Calcium carbonate films and helices grown in solutions of poly(aspartate)

Addadi, 1992, Angew. Chem. Int. Ed. Engl., 31, 153, 10.1002/anie.199201531

Lowenstam, 1989

1989

Greenfield, 1984, Amer. Zool., 24, 925, 10.1093/icb/24.4.925

Weiner, 1991, Trends Biochem. Sci., 16, 252, 10.1016/0968-0004(91)90098-G

Addadi, 1987, Proc. Natl. Acad. Sci. USA, 84, 2732, 10.1073/pnas.84.9.2732

Addadi, 1991, ACS Symp. Ser., 444, 13, 10.1021/bk-1991-0444.ch002

Gauldie, 1988, Comp. Biochem. Physiol. A, 90, 501, 10.1016/0300-9629(88)90227-7

Pach, 1990, J. Mater. Res., 5, 2928, 10.1557/JMR.1990.2928

Marland, 1975, Geochim. Cosmochim. Acta, 39, 83, 10.1016/0016-7037(75)90186-6

S.E. Rudnick, PhD Thesis, Boston University, 1979.

R. Brooks, L.M. Clark, E.F. Thurston, Philos. Trans. R. Soc. London Ser. A 243.

Dickens, 1970, Inorg. Chem., 9, 480, 10.1021/ic50085a010

R.E. Stoiber, S.A. Morse, Crystal Identification with the Polarizing Microscope, Chapman and Hall, New York, 1994, p. 200; and personal communications with S.A. Morse. Conoscopy of the film patches yields single-crystal interference figures, which in some cases appear biaxial (the isogyres have borders of red and blue due to dispersion, and the hyperbolic legs separate, but remain in the field of view as the stage is rotated), but it is possible that these are pseudo-biaxial figures produced by strain in the thin film structures. This is suggested because the optic angle was not very well defined, and seemed to vary among samples.

L. Gower, D.A. Tirrell, poster presented at the 7th Int. Symp. on Biomineralization, Monoco, November 1993. At that time, we reported preliminary observations of “helical calcite crystals”. As this report describes, we have since determined that these are spherulitic vaterite particles.

Sims, 1995, J. Chem. Soc., Chem. Comm., 10, 1031, 10.1039/c39950001031

Garcia-Ruiz, 1985, J. Crystal Growth, 73, 251, 10.1016/0022-0248(85)90301-X

Weedon, 1995, Biol. Bull., 188, 281, 10.2307/1542305

Mutvei, 1972, Biomineralisation – Research Reports, 6, 96

Wada, 1972, Biomineralisation – Research Reports, 6, 141

Liu, 1992, Mater. Res. Soc. Symp. Proc., 255, 9, 10.1557/PROC-255-9

Zaremba, 1996, Chem. Mater., 8, 679, 10.1021/cm9503285

Okazaki, 1981, Biol. Bull., 161, 402, 10.2307/1540945