Catalysis using colloidal-supported gold-based nanoparticles
Tóm tắt
The discovery of novel m aterials that can be active, selective and stable catalysts for the efficient transformation of organic molecules to useful products is of high importance. In recent years, there has been significant interest in the utilisation of supported gold-based nanoparticles that can be effective catalysts for a broad range of chemical processes. In this paper, we describe and discuss the utilisation of gold-based nanoparticles as efficient catalysts for a range of important reactions, with particular emphasis placed on our team recent research.
Tài liệu tham khảo
Bond GC, Thompson DT (1999) Catalysis by gold. Catal Rev Sci Eng 41:319–388
Bond GC, Sermon PA, Webb G, Buchanan DA, Wells PB (1973) Hydrogenation over supported gold catalysts. J Chem Soc Chem Commun (13):444-445
Hutchings GJ (1985) Vapor-phase hydrochlorination of acetylene—correlation of catalytic activity of supported metal chloride catalysts. J Catal 96:292–295
Haruta M, Kobayashi T, Sano H, Yamada N (1987) Novel gold catalysts for the oxidation of carbon-monoxide at a temperature far below 0 °C. Chem Lett 16:405–408
Hashmi ASK, Hutchings GJ (2006) Gold catalysis. Angew Chem Int Ed 45:7896–7936
Della Pina C, Falletta E, Prati L, Rossi M (2008) Selective oxidation using gold. Chem Soc Rev 37:2077–2095
Herzing AA, Kiely CJ, Carley AF, Landon P, Hutchings GJ (2008) Identification of active gold nanoclusters on iron oxide supports for CO oxidation. Science 321:1331–1335
Xie XW, Li Y, Liu ZQ, Haruta M, Shen WJ (2009) Low-temperature oxidation of CO catalysed by Co3O4 nanorods. Nature 458:746–749
Haruta M (2011) Spiers memorial lecture role of perimeter interfaces in catalysis by gold nanoparticles. Faraday Discuss 152:11–32
Yoshida H, Kuwauchi Y, Jinschek JR et al (2012) Visualizing gas molecules interacting with supported nanoparticulate catalysts at reaction conditions. Science 335:317–319
Akita T, Kohyama M, Haruta M (2013) Electron microscopy study of gold nanoparticles deposited on transition metal oxides. Acc Chem Res 46:1773–1782
Abad A, Concepcion P, Corma A, Garcia H (2005) A collaborative effect between gold and a support induces the selective oxidation of alcohols. Angew Chem Int Ed 44:4066–4069
Carrettin S, McMorn P, Johnston P, Griffin K, Hutchings GJ (2002) Selective oxidation of glycerol to glyceric acid using a gold catalyst in aqueous sodium hydroxide. Chem Commun 7:696–697
Sinha AK, Seelan S, Tsubota S, Haruta M (2004) A three-dimensional mesoporous titanosilicate support for gold nanoparticles: vapor-phase epoxidation of propene with high conversion. Angew Chem Int Ed 43:1546–1548
Hughes MD, Xu YJ, Jenkins P et al (2005) Tunable gold catalysts for selective hydrocarbon oxidation under mild conditions. Nature 437:1132–1135
Nkosi B, Adams MD, Coville NJ, Hutchings GJ (1991) Hydrochlorination of acetylene using carbon-supported gold catalysts—a study of catalyst reactivation. J Catal 128:378–386
Corma A, Serna P (2006) Chemoselective hydrogenation of nitro compounds with supported gold catalysts. Science 313:332–334
Landon P, Collier PJ, Papworth AJ, Kiely CJ, Hutchings GJ (2002) Direct formation of hydrogen peroxide from H-2/O-2 using a gold catalyst. Chem Commun (18):2058–2059
Enache DI, Edwards JK, Landon P et al (2006) Solvent-free oxidation of primary alcohols to aldehydes using Au-Pd/TiO2 catalysts. Science 311:362–365
Edwards JK, Solsona BE, Landon P et al (2005) Direct synthesis of hydrogen peroxide from H-2 and O-2 using TiO2-supported Au–Pd catalysts. J Catal 236:69–79
Edwards JK, Solsona B, En N et al (2009) Switching off hydrogen peroxide hydrogenation in the direct synthesis process. Science 323:1037–1041
Edwards JK, Ntainjua E, Carley AF, Herzing AA, Kiely CJ, Hutchings GJ (2009) Direct Synthesis of H2O2 from H-2 and O-2 over Gold, Palladium, and Gold-Palladium Catalysts Supported on Acid-Pretreated TiO2. Angew Chem Int Ed 48:8512–8515
Mallat T, Baiker A (2004) Oxidation of alcohols with molecular oxygen on solid catalysts. Chem Rev 104:3037–3058
Dimitratos N, Lopez-Sanchez JA, Hutchings GJ (2012) Selective liquid phase oxidation with supported metal nanoparticles. Chem Sci 3:20–44
Daniel MC, Astruc D (2004) Gold nanoparticles: assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology. Chem Rev 104:293–346
Lopez-Sanchez JA, Dimitratos N, Miedziak P et al (2008) Au–Pd supported nanocrystals prepared by a sol immobilisation technique as catalysts for selective chemical synthesis. Phys Chem Chem Phys 10:1921–1930
Dimitratos N, Lopez-Sanchez JA, Morgan D et al (2009) Solvent-free oxidation of benzyl alcohol using Au–Pd catalysts prepared by sol immobilisation. Phys Chem Chem Phys 11:5142–5153
Tiruvalam RC, Pritchard JC, Dimitratos N et al (2011) Aberration corrected analytical electron microscopy studies of sol-immobilized Au plus Pd, Au(Pd) and Pd(Au) catalysts used for benzyl alcohol oxidation and hydrogen peroxide production. Faraday Discuss 152:63–86
Meenakshisundaram S, Nowicka E, Miedziak PJ et al (2010) Oxidation of alcohols using supported gold and gold–palladium nanoparticles. Faraday Discuss 145:341–356
He Q, Miedziak PJ, Kesavan L et al (2013) Switching-off toluene formation in the solvent-free oxidation of benzyl alcohol using supported trimetallic Au–Pd–Pt nanoparticles. Faraday Discuss 162:365–378
Zhou CHC, Beltramini JN, Fan YX, Lu GQM (2008) Chemoselective catalytic conversion of glycerol as a biorenewable source to valuable commodity chemicals. Chem Soc Rev 37:527–549
Dimitratos N, Lopez-Sanchez JA, Anthonykutty JM et al (2009) Oxidation of glycerol using gold–palladium alloy-supported nanocrystals. Phys Chem Chem Phys 11:4952–4961
Brett GL, He Q, Hammond C et al (2011) Selective oxidation of glycerol by highly active bimetallic catalysts at ambient temperature under base-free conditions. Angew Chem Int Ed 50:10136–10139
Kesavan L, Tiruvalam R, Ab Rahim MH et al (2011) Solvent-free oxidation of primary carbon–hydrogen bonds in toluene using Au–Pd alloy nanoparticles. Science 331:195–199
bin Saiman MI, Brett GL, Tiruvalam R et al (2012) Involvement of surface-bound radicals in the oxidation of toluene using supported Au–Pd nanoparticles. Angew Chem Int Ed 51:5981–5985
Ab Rahim MH, Forde MM, Jenkins RL et al (2013) Oxidation of methane to methanol with hydrogen peroxide using supported gold–palladium alloy nanoparticles. Angew Chem Int Ed 52:1280–1284