CO2‐Responsive Nanofibrous Membranes with Switchable Oil/Water Wettability

Angewandte Chemie - International Edition - Tập 54 Số 31 - Trang 8934-8938 - 2015
Hailong Che1, Meng Huo1, Peng Liao1, Tommy Fang1, Na Liu2, Lin Feng2, Yen Wei2, Jinying Yuan1
1Key Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, P.R. China
2Key Lab of Bioorganic Phosphorus Chemistry & Chemical Biology of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing, 100084 (P. R. China)

Tóm tắt

Abstract

Responsive polymer interfacial materials are ideal candidates for controlling surface wetting behavior. Here we developed smart nanostructured electrospun polymer membranes which are capable of switching oil/water wettability using CO2 as the trigger. In particular, the combination of CO2‐responsiveness and porous nanostructure enables the as‐prepared membranes to be used as a novel oil/water on–off switch. We anticipate that the promising versatility and simplicity of this system would not only open up a new way of surface wettability change regulation by gas, but also have obvious advantages in terms of highly controlled oil/water separation and CO2 applications.

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