Biodegradable poly(3-hydroxybutyrate-co-3-hydroxyvalerate)/thermoplastic polyurethane blends with improved mechanical and barrier performance

Rehm, 2003, Polyester synthases: Natural catalysts for plastics, Biochem. J., 376, 15, 10.1042/bj20031254 Reis, 2003, Production of polyhydroxyalkanoates by mixed microbial cultures, Bioprocess Biosyst. Eng., 25, 377, 10.1007/s00449-003-0322-4 Serafim, 2004, Optimization of polyhydroxybutyrate production by mixed cultures submitted to aerobic dynamic feeding conditions, Biotechnol. Bioeng., 87, 145, 10.1002/bit.20085 Laycock, 2013, The chemomechanical properties of microbial polyhydroxyalkanoates, Prog. Polym. Sci., 38, 536, 10.1016/j.progpolymsci.2012.06.003 Khanna, 2005, Recent advances in microbial polyhydroxyalkanoates, Process Biochem., 40, 607, 10.1016/j.procbio.2004.01.053 Cava, 2006, Comparative performance and barrier properties of biodegradable thermoplastics and nanobiocomposites versus PET for food packaging applications, J. Plastic Film Sheeting, 22, 265, 10.1177/8756087906071354 Corre, 2012, Morphology and functional properties of commercial polyhydroxyalkanoates: a comprehensive and comparative study, Polym. Test., 31, 226, 10.1016/j.polymertesting.2011.11.002 Keshavarz, 2010, Polyhydroxyalkanoates: bioplastics with a green agenda, Curr. Opin. Microbiol., 13, 321, 10.1016/j.mib.2010.02.006 Nduko, 2012, Biological lactate-polymers synthesized by one-pot microbial factory: Enzyme and metabolic engineering, 213, 10.1021/bk-2012-1105.ch014 Shogren, 1997, Water vapor permeability of biodegradable polymers, J. Environ. Polym. Degrad., 5, 91, 10.1007/BF02763592 Di Lorenzo, 2001, Poly(3-hydroxybutyrate)-based copolymers and blends: Influence of a second component on crystallization and thermal behavior, J. Macromol. Sci. - Phys., 40 B, 639, 10.1081/MB-100107554 Jost, 2015, Effect of different plasticisers on the mechanical and barrier properties of extruded cast PHBV films, Eur. Polym. J., 68, 302, 10.1016/j.eurpolymj.2015.04.012 Peelman, 2013, Application of bioplastics for food packaging, Trends Food Sci. Technol., 32, 128, 10.1016/j.tifs.2013.06.003 Yu, 2006, Polymer blends and composites from renewable resources, Prog. Polym. Sci. Oxf., 31, 576, 10.1016/j.progpolymsci.2006.03.002 Ha, 2002, Miscibility, properties, and biodegradability of microbial polyester containing blends, Prog. Polym. Sci. Oxf., 27, 759, 10.1016/S0079-6700(01)00050-8 Ma, 2012, Toughening of PHBV/PBS and PHB/PBS blends via in situ compatibilization using dicumyl peroxide as a free-radical grafting initiator, Macromol. Mater. Eng., 297, 402, 10.1002/mame.201100224 Cunha, 2016, Film blowing of PHBV blends and PHBV-based multilayers for the production of biodegradable packages, J. Appl. Polym. Sci., 133, 42165, 10.1002/app.42165 Zembouai, 2013, A study of morphological, thermal, rheological and barrier properties of poly(3-hydroxybutyrate-Co-3-Hydroxyvalerate)/polylactide blends prepared by melt mixing, Polym. Test., 32, 842, 10.1016/j.polymertesting.2013.04.004 Ishida, 2009, Toughening of Poly(L-lactide) by melt blending with rubbers, J. Appl. Polym. Sci., 113, 558, 10.1002/app.30134 Liu, 2012, Toughening modification of poly(lactic acid) via melt blending, 27, 10.1021/bk-2012-1105.ch003 Zhang, 2011, Toughening of polylactide with natural rubber grafted with poly(butyl acrylate), Polym. Int., 60, 1548, 10.1002/pi.3118 Zhang, 2013, Thermal, mechanical and rheological properties of polylactide toughened by expoxidized natural rubber, Mater. Des., 45, 198, 10.1016/j.matdes.2012.09.024 Kowalczyk, 2012, Mechanisms of plastic deformation in biodegradable polylactide/poly(1,4- cis-isoprene) blends, J. Appl. Polym. Sci., 124, 4579 Gassner, 1992, On the physical properties of BIOPOL/ethylene-vinyl acetate blends, Polymer, 33, 2508, 10.1016/0032-3861(92)91131-K Han, 2004, Melt reaction in blends of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) and epoxidized natural rubber, Polym. Degrad. Stab., 85, 947, 10.1016/j.polymdegradstab.2003.11.020 Park, 2004, Compatibility of poly(butadiene-co-acrylonitrile) with poly(L-lactide) and poly(3-hydroxybutyrate-co-3-hydroxyvalerate), J. Appl. Polym. Sci., 92, 3508, 10.1002/app.20356 Tatai, 2007, Thermoplastic biodegradable polyurethanes: the effect of chain extender structure on properties and in-vitro degradation, Biomaterials, 28, 5407, 10.1016/j.biomaterials.2007.08.035 Jašo, 2015, Biodegradability study of polylactic acid/thermoplastic polyurethane blends, Polym. Test., 47, 1, 10.1016/j.polymertesting.2015.07.011 Kim, 1998, Effect of chemical structure on the biodegradation of polyurethanes under composting conditions, Polym. Degrad. Stab., 62, 343, 10.1016/S0141-3910(98)00017-2 Seidenstücker, 1998, Innovative