Atomically precise bimetallic metal ensembles with tailorable synergistic effects

Corma, 2013, Exceptional oxidation activity with size-controlled supported gold clusters of low atomicity, Nat. Chem., 5, 775, 10.1038/nchem.1721 Guan, 2018, Water oxidation on a mononuclear manganese heterogeneous catalyst, Nat. Catal., 1, 870, 10.1038/s41929-018-0158-6 Ji, 2021, Matching the kinetics of natural enzymes with a single-atom iron nanozyme, Nat. Catal., 4, 407, 10.1038/s41929-021-00609-x Coelho, 2013, Olefin cyclopropanation via carbene transfer catalyzed by engineered cytochrome P450 enzymes, Science, 339, 307, 10.1126/science.1231434 Bols, 2021, Coordination and activation of nitrous oxide by iron zeolites, Nat. Catal., 4, 332, 10.1038/s41929-021-00602-4 Chen, 2021, Regulating coordination number in atomically dispersed Pt species on defect-rich graphene for n-butane dehydrogenation reaction, Nat. Commun., 12, 2664, 10.1038/s41467-021-22948-w Yao, 2017, Atomic-layered Au clusters on α-MoC as catalysts for the low-temperature water-gas shift reaction, Science, 357, 389, 10.1126/science.aah4321 Vercammen, 2020, Shape-selective C–H activation of aromatics to biarylic compounds using molecular palladium in zeolites, Nat. Catal., 3, 1002, 10.1038/s41929-020-00533-6 Leyva-Pérez, 2017, Sub-nanometre metal clusters for catalytic carbon-carbon and carbon-heteroatom cross-coupling reactions, Dalton Trans., 46, 15987, 10.1039/C7DT03203J Khoshsefat, 2021, Multinuclear late transition metal catalysts for olefin polymerization, Coord. Chem. Rev., 434, 213788, 10.1016/j.ccr.2021.213788 Hanhan, 2013, Effective binuclear Pd(II) complexes for Suzuki reactions in water, Appl. Organomet. Chem., 27, 570, 10.1002/aoc.3034 Xia, 2003, J. Am. Chem. Soc., 125, 10362, 10.1021/ja0355325 Zhao, 2020, Structural transformation of highly active metal–organic framework electrocatalysts during the oxygen evolution reaction, Nat. Energy, 5, 881, 10.1038/s41560-020-00709-1 Jin, 2019, Low temperature oxidation of ethane to oxygenates by oxygen over iridium-cluster catalysts, J. Am. Chem. Soc., 141, 18921, 10.1021/jacs.9b06986 McKenzie, 1988, High turnover catalysis at bimetallic sites of the hydration of nitriles to carboxamides co-catalysed by acid. Highly specific hydration of acrylonitrile to acrylamide, J. Chem. Soc. Chem. Commun., 112, 112, 10.1039/c39880000112 Nagashima, 2006, Dynamic titanium phosphinoamides as unique bidentate phosphorus ligands for platinum, Organometallics, 25, 1987, 10.1021/om0509600 Feng, 2019, Transition-metal-bridged bimetallic clusters with multiple uranium–metal bonds, Nat. Chem., 11, 248, 10.1038/s41557-018-0195-4 Eisenhart, 2015, Configuring bonds between first-row transition metals, Acc. Chem. Res., 48, 2885, 10.1021/acs.accounts.5b00336 Török, 1998, Nickel(II)-, copper(II)- and zinc(II)-complexes of some substituted imidazole ligands, J. Inorg. Biochem., 71, 7, 10.1016/S0162-0134(98)10027-2 Coutiño-Gonzalez, 2017, Silver clusters in zeolites: from self-assembly to ground-breaking luminescent properties, Acc. Chem. Res., 50, 2353, 10.1021/acs.accounts.7b00295 Chen, 2020, Recent advances of precise Cu nanoclusters in microporous materials, Chem. Asian J., 15, 1819, 10.1002/asia.202000331 Peng, 2021, Fully exposed cluster catalyst (FECC): toward rich surface sites and full atom utilization efficiency, ACS Cent. Sci., 7, 262, 10.1021/acscentsci.0c01486 Goswami, 2020, Double rotors with fluxional axles: domino rotation and azide–alkyne huisgen cycloaddition catalysis, Angew. Chem. Int. Ed., 59, 12362, 10.1002/anie.202002739 Sroka-Bartnlcka, 2010, Complementarity of solvent-free MALDI TOF and solid-state NMR spectroscopy in spectral analysis of polylactides, Anal. Chem., 82, 323, 10.1021/ac9020006 Dass, 2008, Nanoparticle MALDI-TOF mass spectrometry without fragmentation: Au 25 (SCH 2 CH 2 Ph) 18 and mixed monolayer Au 25 (SCH 2 CH 2 Ph) 18− x (L) x, J. Am. Chem. Soc., 130, 5940, 10.1021/ja710323t Zavras, 2013, Synthesis, structure and gas-phase reactivity of a silver hydride complex [Ag 3 {(PPh 2 ) 2 CH 2 } 3 (μ 3 -H)(μ 3 -Cl)]BF 4, Angew. Chem. Int. Ed., 52, 8391, 10.1002/anie.201302436 Giordanino, 2013, Characterization of Cu-exchanged SSZ-13: a comparative FTIR, UV-Vis, and EPR study with Cu-ZSM-5 and Cu-β with similar Si/Al and Cu/Al ratios, Dalton Trans., 42, 12741, 10.1039/c3dt50732g Godiksen, 2017, Identification and quantification of copper sites in zeolites by electron paramagnetic resonance spectroscopy, Top. Catal., 60, 13, 10.1007/s11244-016-0731-7 Chen, 2020, Differential adsorption of l- and d-lysine on achiral MFI zeolites as determined by synchrotron X-ray powder diffraction and thermogravimetric analysis, Angew. Chem. Int. Ed., 59, 1093, 10.1002/anie.201909352 Lo, 2018, The contribution of synchrotron X-ray powder diffraction to modern zeolite applications: a mini-review and prospects, Chem, 4, 1, 10.1016/j.chempr.2018.04.018 Lo, 2016, Elucidation of adsorbate structures and interactions on brønsted acid sites in H-ZSM-5 by synchrotron X-ray powder diffraction, Angew. Chem. Int. Ed., 55, 5981, 10.1002/anie.201600487 Ye, 2017, Decarboxylation of lactones over Zn/ZSM-5: elucidation of the structure of the active site and molecular interactions, Angew. Chem. Int. Ed., 56, 10711, 10.1002/anie.201704347 Lo, 2020, Evaluation of Brønsted and Lewis acid sites in H-ZSM-5 and H-USY with or without metal modification using probe molecule-synchrotron X-ray powder diffraction, Appl. Catal. Gen., 596, 117528, 10.1016/j.apcata.2020.117528 Zheng, 2012, Force field for molecular dynamics computations in flexible ZIF-8 framework, J. Phys. Chem. C, 116, 933, 10.1021/jp209463a García-García, 2014, MOF catalysis in relation to their homogeneous counterparts and conventional solid catalysts, Chem. Sci., 5, 2979, 10.1039/c4sc00265b Worrell, 2013, Direct evidence of a dinuclear copper intermediate in Cu(I)-catalyzed azide-alkyne cycloadditions, Science, 340, 457, 10.1126/science.1229506