Assembly of mesoporous SnO2 spheres and carbon nanotubes network as a high-performance anode for lithium-ion batteries

Journal of Materials Science - Tập 53 - Trang 15621-15630 - 2018
Xuejun Liu1, Pengcheng Xu2, Xinru Li2, Yiting Peng1, Zaiyuan Le2
1Shanghai Key Laboratory of Materials Protection and Advanced Materials in Electric Power, Shanghai University of Electric Power, Shanghai, People’s Republic of China
2Department of Chemical and Biomolecular Engineering, University of California, Los Angeles, USA

Tóm tắt

We report a facile and effective aerosol-spray strategy toward high-performance anodes for lithium-ion batteries by incorporating mesoporous SnO2 spheres of high-capacity materials with surface-modified carbon nanotubes (MCNTs). SnO2 nanocrystals are self-assembled into mesoporous spheres, and MCNTs with abundant carboxylic groups serve as a conductive scaffold. Driven by the strong interaction between the surface of metal oxide and the carboxylic groups on CNTs, a robust nanocomposite architecture is in situ formed. Such nanocomposite architecture possesses several advantages as an anode for lithium-ion batteries. First, mesoporous SnO2 spheres inherit the advantageous features of conventional nanoparticles, such as the capability to accommodate volume expansion and reduce Li+ diffusion distance. Second, the robust interface between nanocrystals in the SnO2 spheres provides the high structural stability that would prolong the life span of the electrode. Third, MCNTs that strongly bind to SnO2 spheres serve as a three-dimensional network, offering both improved electronic transport and mechanical strength of the electrode. Therefore, as-prepared nanocomposite delivers high capacity of 963 mAh g−1 at 0.1 C and 701 mAh g−1 at 5 C, respectively. Significantly improved cycling performance is achieved over the bare SnO2 spheres counterpart.