biodegradable materials based upon starch and thermoplastic poly(ester-urethane) (TPU), Polym. Degrad. Stab., 59, 279, 10.1016/S0141-3910(97)00199-7 Li, 2007, Toughening of polylactide by melt blending with a biodegradable poly(ether)urethane elastomer, Macromol. Biosci., 7, 921, 10.1002/mabi.200700027 Yu, 2014, Improvement in toughness of polylactide by melt blending with bio-based poly(ester)urethane, Chin. J. Polym. Sci. Engl. Ed., 32, 1099, 10.1007/s10118-014-1487-9 Jašo, 2014, Bio-plastics and elastomers from polylactic acid/thermoplastic polyurethane blends, J. Appl. Polym. Sci., 131, 41104, 10.1002/app.41104 Wang, 2014, Morphology and properties of renewable poly(3-hydroxybutyrate-co-3- hydroxyvalerate) blends with thermoplastic polyurethane, Polym. Eng. Sci., 54, 1113, 10.1002/pen.23655 Alata, 2007, Effect of aging on the mechanical properties of poly(3-hydroxybutyrate-co- 3-hydroxyhexanoate), Macromolecules, 40, 4546, 10.1021/ma070418i Liu, 2009, Reducing the formation of six-membered ring ester during thermal degradation of biodegradable PHBV to enhance its thermal stability, Polym. Degrad. Stab., 94, 18, 10.1016/j.polymdegradstab.2008.10.016 AENOR (Asociación Española de Normalización y Certificación), 2006 Utracki, 1991, Polymer alloys and blends. State of the art, Polym. Netw. Blends, 1, 61 Simha, 1962, On a general relation involving the glass temperature and coefficients of expansion of polymers, J. Chem. Phys., 37, 1003, 10.1063/1.1733201 Kunioka, 1989, Crystalline and thermal properties of bacterial copolyesters: Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) and poly(3-hydroxybutyrate-co-4-hydroxybutyrate), Macromolecules, 22, 694, 10.1021/ma00192a031 Gunaratne, 2005, Multiple melting behaviour of poly(3-hydroxybutyrate-co-hydroxyvalerate) using step-scan DSC, Eur. Polym. J., 41, 2980, 10.1016/j.eurpolymj.2005.06.015 Grassie, 1984, The thermal degradation of poly(-(d)-β-hydroxybutyric acid): Part 3-The reaction mechanism, Polym. Degrad. Stab., 6, 127, 10.1016/0141-3910(84)90032-6 Abate, 1994, Thermal degradation of microbial poly(4-hydroxybutyrate), Macromolecules, 27, 332, 10.1021/ma00080a004 Floros, 2012, Enhancement of thermal stability, strength and extensibility of lipid-based polyurethanes with cellulose-based nanofibers, Polym. Degrad. Stab., 97, 1970, 10.1016/j.polymdegradstab.2012.02.016 Barick, 2010, Thermal and dynamic mechanical characterization of thermoplastic polyurethane/organoclay nanocomposites prepared by melt compounding, Mater. Sci. Eng. A, 527, 812, 10.1016/j.msea.2009.10.063 Herrera, 2002, Thermal degradation of thermoplastic polyurethane elastomers (TPU) based on MDI, Polym. Degrad. Stab., 78, 323, 10.1016/S0141-3910(02)00181-7 Simões, 2009, Mechanical properties of poly(ε-caprolactone) and poly(lactic acid) blends, J. Appl. Polym. Sci., 112, 345, 10.1002/app.29425 Loureiro, 2015, Mechanical characterization of polyhydroxyalkanoate and poly(lactic acid) blends, J. Thermoplast. Compos. Mater., 28, 195, 10.1177/0892705712475020 Broz, 2003, Structure and mechanical properties of poly(D,L-lactic acid)/poly(ε-caprolactone) blends, Biomaterials, 24, 4181, 10.1016/S0142-9612(03)00314-4 Bliznakov, 2000, Mechanical properties of blends of HDPE and recycled urea-formaldehyde resin, J. Appl. Polym. Sci., 77, 3220, 10.1002/1097-4628(20000929)77:14<3220::AID-APP250>3.0.CO;2-4 Tomar, 2007, Mechanical properties of PBT/ABAS blends, J. Appl. Polym. Sci., 104, 1807, 10.1002/app.25831 Follain, 2014, Structure and barrier properties of biodegradable polyhydroxyalkanoate films, J. Phys. Chem. C, 118, 6165, 10.1021/jp408150k Martínez-Abad, 2016, Characterization of polyhydroxyalkanoate blends incorporating unpurified biosustainably produced poly(3-hydroxybutyrate-co-3-hydroxyvalerate), J. Appl. Polym. Sci., 133, 42633, 10.1002/app.42633 Puglia, 2014, Influence of organically modified clays on the properties and disintegrability in compost of solution cast poly(3-hydroxybutyrate) films, Polym. Degrad. Stab., 99, 127, 10.1016/j.polymdegradstab.2013.11.013 Weng, 2010, Biodegradation behavior of PHBV films in a pilot-scale composting condition, Polym. Test., 29, 579, 10.1016/j.polymertesting.2010.04.002 Iggui, 2015, A biodegradation study of poly(3-hydroxybutyrate-co-3-hydroxyvalerate)/organoclay nanocomposites in various environmental conditions, Polym. Degrad. Stab., 119, 77, 10.1016/j.polymdegradstab.2015.05.002 Arrieta, 2014, Disintegrability under composting conditions of plasticized PLA-PHB blends, Polym. Degrad. Stab., 108, 307, 10.1016/j.polymdegradstab.2014.01.034 Fortunati, 2012, New multifunctional poly(lactide acid) composites: Mechanical, antibacterial, and degradation properties, J. Appl. Polym. Sci., 124, 87, 10.1002/app.35039