Benzoylformamides như là các base photocaged đa năng cho photopolymer hóa gốc tự do oxi hóa khử

P. Xiao, J. Zhang, F. Dumur, M. A. Tehfe, F. Morlet-Savary, B. Graff, D. Gigmes, J. P. Fouassier and J. Lalevee, Visible light sensitive photoinitiating systems: Recent progress in cationic and radical photopolymerization reactions under soft conditions, Prog. Polym. Sci., 2015, 41, 32–66. P. Xiao, F. E. D. E. Dumur, M. Tehfe, B. Graff, D. Gigmes, J. P. Fouassier and J. Lalev E E, Difunctional acridinediones as photoinitiators of polymerization under UV and visible lights: Structural effects, Polymer, 2013, 14, 3458–3466. J. Zhang, F. Dumur, P. Xiao, B. Graff, D. Gigmes, J. P. Fouassier and J. Lalevee, Aminothiazonaphthalic anhydride derivatives as photoinitiators for violet/blue LED-Induced cationic and radical photopolymerizations and 3D-Printing resins, J. Polym. Sci., Part A: Polym. Chem., 2016, 54, 1189–1196. H. Mokbel, P. Xiao, C. Simonnet-Jegat, F. Dumur, D. Gigmes, J. Toufaily, T. Hamieh, J. P. Fouassier and J. Lalevee, Iodonium-polyoxometalate and thianthrenium-polyoxometalate as new one-component UV photoinitiators for radical and cationic polymerization, J. Polym. Sci., Part A: Poly. Chem., 2015, 53, 981–989. J. Zhang, M. Frigoli, F. Dumur, P. Xiao, L. Ronchi, B. Graff, F. Morlet-Savary, J. P. Fouassier, D. Gigmes and J. Lalevee, Design of Novel Photoinitiators for Radical and Cationic Photopolymerizations under Near UV and Visible LEDs (385, 395, and 405 nm), Macromolecules, 2014, 47, 2811–2819. N. Karaca, D. K. Balta, N. Ocal and N. Arsu, Thioxanthonation of fluorenone: Visible photoinitiator for radical polymerization, J. Polym. Sci., Part A: Polym. Chem., 2016, 54, 1012–1019. S. Dadashi-Silab, C. Aydogan and Y. Yagci, Shining a light on an adaptable photoinitiator: advances in photopolymerizations initiated by thioxanthones, Polym. Chem., 2015, 6, 6595–6615. C. Dietlin, S. Schweizer, P. Xiao, J. Zhang, F. Morlet-Savary, B. Graff, J. Fouassier and J. Lalevee, Photopolymerization upon LEDs: new photoinitiating systems and strategies, Polym. Chem., 2015, 6, 3895–3912. K. Suyama, H. Araki and M. Shirai, Quaternary ammonium salt as DBU-generating photobase generator, J. Photopolym. Sci. Technol., 2006, 19, 81–84. K. Arimitsu and R. Endo, Photochemical generation of superbases and its application to photoreactive materials, J. Photopolym. Sci. Technol., 2010, 23, 135–136. X. Sun, J. P. Gao and Z. Y. Wang, Bicyclic guanidinium tetraphenylborate: a photobase generator and a photocatalyst for living anionic ring-opening polymerization and cross-linking of polymeric materials containing ester and hydroxy groups, J. Am. Chem. Soc., 2008, 130, 8130–8131. C. E. Hoyle, A. B. Lowe and C. N. Bowman, Thiol-click chemistry: a multifaceted toolbox for small molecule and polymer synthesis, Chem. Soc. Rev., 2010, 39, 1355–1387. T. Ibe, R. B. Frings, A. Lachowicz, S. Kyo and H. Nishide, Nitroxide polymer networks formed by Michael addition: on site-cured electrode-active organic coating, Chem. Commun., 2010, 46, 3475–3477. R. Popielarz, A. M. Sarker and D. C. Neckers, Applicability of tetraphenylborate salts as free radical initiators, Macromolecules, 1998, 31, 951–954. S. Hu, A. M. Sarker, Y. Kaneko and D. C. Neckers, Reactivities of Chromophore-Containing Methyl Tri-n-butylammonium Organoborate Salts as Free Radical Photoinitiators: Dependence on the Chromophore and Borate Counterion 1, Macromolecules, 1998, 31, 6476–6480. S. Hassoon, A. Sarker, M. Rodgers and D. C. Neckers, Photochemistry of (benzophenonylmethyl)-tri-n-butylammonium triphenylbutylborate: inter-and intra-ion-pair electron transfer photoreduction, J. Am. Chem. Soc., 1995, 117, 11369–11370. C. N. Bowman, W. Xi, C. Kloxin and M. Krieger, A new photoclick reaction strategy: photo-induced catalysis of the thiol-Michael addition via a caged primary amine, Chem. Commun., 2013, 49, 4504–4506. Y. Jian, Y. He, Y. Sun, H. Yang, W. Yang and J. Nie, Thiol-epoxy/thiol-acrylate hybrid materials synthesized by photopolymerization, J. Mater. Chem., 2013, 1, 4481–4489. X. Yu, J. Chen, J. Yang, Z. Zeng and Y. Chen, Preparation of a series of photoinitiators and their use in the thermal curing of epoxide and radical polymerization of acrylate, Polymer, 2005, 46, 5736–5745. K. Suyama and M. Shirai, Photobase generators: Recent progress and application trend in polymer systems, Prog. Polym. Sci., 2009, 34, 194–209. M. He, X. Huang, Y. Huang, Z. Zeng and J. Yang, Photoinduced redox initiation for fast polymerization of acrylaytes based on latent superbase and peroxides, Polymer, 2012, 53, 3172–3177. M. He, G. Chen, X. Huang, R. Xu, Z. Zeng and J. Yang, N-Phthaloyltranexamic acid ammonium salt derivatives as photocaged superbase for redox free radical photopolymerization, Polym. Chem., 2014, 5, 2951–2960. M. He, X. Huang, Z. Zeng and J. Yang, Phototriggered base proliferation: a highly efficient domino reaction for creating functionally photo-screened materials, Macromolecules, 2013, 46, 6402–6407. M. He, M. Su, Z. Yu, G. Chen, Z. Zeng and J. Yang, Benzoylformamides as new photocaged bases for photo-latent anion polymerization, Chin. Chem. Lett., 2015, 26, 21–25. T. Lavy, Y. Sheynin and M. Kaftory, The effects of space formed by host molecules in inclusion compounds on the homogeneity/heterogeneity of the photoreaction in the solid state, Eur. J. Org. Chem., 2004, 4802–4808. J. L. Jesuraj and J. Sivaguru, Photochemical type II reaction of atropchiral benzoylformamides to point chiral oxazolidin-4-ones. Axial chiral memory leading to enantiomeric resolution of photoproducts, Chem. Commun., 2010, 46, 4791–4793. A. Natarajan, J. T. Mague and V. Ramamurthy, Asymmetric induction during Yang cyclization of α-oxoamides: the power of a covalently linked chiral auxiliary is enhanced in the crystalline state, J. Am. Chem. Soc., 2005, 127, 3568–3576. A. J. Ayitou, J. L. Jesuraj, N. Barooah, A. Ugrinov and J. Sivaguru, Enantiospecific photochemical Norrish/Yang type II reaction of nonbiaryl atropchiral α-oxoamides in solution-axial to point chirality transfer, J. Am. Chem. Soc., 2009, 131, 11314–11315. U. Zehavi, Photochemical reactions of phenylglyoxalyl amides, J. Org. Chem., 1977, 42, 2821–2825.