Tài liệu tham khảo

Armand M, Tarascon JM (2008) Building better batteries. Nature 451:652–657. https://doi.org/10.1038/451652a Simon P, Gogotsi Y (2008) Materials for electrochemical capacitors. Nat Mater 7:845–854. https://doi.org/10.1038/nmat2297 Miller JR, Simon P (2008) Electrochemical capacitors for energy management. Science 321:651–652. https://doi.org/10.1126/science.1158736 Bruce PG, Scrosati B, Tarascon JM (2008) Nanomaterials for rechargeable lithium batteries. Angew Chem Int Ed Engl 47:2930–2946. https://doi.org/10.1002/anie.200702505 Chen G, Yan L, Luo H, Guo S (2016) Nanoscale engineering of heterostructured anode materials for boosting lithium-ion storage. Adv Mater 28:7580–7602. https://doi.org/10.1002/adma.201600164 Liu Y, Peng XS (2017) Recent advances of supercapacitors based on two-dimensional materials. Appl Mater Today 8:104–115. https://doi.org/10.1016/j.apmt.2017.05.002 Hossain A, Bandyopadhyay P, Guin PS, Roy S (2017) Recent developed different structural nanomaterials and their performance for supercapacitor application. Appl Mater Today 9:300–313. https://doi.org/10.1016/j.apmt.2017.08.010 Li J, Zhao Y, Wang N, Guan L (2011) A high performance carrier for SnO2 nanoparticles used in lithium ion battery. Chem Commun 47:5238–5240. https://doi.org/10.1039/c1cc10542f Han S, Jang B, Kim T, Oh SM, Hyeon T (2005) Simple synthesis of hollow tin dioxide microspheres and their application to lithium-ion battery anodes. Adv Funct Mater 15:1845–1850. https://doi.org/10.1002/adfm.200500243 Ji HX, Wu XL, Fan LZ et al (2010) Self-wound composite nanomembranes as electrode materials for lithium ion batteries. Adv Mater 22:4591–4595. https://doi.org/10.1002/adma.201001422 Zhang WM, Hu JS, Guo YG et al (2008) Tin-nanoparticles encapsulated in elastic hollow carbon spheres for high-performance anode material for lithium ion batteries. Adv Mater 20:1160–1165. https://doi.org/10.1002/adma.200701364 Paek SM, Yoo E, Honma I (2009) Enhanced cyclic performance and lithium storage capacity of SnO2/graphene nanoporous electrodes with three-dimensionally delaminated flexible structure. Nano Lett 9:72–75. https://doi.org/10.1021/nl802484w Lou XW, Li CM, Archer LA (2009) Designed synthesis of coaxial SnO2@carbon hollow nanospheres for highly reversible lithium storage. Adv Mater 21:2536–2539. https://doi.org/10.1002/adma.200803439 Courtney IA, Dahn JR (1997) Key factors controlling the reversibility of the reaction of lithium with SnO2 and Sn2 BPO 6 glass. J Electrochem Soc 144:2943–2948. https://doi.org/10.1149/1.1837941 Courtney IA, Dahn JR (1997) Electrochemical and in situ X‐ray diffraction studies of the reaction of lithium with tin oxide composites. J Electrochem Soc 144:2045–2052. https://doi.org/10.1149/1.1837740 Zhang HX, Feng C, Zhai YC, Jiang KL, Li QQ, Fan SS (2009) Cross-stacked carbon nanotube sheets uniformly loaded with SnO2 nanoparticles: a novel binder-free and high-capacity anode material for lithium-ion batteries. Adv Mater 21:2299–2304. https://doi.org/10.1002/adma.200802290 Peng Y, Le Z, Wen M et al (2017) Mesoporous single-crystal-like TiO2 mesocages threaded with carbon nanotubes for high-performance electrochemical energy storage. Nano Energy 35:44–51. https://doi.org/10.1016/j.nanoen.2017.03.003 Jin R, Jiang H, Sun Y, Ma Y, Li H, Chen G (2016) Fabrication of NiFe2O4/C hollow spheres constructed by mesoporous nanospheres for high-performance lithium-ion batteries. Chem Eng J 303:501–510. https://doi.org/10.1016/j.cej.2016.06.032 Jin R, Wang Q, Cui Y, Zhang S (2017) MFe2O4 (Má = áNi, Co) nanoparticles anchored on amorphous carbon coated multiwalled carbon nanotubes as anode materials for lithium-ion batteries. Carbon 123:448–459. https://doi.org/10.1016/j.carbon.2017.07.092 Ma F, Yuan A, Xu J, Hu P (2015) Porous α-MoO3/MWCNT nanocomposite synthesized via a surfactant-assisted solvothermal route as a lithium-ion-battery high-capacity anode material with excellent rate capability and cyclability. ACS Appl Mater Interfaces 7:15531–15541. https://doi.org/10.1021/acsami.5b03953 Mai LQ, Yang F, Zhao YL et al (2011) Molybdenum oxide nanowires: synthesis & properties. Mater Today 14:346–353. https://doi.org/10.1016/S1369-7021(11)70165-1 Lee SH, Noh Y, Jo Y-R, Kim Y, Kim B-J, Kim WB (2018) Carbon-Encapsulated SnO2 core–shell nanowires directly grown on reduced graphene oxide sheets for high-performance Li-ion battery electrodes. Energy Technol 6:1255–1260. https://doi.org/10.1002/ente.201700804 Han C, Zhang B, Zhao K et al (2017) Oxalate-assisted formation of uniform carbon-confined SnO2 nanotubes with enhanced lithium storage. Chem Commun 53:9542–9545. https://doi.org/10.1039/C7CC05406H Liu Z, Sun F, Gu L et al (2017) Post iron decoration of mesoporous nitrogen-doped carbon spheres for efficient electrochemical oxygen reduction. Adv Energy Mater 7:1701154. https://doi.org/10.1002/aenm.201701154 Nie P, Yuan J, Wang J et al (2017) Prussian blue analogue with fast kinetics through electronic coupling for sodium ion batteries. ACS Appl Mater Interfaces 9:20306–20312. https://doi.org/10.1021/acsami.7b05178 Le Z, Liu F, Nie P et al (2017) Pseudocapacitive sodium storage in mesoporous single-crystal-like TiO2–graphene nanocomposite enables high-performance sodium-ion capacitors. ACS Nano 11:2952–2960. https://doi.org/10.1021/acsnano.6b08332 Shen L, Liu F, Chen G et al (2016) Encapsulation of SnO 2 nanocrystals into hierarchically porous carbon by melt infiltration