BaTiO3-based piezoelectrics: Fundamentals, current status, and perspectives

Applied Physics Reviews - Tập 4 Số 4 - 2017
Matias Acosta1, Nikola Novak1, Verónica García1, Satyanarayan Patel1,2, Rahul Vaish2, Jurij Koruza1, George A. Rossetti3,4, Jürgen Rödel1
1Institute of Materials Science, Technische Universität Darmstadt 1 , Darmstadt 64287, Germany
2School of Engineering, Indian Institute of Technology Mandi 2 , Himachal Pradesh 175001, India
3Connecticut 3 , Storrs, 06269, USA
4Department of Materials Science and Engineering and Institute of Materials Science, University of Connecticut, Storrs, Connecticut 06269, USA

Tóm tắt

We present a critical review that encompasses the fundamentals and state-of-the-art knowledge of barium titanate-based piezoelectrics. First, the essential crystallography, thermodynamic relations, and concepts necessary to understand piezoelectricity and ferroelectricity in barium titanate are discussed. Strategies to optimize piezoelectric properties through microstructure control and chemical modification are also introduced. Thereafter, we systematically review the synthesis, microstructure, and phase diagrams of barium titanate-based piezoelectrics and provide a detailed compilation of their functional and mechanical properties. The most salient materials treated include the (Ba,Ca)(Zr,Ti)O3, (Ba,Ca)(Sn,Ti)O3, and (Ba,Ca)(Hf,Ti)O3 solid solution systems. The technological relevance of barium titanate-based piezoelectrics is also discussed and some potential market indicators are outlined. Finally, perspectives on productive lines of future research and promising areas for the applications of these materials are presented.

Từ khóa


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