Bisporphyrin-calix[4]arene heterotopic receptors of multifunctional substrates

Russian Journal of General Chemistry - Tập 81 - Trang 594-601 - 2011
G. M. Mamardashvili1, S. V. Zvezdina1, N. Zh. Mamardashvili1
1Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo, Russia

Tóm tắt

In order to create heterotopic receptors of polyfunctional substrates we have synthesized the bisporphyrin-calix[4]arene crown ethers [6] with the amino and hydroxy groups in tetrapyrrole fragments and polyethyleneoxide complexing cavity in the calix[4]arene fragment of the macrocycle. Their spectral properties and complexing ability toward the alkali metal cations, organic diamines, and dicarboxylic acid esters were investigated.

Tài liệu tham khảo

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