for high-performance lithium storage. J Mater Chem A 4:18706–18710. https://doi.org/10.1039/c6ta09015j Peng Y, Chen Z, Le Z, Xu Q, Li H, Lu Y (2015) Mesoporous crystalline–amorphous oxide nanocomposite network for high-performance lithium storage. Chem Commun 51:12056–12059. https://doi.org/10.1039/C5CC03534A Lytle JC, Yan HW, Ergang NS, Smyrl WH, Stein A (2004) Structural and electrochemical properties of three-dimensionally ordered macroporous tin (IV) oxide films. J Mater Chem 14:1616–1622. https://doi.org/10.1039/b401890g Nie P, Xu G, Jiang J et al (2018) Aerosol-spray pyrolysis toward preparation of nanostructured materials for batteries and supercapacitors. Small Methods 2:1700272. https://doi.org/10.1002/smtd.201700272 Nie P, Le Z, Chen G et al (2018) Graphene caging silicon particles for high-performance lithium-ion batteries. Small 14:1800635. https://doi.org/10.1002/smll.201800635 Chen Z, Peng Y, Liu F et al (2015) Hierarchical nanostructured WO3 with biomimetic proton channels and mixed ionic-electronic conductivity for electrochemical energy storage. Nano Lett 15:6802–6808. https://doi.org/10.1021/acs.nanolett.5b02642 Gao C, Vo CD, Jin YZ, Li W, Armes SP (2005) Multihydroxy polymer-functionalized carbon nanotubes: synthesis, derivatization, and metal loading. Macromolecules 38:8634–8648. https://doi.org/10.1021/ma050823e Liu F, Xiao Q, Wu HB et al (2017) Regenerative polysulfide-scavenging layers enabling lithium–sulfur batteries with high energy density and prolonged cycling life. ACS Nano 11:2697–2705. https://doi.org/10.1021/acsnano.6b07603 Wu X, Wu HB, Xiong W et al (2016) Robust iron nanoparticles with graphitic shells for high-performance Ni–Fe battery. Nano Energy 30:217–224. https://doi.org/10.1016/j.nanoen.2016.09.029 Li X, Le Z, Chen X et al (2018) Graphene oxide enhanced amine-functionalized titanium metal organic framework for visible-light-driven photocatalytic oxidation of gaseous pollutants. Appl Catal B 236:501–508. https://doi.org/10.1016/j.apcatb.2018.05.052 Zhang H, Song H, Chen X, Zhou J, Zhang H (2012) Preparation and electrochemical performance of SnO2@ carbon nanotube core–shell structure composites as anode material for lithium-ion batteries. Electrochim Acta 59:160–167. https://doi.org/10.1016/j.electacta.2011.10.055 Kou Y, Xu Y, Guo Z, Jiang D (2011) Supercapacitive energy storage and electric power supply using an aza-fused π-conjugated microporous framework. Angew Chem Int Ed 50:8753–8757. https://doi.org/10.1002/anie.201103493 Idota Y, Kubota T, Matsufuji A, Maekawa Y, Miyasaka T (1997) Tin-based amorphous oxide: a high-capacity lithium-ion-storage material. Science 276:1395–1397. https://doi.org/10.1126/science.276.5317.1395 Zhu C, Usiskin RE, Yu Y, Maier J (2017) The nanoscale circuitry of battery electrodes. Science 358:eaao2808. https://doi.org/10.1126/science.aao2808 Guo J, Liu Q, Wang C, Zachariah MR (2012) Interdispersed amorphous MnOx–carbon nanocomposites with superior electrochemical performance as lithium-storage material. Adv Funct Mater 22:803–811. https://doi.org/10.1002/adfm.201102137 Cui LF, Chan CK, Ruffo R, Peng H, Cui Y (2015) US Patent No. 9,061,902. US Patent and Trademark Office, Washington, DC Zhang L, Zhao K, Yu R et al (2017) Phosphorus enhanced intermolecular interactions of SnO2 and graphene as an ultrastable lithium battery anode. Small 13:1603973. https://doi.org/10.1002/smll.201603973 Zhou X, Wan LJ, Guo YG (2013) Binding SnO2 nanocrystals in nitrogen‐doped graphene sheets as anode materials for lithium‐ion batteries. Adv Mater 25:2152–2157. https://doi.org/10.1002/adma.201300071 Zhang H, Song H, Chen X, Zhou J, Zhang H (2012) Preparation and electrochemical performance of SnO2@ carbon nanotube core–shell structure composites as anode material for lithium-ion batteries. Electrochim Acta 59:160–167. https://doi.org/10.1016/j.electacta.2011.10.055 Lou XW, Li CM, Archer LA (2009) Designed synthesis of coaxial SnO2@ carbon hollow nanospheres for highly reversible lithium storage. Adv Mater 21:2536–2539. https://doi.org/10.1002/adma.200803439 Noerochim L, Wang JZ, Chou SL, Wexler D, Liu HK (2012) Free-standing single-walled carbon nanotube/SnO2 anode paper for flexible lithium-ion batteries. Carbon 50:1289–1297. https://doi.org/10.1016/j.carbon.2011.10.049 Lei C, Chen Z, Sohn HS et al (2014) Better lithium-ion storage materials made through hierarchical assemblies of active nanorods and nanocrystals. J. Mater. Chem. A 2:17536–17544. https://doi.org/10.1039/c4ta03715d Köse H, Aydin AO, Akbulut H (2013) Sol–gel preparation and electrochemical characterization of SnO2/MWCNTs anode materials for Li-ion batteries. Appl Surf Sci 275:160–167. https://doi.org/10.1016/j.apsusc.2013.01.055 Wen ZH, Wang Q, Zhang Q, Li JH (2007) In situ growth of mesoporous SnO2 on multiwalled carbon nanotubes: a novel composite with porous‐tube structure as anode for lithium batteries. Adv Func Mater 17:2772–2778. https://doi.org/10.1002/adfm.200600739 Jin RC, Meng YF, Li GH (2017) Multiwalled carbon nanotubes@ C@ SnO2 quantum dots and SnO2 quantum dots@ C as high rate anode materials for lithium-ion batteries. Appl Surf Sci 423:476–483. https://doi.org/10.1016/j.apsusc.2017.06.215 Lee K, Shin S, Degen T, Lee W, Yoon YS (2017) In situ analysis of SnO2/Fe2O3/RGO to unravel the structural collapse mechanism and enhanced electrical conductivity for lithium-ion batteries. Nano Energy 32:397–407. https://doi.org/10.1016/j.nanoen.2016.12.058