Boron clusters: Do they receive the deserved interest?

Pure and Applied Chemistry - Tập 75 Số 9 - Trang 1305-1313 - 2003
Francesç Teixidor1, Clara Viñas1, Albert Demonceau1, Raikko Kivekäs1
1Institut de Ciència de Materials de Barcelona (CSIC), Campus U.A.B., E-08193 Bellaterra, Spain

Tóm tắt

Abstract New applications in which the carborane and metallacarborane species play a crucial role have been recently developed. In these applications, clusters display many particular characteristics that do not find parallel in their organic counterparts. The o-carborane can modulate the C···C distances depending on the substituents bonded to the cluster carbon atom and can lead to the formation of uncommon halogenophosphane charge-transfer “spoke ” complexes with iodine due to their electron-withdrawing capacity. Besides, metallacarboranes have been used as doping agents in organic conducting polymers and as catalysts in Kharasch reactions.

Từ khóa


Tài liệu tham khảo

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Thông tin
Thông tin xuất bản

Pure and Applied Chemistry

Tập 75 Số 9

1305-1313

Thông tin tác giả