylation of microalgal oil without hydrogen into hydrocarbon for the production of transportation fuel, Catal Today

10.1007/s10562-009-9900-7

10.1021/ef060455v

10.1039/9781849732260-00496

10.1016/j.fuel.2008.07.004

MurzinDY KubickováI SnåreM Mäki‐ArvelaPandMyllyojaJ Method for the manufacture of hydrocarbons. US Patent Number 7491858 (2009).

10.1007/s10562-009-9889-y

10.1016/j.apcata.2008.12.001

10.1002/cssc.201000370

10.1016/j.cattod.2009.07.064

10.1016/j.fuel.2007.06.006

10.1016/j.apcata.2009.12.028

10.1007/s11244-011-9608-y

10.1039/b923198f

10.1021/ie060334i

10.1134/S0965544111050069

10.1007/s10562-009-0248-9

10.1016/j.apcata.2011.01.042

LestariS BeltraminiJandLuGQ Preparation and characterization of mesoporous Ni/Zr‐laponite for the catalytic deoxygenation of vegetable oils into liquid hydrocarbons in International Conference on Nanoscience and Nanotechnology ICONN ‘06 (2006).

10.1016/j.cattod.2009.03.002

10.1016/j.cattod.2010.10.048

10.1007/s11244-010-9456-1

10.1016/j.cattod.2005.07.188

10.1007/s10562-008-9457-x

10.1016/j.fuel.2009.11.006

10.1021/ef900110t

10.1016/j.fuel.2010.10.025

10.1016/j.apcata.2009.12.005

10.1016/j.fuel.2010.05.033

10.1016/S1381-1169(02)00447-8

10.1021/ef00053a026

10.1021/jp051973u

10.1016/j.biortech.2006.10.025

10.1021/ef00054a024

10.1016/j.fuel.2008.10.022

10.1016/j.apcata.2011.02.025

10.1246/bcsj.44.1606

10.1016/0920-5861(89)80017-3

10.1016/j.cej.2012.02.027

10.1016/j.cej.2007.03.064

10.1039/b910806h

http://www.avjetbiotech.com/[accessed December 2011].

http://www.redwolfrefining.com/[accessed December 2011].

Smejkal Q, 2009, Thermodynamic balance in reaction system of total vegetable oil hydrogenation, Chem Eng J, 146, 155

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Thông tin xuất bản

Journal of Chemical Technology and Biotechnology

Tập 87 Số 8

1041-1050

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