Các điện cực tự đứng dựa trên Bismuth cho sản xuất Ammonia trong điều kiện môi trường trung tính

Nano-Micro Letters - Tập 12 Số 1 - 2020
Ying Sun1, Zizhao Deng1, Xi‐Ming Song2, Hui Li1, Zi‐Hang Huang1, Qin Zhao1, Daming Feng1, Wei Zhang2, Zhao‐Qing Liu3, Tianyi Ma4
1Institute of Clean Energy Chemistry, Key Laboratory for Green Synthesis and Preparative Chemistry of Advanced Materials, College of Chemistry, Liaoning University, Shenyang, 110036, People’s Republic of China
2Key Laboratory for Green Synthesis and Preparative Chemistry of Advanced Materials, College of Chemistry, Liaoning University, Shenyang, 110036, People’s Republic of China
3School of Chemistry and Chemical Engineering, Guangzhou Key Laboratory for Environmentally Functional Materials and Technology, Guangzhou University, Guangzhou 510006, People’s Republic of China
4Discipline of Chemistry, University of Newcastle, Callaghan, NSW 2308, Australia

Tóm tắt

Tóm tắtPhản ứng khử nitơ điện xúc tác là một chiến lược không phát thải carbon và tiết kiệm năng lượng cho việc tổng hợp ammonia hiệu quả trong điều kiện môi trường. Ở đây, chúng tôi báo cáo về việc tổng hợp các hạt Bi2O3 kích thước nano được hình thành trên graphene nghiền tách chức năng (Bi2O3/FEG) thông qua một phương pháp lắng điện hóa đơn giản. Bi2O3/FEG độc lập thu được đạt được hiệu suất Faradaic cao là 11,2% và năng suất NH3 lớn là 4,21 ± 0,14 $$ \upmu{\text{g}}_{{{\text{NH}}_{3} }} $$ μ g NH 3  h−1 cm−2 ở − 0,5 V so với điện cực hydro đảo chiều trong dung dịch Na2SO4 0,1 M, tốt hơn so với trong môi trường axit và kiềm mạnh. Nhờ vào sự tương tác mạnh mẽ của băng Bi 6p với quỹ đạo N 2p, đặc điểm không có chất kết dính, và sự chuyển giao điện tử dễ dàng, Bi2O3/FEG đạt được hiệu suất xúc tác vượt trội và độ ổn định dài hạn xuất sắc so với hầu hết các chất xúc tác đã được báo cáo trước đây. Nghiên cứu này có ý nghĩa trong việc thiết kế các điện xúc tác dựa trên Bismuth có chi phí thấp và hiệu quả cao cho tổng hợp ammonia điện hóa.

Từ khóa


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